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CHM136Exam4(S2006) YCP CHM 136
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  • Title: CHM136Exam4(S2006)
  • Type: Notes
  • School: YCP
  • Course: CHM 136
  • Term: Spring

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136 CHM General Chemistry II Exam 4, Spring 2006 Dr. Steel Name 1. True or False. Indicate whether each statement is true or false by circling the appropriate letter. (2 points each) T T T T T T T T T T F F F F F F F F F F All endothermic processes are non-spontaneous. At the endpoint of a titration the pH of the solution is 7.00 The enthalpy change of a reaction equals the change in internal energy when there is no change in the volume of the system. Heat and temperature are interchangeable terms. Kinetic energy is the energy of motion. Entropy is a measure of the heat of substance in it pure form at STP. A spontaneous process increases the entropy of the universe. The pH of a buffer is close to the pKa of the weak acid used to prepare it. An ionic salt is typically less soluble in a solution containing one of the ions of the salt than it is in pure water. If a process has a positive So it will always be spontaneous. sys 2. A sample of copper has a mass of 26.2 grams and is heated to a temperature of 83.7 C. It is placed into a calorimeter containing 80.0 g of water at 21.3 C. Find the temperature at which the system equilibrates. (12 points) 3. A 150-gram sample of water vapor is heated from 110 C to 143 C. As it warms the sample expands by 250 mL against a constant atmospheric pressure of 3.75 atm. What is the change in internal energy ( E) of the sample of water vapor? (10 points) 4. The reaction below has an equilibrium constant K = 7.21 10-5 at 500. K. Use this and information the thermodynamic information provided on the last page to determine its standard entropy of reaction. (6 points) COCl2(g) CO(g) + Cl2(g) 5. Determine the range of temperatures for which the reaction in question 4 is spontaneous. (6 points) 6. Determine the standard enthalpy of reaction for the following reaction. (10 points) 2 H2S(g) + 3 O2(g) 2 H2O(g) + 2 SO2(g) 7. Determine the standard entropy change for the reaction in question 6. (10 points) 8. Determine the standard free energy change at 25 C for the reaction in question 6. (10 points) 9. What is the heat absorbed or released when 6.92 grams of H2S are reacted with excess oxygen gas, according to the reaction in question 6? (10 points) 10. A buffer solution is prepared by mixing 60.0 mL of 0.655-M hypochlorous acid, HClO, with 50.0 mL of bleach that is 5.00%, by mass, sodium hypochlorite, NaClO. The density of the bleach is 1.08g/mL. What is the pH of the buffer solution? (6 points) Useful Information Thermodynamic Data kJ H o ( mol ) f J So ( mol K ) Cl2(g) CO(g) COCl2(g) H2O(g) H2S(g) O2(g) SO2(g) 0 -110.5 -218.8 -241.8 -20.6 0 -296.8 Specific Heat Capacities 188.8 205.8 205.1 248.2 Copper: 0.385 J g K Water(l): 4.184 J g K Water(g): 1.92 J g K Acid Dissociation Constants Ka Kb HCl HClO ClO-1 H2O large 3.5 10-8 ---1.0 10-14 Molar Masses H C O Na S Cl Cu 1.008 12.01 16.00 22.99 32.07 35.45 63.55 g mol g mol ------2.9 10-7 1.0 10-14 g mol g mol g mol g mol g mol

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Path: N. Kentucky >> SYL >> 081 Fall, 2008
Description: Organic Chemistry Lab CHE 310L-015 Fall 2008 Tuesday 9:25a.m.-12:25 p.m. SC 461 Instructor: Gwen Fields office: SC 442 Phone: 572-6681 E-mail: Fieldsg@nku.edu Office hours: MWF 10-11a.m. T 1-2 p.m. Prerequisite: CHE 121 and CHE121L Co-requisite: CHE ...
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Path: N. Kentucky >> SYL >> 081 Fall, 2008
Description: Organic Chemistry Lab CHE 310L-016 Fall 2008 Thursday 1:40-4:40 p.m. SC 465 Instructor: Gwen Fields office: SC 442 Phone: 572-6681 E-mail: Fieldsg@nku.edu Office hours: MWF 10-11 a.m. T 1-2p.m. Prerequisite: CHE 121 and CHE121L Co-requisite: CHE 310 ...
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Path: N. Kentucky >> SYL >> 081 Fall, 2008
Description: Fall 2008 CHE 310-L-012 ORGANIC CHEMISTRY LABORATORY Tues.; 1:40-4:40 Room SC 461 Prerequisite: CHE 121 and 121L Pre or Co-requisite: CHE 310 Lecture Note carefully: students who withdraw from 310 lecture must withdraw from 310-lab; if they do not,...
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Path: N. Kentucky >> SYL >> 081 Fall, 2008
Description: CHE 310-L-017 ORGANIC CHEMISTRY LABORATORY Fall 2008 M; 2-5 Room SC 465 Prerequisite: CHE 121 and 121L Pre or Co-requisite: CHE 310 Lecture Note carefully: students who withdraw from 310 lecture must withdraw from 310-lab; if they do not, they will b...
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Path: N. Kentucky >> SYL >> 081 Fall, 2008
Description: CHE 310 L 013 Organic Chemistry Laboratory I Fall 2008 Instructor : Prof. K.C. Russell Office : Natural Science Center 350 Internet via: http:/www.nku.edu/~russellk/310l.html e-mail : russellk@nku.edu Phone : (859) 572 - 6110 Requirements: A grade o...
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Path: N. Kentucky >> SYL >> 081 Fall, 2008
Description: Organic Chemistry Laboratory 1 CHE 310L-011 Fall 2008 Instructor: Dr. Bradley Sieve Time Mon 2-5:00 PM Place: SC 461 Office: SC 452 email: sieveb1@NKU.edu Office Hours: Monday 11-12, Tuesday 12-1; Thursday 11-12 Phone: ext 6547 Outside office hours...
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Path: N. Kentucky >> SYL >> 081 Fall, 2008
Description: Instructor: Dr. Grant Edwards SC 443; 859-572-5411 Office Hours: open door, or by appointment Email: edwardsg1@nku.edu CHE 340L-012 ANALYTICAL CHEMISTRY LABORATORY FALL 2008 Learning Outcomes: This courses student learning outcomes fulfill the follow...
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Path: N. Kentucky >> SYL >> 081 Fall, 2008
Description: Biochemistry I CHE 482 / BIO 482 Fall 2008 Class time: Location: Instructor: MWF 11:00 - 11:50 SC 305 Dr. Stefan Paula SC 445 paulas1@nku.edu 572-6552 Office hours: W 1:00 3:00 F 12:00 2:00 or by appointment Text: Fundamentals of Biochemistry: Lif...
081_492_003_sp.pdf
Path: N. Kentucky >> SYL >> 081 Fall, 2008
Description: Research in Chemistry CHE 492 Research Mentor: Office Hours: Prerequisite: Lab Times: Stefan Paula, Ph.D. paulas1@nku.edu 572-6552 (SC 445) Wednesday: 1:00 3:00 pm; Friday: 12:00 2:00 pm, and by appointment Consent of instructor By arrangement wit...
081_492_004_kcr.pdf
Path: N. Kentucky >> SYL >> 081 Fall, 2008
Description: CHE 492 - 004: Chemistry Research Fall 2008 Instructor : Prof. K.C. Russell Office : Natural Science Center 350 Internet via: http:/www.nku.edu/~russellk e-mail : russellk@nku.edu Phone : (859) 572 - 6110 Prerequisites: Lab Times: Office Hours: Commu...
082_310_n01_kcr.pdf
Path: N. Kentucky >> CHM >> 310 Fall, 2008
Description: CHE 310 N01 : Organic Chemistry I Spring 2009 Instructor : Prof. K.C. Russell Office : Natural Science Center 350 Internet: www.nku.edu/~russellk Course web page: www.nku.edu/~russellk/courses/chm310/310.htm e-mail : russellk@nku.edu Phone : (859) 5...
schedule.pdf
Path: N. Kentucky >> CHM >> 310 Fall, 2008
Description: Dr. KC Russell Spring 2008 Phone: (859)572 -6110 Internet: http:/www.nku.edu/~russellk e-mail : russellk@nku.edu 7:00 AM 8:00 AM 9:00 AM 10:00 AM 11:00 AM 12:00 PM 1:00 PM 2:00 PM 3:00 PM MON TUES WED THURS CHE 311 - Discussion SC 305 FRI Offi...

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