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310MSp0901232009

Course: CH 53170, Spring 2009
School: University of Texas
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310M/318M CH MWF 9:00 Lecture 2 F 1/23/2009 Reading Assignment: Continue reviewing Chapter 1 material Textbook Problems: 1.1, 1.2, 1.6, 1.7, 1.20, 1.21, 1.23, 1.27-1.30 Graded Homework: HW#01 will be posted this weekend (due on 2/2) Last Time: Today: Overview of course Introduction to organic chemistry alkanes and constitutional isomers Lewis structures Be sure to download the course syllabus from...

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310M/318M CH MWF 9:00 Lecture 2 F 1/23/2009 Reading Assignment: Continue reviewing Chapter 1 material Textbook Problems: 1.1, 1.2, 1.6, 1.7, 1.20, 1.21, 1.23, 1.27-1.30 Graded Homework: HW#01 will be posted this weekend (due on 2/2) Last Time: Today: Overview of course Introduction to organic chemistry alkanes and constitutional isomers Lewis structures Be sure to download the course syllabus from Blackboard if you have not already done so!!! HW#01 will be posted over the weekend If you have an excusable conflict for ANY of the three midterm exams, the deadline to sign up to take a conflict exam is 5:00 p.m. on Friday, February 6. Please fill out a Petition for Alternate Exam Time form which can be obtained from WEL 2.212. Sign up before the deadline students who miss this deadline WILL NOT be allowed to take the conflict exams!!! Historical definition of organic chemistry = study of compounds produced by living organisms Vital force hypothesis = living systems possess a vital force that is necessary to produce organic compounds. Organic compounds can only be produced by living organisms, or from other organic compounds. Friedrich Wohler (1828) wanted to make ammonium cyanate from silver cyanate and ammonium chloride AgOCN(aq) + silver cyanate chloride (inorganic) NH4Cl(aq) ammonium (inorganic) AgCl(s) silver chloride (inorganic) + NH4OCN(aq) ammonium cyanate (inorganic) Instead of ammonium cyanate, Wohler isolated urea as a product. Urea is an organic compound that was first isolated from human urine in 1773. AgOCN(aq) silver cyanate (inorganic) + NH4Cl(aq) ammonium chloride (inorganic) AgCl(s) silver chloride (inorganic) + H2NCONH2 urea (organic!!!) First known example of an organic compound being produced from inorganic compounds, outside of a living organism. First evidence that the vital force hypothesis was wrong!!! Modern definition of organic chemistry = the chemistry of compounds containing carbon (and hydrogen) >95% of all known chemical compounds are organic compounds that is almost 20 million!!! (Only 1.5 million species of living organisms have been discovered.) Why is carbon special??? 1) Carbon can bond to itself to form long chains. CC single bonds are quite strong, and consequently are quite stable. 2) Carbon also forms strong bonds with a variety of other nonmetal atoms (H, O, N, S, halogens, P). 3) Carbon compounds having the same molecular formula can have different molecular structures. To illustrate this last point, lets take a look at some simple alkanes
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University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 3 M 1/26/2009Reading Assignment: Continue reviewing Chapter 1 material Textbook Problems: 1.13, 1.31, 1.32, 1.38-1.40, 1.67, 1.68 Graded Homework: HW#01 deadline = 3:00 p.m. on Mon 2/2 Last Time: Introduction to org
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 4 W 1/28/2009Reading Assignment: No new reading Textbook Problems: 1.14, 1.24-1.26, 1.33-1.37, 1.49, 1.50, 1.65, 1.66 Graded Homework: HW#01 deadline = 3:00 p.m. on Mon 2/2 Last Time: Today: Lewis structures (conti
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 5 F 1/30/2009Reading Assignment: No new reading Textbook Problems: 1.16-1.18, 1.51-1.55, 1.69, 1.70, 1.74, 1.75 Graded Homework: HW#01 deadline = 3:00 p.m. on Mon 2/2HW#02 deadline = 3:00 p.m. on Thu 2/5Last Time:
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 6 M 2/2/2009Reading Assignment: Sections 1.3, 2.1, 2.2 Textbook Problems: 1.15, 1.19, 1.56-1.63, 1.71-1.73, 1.77, 1.78 Graded Homework: HW#01 deadline = 3:00 p.m. TODAY Last Time: Polar and nonpolar molecules Reson
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 7 W 2/4/2009Reading Assignment: Section 2.3 Textbook Problems: 1.8-1.11, 1.41-1.48 Graded Homework: HW#02 deadline = 3:00 p.m. on Thu 2/5 Last Time: Resonance (continued) Valence bond theory and hybridization HW#03
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 8 F 2/6/2009Reading Assignment: No new reading Textbook Problems: 2.1, 2.2, 2.16-2.23 Graded Homework: HW#03 deadline = 3:00 p.m. on Mon 2/9 Last Time: Valence bond theory and hybrid orbitals (continued) Hybridizat
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 9 M 2/9/2009Reading Assignment: No new reading Textbook Problems: 2.25 Graded Homework: HW#03 deadline = 3:00 p.m. TODAY Last Time: Today: Functional groups Alkanes line-angle structures Degree of substitution C
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 10 W 2/11/2009Reading Assignment: Sections 2.4-2.6 Textbook Problems: 2.3, 2.24, 2.26-2.28 Graded Homework: HW#04 deadline = 3:00 p.m. on Thu 2/12 Last Time: Today:HW#05 deadline = 3:00 p.m. on Mon 2/16 (last graded
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 11 F 2/13/2009Reading Assignment: No new reading Textbook Problems: 2.8, 2.32-2.35 Graded Homework: HW#05 deadline = 3:00 p.m. on Mon 2/16 Last Time: Today:(last graded HW due before Midterm #1) Nomenclature of acy
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 12 M 2/16/2009Reading Assignment: No new reading Textbook Problems: No new problems Graded Homework: HW#05 deadline = 3:00 p.m. TODAY Last Time:(last graded HW due before Midterm #1) Nomenclature of acyclic alkane
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 13 W 2/18/2009Reading Assignment: No new reading Textbook Problems: No new problems Graded Homework: HW#06 will be posted on Thursday (due Th 2/26) Last Time: Today: Conformational analysis of ethane Conformational
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 14 F 2/20/2009Reading Assignment: Sections 2.7-2.9 Textbook Problems: 2.9, 2.12, 2.40-2.44 Graded Homework: HW#06 deadline = 3:00 p.m. on Thu 2/26 Last Time: Conformational analysis of butane Introduction to cycloa
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 15 M 2/23/2009Reading Assignment: Sections 3.1-3.3 Textbook Problems: 2.10, 2.13, 2.14, 2.36, 2.48-2.52, 2.61-2.63 Graded Homework: HW#06 deadline = 3:00 p.m. on Thu 2/26 Last Time: cis/trans stereoisomers of cycloa
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 16 W 2/25/2009Reading Assignment: Sections 3.4-3.6 Textbook Problems: 2.15, 2.53, 2.56, 2.58-2.60, 2.64, 2.65 Graded Homework: HW#06 deadline = 3:00 p.m. on Thu 2/26 Last Time: Today:HW#07 deadline = 3:00 p.m. on Mo
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 17 F 2/27/2009Reading Assignment: No new reading Textbook Problems: 3.1, 3.13-3.19 Graded Homework: HW#07 deadline = 3:00 p.m. on Mon 3/2 Last Time:HW#08 deadline = 3:00 p.m. on Thu 3/5 Conformational analysis of s
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 18 M 3/2/2009Reading Assignment: Sections 3.7 & 3.8 Textbook Problems: 3.2, 3.3, 3.20-3.24 Graded Homework: HW#07 deadline = 3:00 p.m. TODAY Last Time: Today: HW#08 deadline = 3:00 p.m. on Thu 3/5 Stereochemist
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 19 W 3/4/2009Reading Assignment: Sections 4.1 & 4.2 Textbook Problems: 3.4, 3.5, 3.7, 3.8, 3.10(a), 3.25-3.28, 3.30-3.32,3.34, 3.37Graded Homework: Last Time: HW#08 deadline = 3:00 p.m. on Thu 3/5 HW#09 deadl
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 20 F 3/6/2009Reading Assignment: Sections 4.3-4.5 Textbook Problems: Catch up on Chapter 3 problems! Graded Homework: Last Time: Today:HW#09 deadline = 3:00 p.m. on Mon 3/9 HW#10 deadline = 3:00 p.m. on Thu 3/12 A
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 21 M 3/9/2009Reading Assignment: Sections 4.6 & 4.7 Textbook Problems: 4.1-4.4, 4.9-4.13 Graded Homework: Last Time:HW#09 deadline = 3:00 p.m. TODAY HW#10 deadline = 3:00 p.m. on Thu 3/12 Diastereomers and meso co
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 22 W 3/11/2009Reading Assignment: Sections 3.9, 5.1-5.3 Textbook Problems: 4.14-4.17, 4.24-4.31, 4.36, 4.38-4.45, 4.47-4.54 Graded Homework: Last Time:HW#10 deadline = 3:00 p.m. on Thu 3/12 HW#11 deadline = 3:00 p.m
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 23 F 3/13/2009Reading Assignment: Sections 6.1-6.3 (we will begin Ch. 6 on M 3/23, Textbook Problems: 4.32-4.35, 4.37, 4.46, 5.1-5.20, 5.23, 5.24 Graded Homework: Last Time:but no Ch. 6 material will be included on
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 24 M 3/23/2009Reading Assignment: No new reading Textbook Problems: No new problemsthe last book problems that Graded Homework: Last Time:are relevant for Exam #2 were assigned F 3/13 HW#11 deadline = 3:00 p.m. TOD
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 25 W 3/25/2009Reading Assignment: Sections 4.5, 6.1-6.3 Textbook Problems: New problems will be assigned on Friday Graded Homework: HW#12 will be posted tomorrow (due Thu 4/2) Last Time: Nomenclature and stereochemi
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 26 F 3/27/2009Reading Assignment: No new reading Textbook Problems: 4.20, 4.22, 6.1-6.3, 6.13-6.15, 6.21, 6.22, 6.48, 6.49 Graded Homework: HW#12 deadline = 3:00 p.m. on Thu 4/2 Last Time: Today: Regioselectivity of
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 27 M 3/30/2009Reading Assignment: Sections 6.4 & 6.5 Textbook Problems: 6.4-6.6, 6.17, 6.27, 6.29, 6.35, 6.50 Graded Homework: HW#12 deadline = 3:00 p.m. on Thu 4/2 Last Time: Reaction coordinate diagrams Why is t
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 28 W 4/1/2009Reading Assignment: Sections 6.6 & 6.7 Textbook Problems: 6.7, 6.8, 6.20, 6.23, 6.25, 6.26, 6.28, 6.30-6.34, 6.46 Graded Homework: HW#12 deadline = 3:00 p.m. on Thu 4/2 Last Time: Today: Stereoselectivi
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 29 F 4/3/2009Reading Assignment: No new reading Textbook Problems: 6.9, 6.16, 6.18, 6.19, 6.36, 6.37 Graded Homework: HW#13 deadline = 3:00 p.m. on Mon 4/6 Last Time:HW#14 deadline = 3:00 p.m. on Thu 4/9 Acid-catal
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 30 M 4/6/2009Reading Assignment: Sections 7.1-7.5 Textbook Problems: 6.11, 6.12, 6.38-6.41, 6.43-6.45, 6.47 Graded Homework: HW#13 deadline = 3:00 p.m. TODAY Last Time: Halohydrin & haloether formation Oxymercurati
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 31 W 4/8/2009Reading Assignment: Sections 7.6 & 7.7 Textbook Problems: 7.1, 7.2, 7.7 plus Alkyne Nomenclature PracticeProblems (online handout)Graded Homework: HW#14 deadline = 3:00 p.m. on Thu 4/9 Last Time: Toda
University of Texas - CH - 53170
CH 310M/318M MWF 9:00 Lecture 32 F 4/10/2009Reading Assignment: Sections 7.8 & 7.9 Textbook Problems: 7.3, 7.10, 7.15, 7.26 Graded Homework: HW#15 deadline = 3:00 p.m. on Mon 4/13 Last Time: HW#16 deadline = 3:00 p.m. on Thu 4/16 Ozonolysis o
Istanbul Technical University - IE - IE 306
Performance Evaluation Techniques Summer 2005 Workload Modeling and GenerationDr.-Ing. Andreas WilligTelecommunication Networks Group (TKN) Technical University Berlin awillig@ieee.org June 26, 2005Andreas WilligModule Summary In this module
Temple - BIOLOGY - 2112
WAVELENG TH 450 475 500 525 550 575 600 625 650 675 7000D BENCH 1 0D BENCH 2 1.85 1.48 0.398 0.108 0.078 0.074 0.074 0.082 0.117 0.116 0.07 1.999 1.03 0.522 0.588 0.556 0.802 0.556 1.68 1.999 1.045 1.999OD BENCH 3 1.999 1.9 0.618 0.122 0.045 0.02
Temple - BIOLOGY - 2112
400 425 450 475 500 525 550 575 600 625 650 675 7001.3 1.95 1.85 1.48 0.4 0.11 0.08 0.07 0.07 0.08 0.12 0.12 0.072 2 2 1.03 0.52 0.59 0.56 0.8 0.56 1.68 2 1.05 22 2 2 1.9 0.62 0.12 0.05 0.03 0.02 0.02 0.15 0.45 0.742 2 1.42 0.96 0.51 0.43 0.3
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Atinuke Omolara Physics 1061 Lab: Section 4 Instructor: Charles Swartz February 23, 2009Objective: In this experiment we will study average velocity by using an air track and photogate timing system. We will also differentiate between average and i
Temple - ECON - 1101
Atinuke Omolara Macroeconomics 1101: Section 007 Dr. Donald Wargo Due: February 26, 2009Internet Assignment1. Iraq and Afghanistan We are still involved in wars in Iraq and Afghanistan. Both are an emerging economies and still a (perceived) threa
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Atinuke Omolara Physics Lab 1061: The Coefficient of Friction Charles Swartz March 2, 2009 Objective: In this lab we measured the coefficient of kinetic friction for a wood block sliding on a level plane and an inclined plane. Through the experimenta
Temple - PHYSICS - 1061
Atinuke Omolara Physics Lab 1061 Momentum- Elastic and Inelastic Collisions March 16, 2009Objective: To study momentum and the conservation of energy in one dimensional collisions Introduction:Collisions between two (or more) objects provide a go
Temple - BIOLOGY - 1111
Atinuke Omolara 911176509 Biology Assignment #1 tinuomo@temple.edu Search Terms: Phylogeny and Human There is currently little explanation to the demographic history of human evolution due to a lack of anthropological evidence from the Middle Stone
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Atinuke Omolara Mosaic 852, Section 84 Professor Jamal Benin Makeup TestRiver out of Eden, written by Richard Dawkins, and Good Natured: the Origins of Right and Wrong in Humans and Other Animals, written by Frans de Waal, are two works that delve
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Atinuke Omolara Physic Lab 1061 Projectile Motion and the Conservation of Energy Charles SwartzObjective: We will predict the position of a ball that is shot at an angle using project motion and observe if the total mechanical energy is conserved.
Temple - PHYSICS - 1061
Atinuke Omolara Physics 1061 Lab Circular Motion Charles SwartzObjective: To measure the centripetal acceleration and show that it depends on the speed of the object and the radius of the circle. Introduction: An object moving in a circular path at
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Atinuke Omolara April 2, 2009 Macroeconomics 1101 Dr. Donald WargoThe comic that I found the most compelling was the one about the island that developed its own currency. The booklet began describing the history of money in a story about a communit
Temple - ENGLISH - 1197
In Arundhati Roy's novel, The God of Small Things, the laws of India's caste system are broken by the characters of Ammu and Velutha, an Untouchable or Paravan. Velutha works at the Paradise Pickles and Preserves Factory owned by Ammu's family. Yet,
Temple - BIOLOGY - 1111
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Atinuke Omolara November 25, 2008 Mosaic Humanities 851, Section 62 Professor B.Preston LylesIn a region of the world where chaos and uncertainty prevailed, a grand empire emerged from the depths of the earth. At the moment, you are entering a civi
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Enzyme Lab Protocol October 22, 2008 Biology 2112 Part A Objective: We are finding the absorbency of the different concentrations of pnitrophenol and make a Procedure: 1. Label six tubes 1,2,3,4,5, Blank 2. Prepare the dilutions of P-ntirophenol usin
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Temple - BIOLOGY - 1111
0 -1 -2 -3 -4 -5 -6 -7 -8 -9 -10 1 2 3 4 5 6 7 8 9 10 0 0 -1 -2 -3 -4 -5 -6 -7 -8 -9 -10 1 2 3 4 5 6 7 8 9 10 08.52 7.54 7.13 6.84 6.55 6.16 5.13 3.04 2.74 2.63 2.54 10.64 11.11 11.34 11.48 11.57 11.66 11.72 11.79 11.82 11.87 8.31 4.45 2.75 2.53 2.
Temple - BIOLOGY - 1111
0.5 1 1.5 2 2.50.04 0.09 0.14 0.2 0.23Standard Curve Coomassie Blu0.23 0.22 0.21 0.2 0.19 0.18 0.17 0.16 0.15 0.14 0.13 0.12 0.11 0.1 0.09 0.08 0.07 0.06 0.05 0.04 0.03 0.5 0.75 1 1.25 1.5 1.75 2 2.25Optical DensityCoomassie Blue2.5Cooma
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Temple - BIOLOGY - 1111
Temple - BIOLOGY - 1111
1 2 3 4 5 6 7 8 9 10 11 12 13 1410.9 11.3 8.3 12.2 11.1 8.2 10.4 7.8 9.9 10.2 12.1 11.1 9.8 111 2 3 4 5 6 7 8 9 10 11 12 13 1412.9 15.7 12.8 13.4 14.8 11.3 14.9 15.2 11.2 14.1 13.9 13.6 12.3 14Reaction time of Do16 15.5 15 14.5Distance (cm