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C12S5F04
Course: CHE 12, Fall 2009School: Illinois State
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12 Chapter Sheet 5 Hydroboration - Oxidation 1) Give the product for the following reactions. a) 1) B2H6 2) H2O, NaOH, H2O2 b) 1) BH3-THF 2) H2O, NaOH, H2O2 c) 1) 2) B2H6 H2O, NaOH, H2O2 d) 1) BH3-THF 2) H2O, NaOH, H2O2 e) 1) B2H6 2) H2O, NaOH, H2O2 f) 1) BH3-THF 2) H2O, NaOH, H2O2 g) 1) B2H6 2) H2O, NaOH, H2O2
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12 Chapter Sheet 5
Hydroboration - Oxidation
1) Give the product for the following reactions.
a) 1) B2H6 2) H2O, NaOH, H2O2 b)
1) BH3-THF 2) H2O, NaOH, H2O2
c)
1) 2) B2H6 H2O, NaOH, H2O2
d)
1) BH3-THF 2) H2O, NaOH, H2O2
e) 1) B2H6 2) H2O, NaOH, H2O2
f)...
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Illinois State - CHE - 232
Chapter 12 Sheet 5Hydroboration - Oxidation1) Give the product for the following reactions.a) 1) B2H6 2) H2O, NaOH, H2O2 b)1) BH3-THF 2) H2O, NaOH, H2O2c)1) B2H6 2) H2O, NaOH, H2O2d)1) BH3-THF 2) H2O, NaOH, H2O2e) 1) B2H6 2) H2O, NaOH
Illinois State - CHE - 220
CHE 220Chapter 1 Sheet 1Lewis StructuresDraw Lewis structures for the following species, using lines for covalent bonds and showing any nonbonding electrons that are present. Show formal charges where relevant. a) NF3 (First atom is the central
Illinois State - CHE - 220
CHE 220Chapter 8 Sheet 4Oxidation1) Show all the products for the following reactions.a) KMnO4HOb)OHCrO3 H2SO4c)HOHK2Cr2O7 H2SO4d)OHK2Cr2O7 H2SO4e)OHPCCf)HOH HCrO3 H2SO4g)KMnO4HO
Illinois State - CHE - 14
CHE 220Chapter 14 Sheet 1Carboxylic Acid Nomenclature1) Give the IUPAC name for the following molecules.Oa) b) c)OHOOHHO OOH3-(1-methylethyl) benzoic acid2-ethylpentanoic acid3-hydroxy-5-(1,2-dimethylpropyl)benzoic acidCld)
Illinois State - CHE - 220
CHE 220Chapter 14 Sheet 1Carboxylic Acid Nomenclature1) Give the IUPAC name for the following molecules.Oa) b) c)OHOOHHO OOH3-(1-methylethyl) benzoic acid2-ethylpentanoic acid3-hydroxy-5-(1,2-dimethylpropyl)benzoic acidCld)
Illinois State - CHE - 220
CHE 220Chapter 6 & 7 Sheet 4Chirality1) Determine if the following compounds are chiral or achiral.a) HOH OH Hb)c) H HHd) Br HH H Bre)f) HOH g) OH HBr CH 3 I Br CH3h)i)H H Hj)H3C HH CH3k)H H3CH CH3
Illinois State - CHE - 10
CHE 220Chapter 10 Sheet 2Acylation of Amines1) Predict the products for the following reactions.a) NH2 + N H O HN Ob)NH2 + ClOc) NH2 + ClO N H O + H3C NH Cl H3C O + Cl N O H O NOd)e)NH2
Illinois State - CHE - 220
CHE 220Chapter 10 Sheet 2Acylation of Amines1) Predict the products for the following reactions.a) NH2 + N H O HN Ob)NH2 + ClOc) NH2 + ClO N H O + H3C NH Cl H3C O + Cl N O H O NOd)e)NH2
Illinois State - CHE - 220
CHE 220Chapter 3 Sheet 4Cycloalkane Conformations and some Nomenclature (Cis/Trans)1) Give the IUPAC name for the following molecules.a)CH3b)H3CCH3c)d)e)f)H H3CCH3 HCH3g)H 3C HHh)H Hi)H3C H H CH32) Draw the
Illinois State - CHE - 14
CHE 220Chapter 14 Sheet 2Reactions of Carboxylic Acids1) Provide products for the following reactions.a) O O OH 1) LiAlH4, THF 2) H+, H2O c) OH O d) O O OH 1) Br2, P 2) H+, H2O 3) NH3, H2O, OH O OH OH 1) Br2, P 2) H+, H2Ob)e)OO
Illinois State - CHE - 220
CHE 220Chapter 14 Sheet 2Reactions of Carboxylic Acids1) Provide products for the following reactions.a) O O OH 1) LiAlH4, THF 2) H+, H2O c) OH O d) O O OH 1) Br2, P 2) H+, H2O 3) NH3, H2O, OH O OH OH 1) Br2, P 2) H+, H2Ob)e)OO
Illinois State - CHE - 220
CHE 220Chapter 9 Sheet 8Friedel-Crafts Acylation1) Give the products for the reactions shown below. (Assume that only a single addition will occur to each aromatic ring.)Cl a) + O AlCl3O b) + ClAlCl3c) + O d) + CH3 e) O + O f) O Cl AlCl3
Illinois State - CHE - 220
CHE 220Chapter 6 & 7 Sheet 9SN1 & SN2 Mechanisms Galore1) Provide a mechanism for each of the reactions shown below.a) -CNISN2 ReactionNCb)CH3OH+ H+ICH3OSN1 Reaction+ I-CH3OHH O H3Cc)HBrCH3S-SCH3 HSN2 Reaction
Illinois State - CHE - 220
CHE 220Chapter 8 Sheet 3BStereospecific Conversion1) Show all the products for the following reactions.a)HO+ PBr3Brb)PBr3Br OHc)HOHSOCl2 pyridineClHd)OH+ SOCl2 pyridine SOCl2 pyridineCle)ClOHf) SOCl2 pyrid
Illinois State - CHE - 10
CHE 220Chapter 10 Sheet 4Amine Formation1) Predict the products for the following reactions.a) Cl NH3 NH2b)Br KCNCNc) Cl1) KCN 2) LiAlH4, Et2O 3) H+ , H2O 1) N3Br O 2) LiAlH4, Et2O 3) H+ , H2ONH2d)NH2e)NH2NH2
Illinois State - CHE - 220
CHE 220Chapter 10 Sheet 4Amine Formation1) Predict the products for the following reactions.a) Cl NH3 NH2b)Br KCNCNc) Cl1) KCN 2) LiAlH4, Et2O 3) H+ , H2O 1) N3Br O 2) LiAlH4, Et2O 3) H+ , H2ONH2d)NH2e)NH2NH2
Illinois State - CHE - 13
CHE 220Chapter 13 Sheet 7Grignard Reduction1) Give the product for the following reactions.a) 1) CH3MgBrO2) H+/H2OOH MgBr HOb)O1) 2) H+/H2Oc) 1) CH3CH2MgBr O 2) H+/H2O 1) 2) H+/H2O OHd)OMgBr OHe)1) CH3MgBrO2) H+/H2O
Illinois State - CHE - 220
CHE 220Chapter 13 Sheet 7Grignard Reduction1) Give the product for the following reactions.a) 1) CH3MgBrO2) H+/H2OOH MgBr HOb)O1) 2) H+/H2Oc) 1) CH3CH2MgBr O 2) H+/H2O 1) 2) H+/H2O OHd)OMgBr OHe)1) CH3MgBrO2) H+/H2O
Illinois State - CHE - 220
CHE 220Chapter 8 Sheet 7Reaction of Ethers1) Show all the products for the following reactions.a) HBrOb)HIOc) CH3S-Od)CH3S-Oe)O1) LiAlH4 2) H+/H2O CH3MgBrf)Og)H2SO4OCH3OHh)H2SO4OCH3OH
Illinois State - CHE - 220
CHE 220Chapter 6 & 7 Sheet 10Choosing a Mechanism1) Decide by which mechanism each of the following molecules will react, SN1 or SN2.a) b) c)ClCl Brd)BrCH3Cl e) f)Ig)h)Ii)IH Br2) For those molecules reacting by an SN1 r
Illinois State - CHE - 220
CHE 220Chapter 4/5 Sheet 15Halogenation of Dienes1) Give the major organic products for the following reactions.a)+ Br2BrCCl4Br Br BrClb) + Cl2 CCl4Cl ClCl Cl Cl Cl Br Brc)+ Cl2 CCl4Cl Brd)+ Br2 CCl4Br
Illinois State - CHE - 13
CHE 220Chapter 13 Sheet 4Formation of Hemiacetals1) Give the products for the reactions shown below.a) O HOCH3b)OHOCH2CH3c)O HOCH(CH3)2d) O O CHHOCH3e)CH3CH2OH
Illinois State - CHE - 220
CHE 220Chapter 13 Sheet 4Formation of Hemiacetals1) Give the products for the reactions shown below.a) O HOCH3b)OHOCH2CH3c)O HOCH(CH3)2d) O O CHHOCH3e)CH3CH2OH
Illinois State - CHE - 10
CHE 220Chapter 10 Sheet 4Amine Formation1) Predict the products for the following reactions.a) Cl NH3b)Br KCNc) Cl1) KCN 2) LiAlH4, Et2O 3) H+ , H2O 1) N3Br O 2) LiAlH4, Et2O 3) H+ , H2O LiAlH4d)e)NH2
Illinois State - CHE - 220
CHE 220Chapter 10 Sheet 4Amine Formation1) Predict the products for the following reactions.a) Cl NH3b)Br KCNc) Cl1) KCN 2) LiAlH4, Et2O 3) H+ , H2O 1) N3Br O 2) LiAlH4, Et2O 3) H+ , H2O LiAlH4d)e)NH2
Illinois State - CHE - 220
CHE 220Chapter 6 & 7 Sheet 5Nucleophilic Substitution Reactions1) Provide products for the following nucleophilic substitution reactions.a) -OHIb)C N Brc)BrOCH3d)CH3S-Cle)ClNH3f)I-Cl HONH2g)BrCH3CO2CH3CO2
Illinois State - CHE - 13
CHE 220Chapter 13 Sheet 8Wittig Reaction1) Give the products for the reactions shown below.a)O P = phenyl BenzeneZ-isomers of all the Wittig products would also occurb) O c) O CH P Benzene P Benzene C H
Illinois State - CHE - 220
CHE 220Chapter 13 Sheet 8Wittig Reaction1) Give the products for the reactions shown below.a)O P = phenyl BenzeneZ-isomers of all the Wittig products would also occurb) O c) O CH P Benzene P Benzene C H
Illinois State - CHE - 220
CHE 220Chapter 8 Sheet 3Alcohols to Alkyl Halides1) Show all the products for the following reactions.a) HBrHOb)HClOHc)HOHHCl d)OHHBr e)HOH HHBr f)HClH OHg)OHHCl
Illinois State - CHE - 220
CHE 220Chapter 8 Sheet 3Alcohols to Alkyl Halides1) Show all the products for the following reactions.a) HBrHOBrb)HClOHClc)HOHHCl Cld)OHHBr Bre)HOH HHBr HBr Hf)HClH OHCl Hg)OHHCl C
Illinois State - CHE - 10
CHE 220Chapter 10 Sheet 1Amine Nomenclature1) Give the IUPAC name for the following molecules.a) b) c)Cl NH2 N H NH2d)NH2e) f)H NNH2
Illinois State - CHE - 220
CHE 220Chapter 10 Sheet 1Amine Nomenclature1) Give the IUPAC name for the following molecules.a) b) c)Cl NH2 N H NH2d)NH2e) f)H NNH2
Illinois State - CHE - 15
CHE 220Chapter 20 Sheet 1Carboxylic Acid Derivatives Nomenclature1) Give the IUPAC name for the following molecules.Oa) b) c)Cl O O- K+ HO O OOOd) e)OH OO-Na+f)O Brg)O Clh)OH Oi)O H2NBrj)O HNk)O N
Illinois State - CHE - 220
CHE 220Chapter 20 Sheet 1Carboxylic Acid Derivatives Nomenclature1) Give the IUPAC name for the following molecules.Oa) b) c)Cl O O- K+ HO O OOOd) e)OH OO-Na+f)O Brg)O Clh)OH Oi)O H2NBrj)O HNk)O N
Illinois State - CHE - 220
CHE 220Chapter 8 Sheet 5Ethers1) Give the IUPAC name for the following molecules.a) b) c)OH BrH3CO Br Bre)OCH2CH3d)Of)OH3CO H
Illinois State - CHE - 232
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Chemistry 360 Dr. Jean M. Standard Fall 2008 October 10, 2008Name _KEY_Exam 2 100 points1 . ) (14 points) Determine the standard molar enthalpy of formation of B2H6 (g) at 298 K using only the data below. The standard state of boron at 298 K is
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Illinois State - CHE - 360
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Chemistry 360 Dr. Jean M. StandardProblem Set 7 Solutions1 . Determine A for a process in which 0.160 mol of an ideal gas expands reversibly and isothermally from 1.0 L to 3.5 L at 37C. A good place to start is the fundamental equation for A, dA
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Illinois State - MATH - 119
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!"! ## % ( + ! ' ) '$& "!' #* * #*%% #! " $!",, ! " % & ) " # $-)'$* #)## +)#+ ! . !) ' 0(" ! .# & ' $ !# $ 0) #/ * ) *'!!# ( )"' ! &#"# ) "$&, + ! . !) ' 1 0(" ! .# & '
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