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Cornell - CS - 419
CS419: Computer NetworksLecture 10, Part 4: Apr 18, 2005 Transport: TCP congestion controlTCP performanceCS419Weve seen how TCP the protocol worksSequencing, receive window, connection setup and teardownAnd weve seen techniques to make it pe
Oregon - CH - 2007
Amplifying small signalsModern physical chemistry often involves detection of signals which may be difficult to distinguish from noise. In such an experiment, it becomes necessary to recognize the fundamental sources of noise so that they may be dea
Oregon - CH - 418
Chemistry 418 PHYSICAL CHEMISTRY LABORATORY Winter, 2009Lecture/Discussion Lab 12:00 Monday and Tuesday 2:00 Tuesday or Wednesday 331 Klamath 120 KlamathOffice hours will be held in 174 Klamath at times to be posted on the class web site. Teaching
Oregon - CH - 417
Chemistry 417 Laboratory ScheduleTuesdayGroup: September 30 October 7 October 14 October 21 October 28 November 4 November 11 November 18 November 25 December 2 December 8-12 Group: October 1 October 8 October 15 October 22 October 29 November 5
Oregon - CH - 2007
Error analysis without tearsOne of the most dreaded aspects of the physical chemistry laboratory is the propagation of error. The purpose of this note is to show you how to use some of the modern mathematical tools to relieve yourself of some of the
Oregon - CH - 417
Error analysis without tearsOne of the most dreaded aspects of the physical chemistry laboratory is the propagation of error. The purpose of this note is to show you how to use some of the modern mathematical tools to relieve yourself of some of the
Oregon - CH - 2007
The square probability densityTo emphasize the generality of the points covered in the previous lecture, we examine another probability density function:"1, 0 ! x ! 1 f ( x) = # $0, otherwiseThe square probability densityWhat are the mean and v
Oregon - CH - 417
The square probability densityTo emphasize the generality of the points covered in the previous lecture, we examine another probability density function:"1, 0 ! x ! 1 f ( x) = # $0, otherwiseThe square probability densityWhat are the mean and v
Oregon - CH - 417
Error propagationWe wish to address the following question: How does the error in a measurement affect the uncertainty of a calculated parameter? This question arises whenever there is a parameter you want to measure which cannot be observed directl
Oregon - CH - 2007
The least squares methodThe method of least squares is a technique for finding the "best" set of parameters to fit a set of experimental data. It is the most commonly used fitting technique (other than "eyeballing" the data) used by physical scienti
Oregon - CH - 417
The least squares methodThe method of least squares is a technique for finding the "best" set of parameters to fit a set of experimental data. It is the most commonly used fitting technique (other than "eyeballing" the data) used by physical scienti
Oregon - CH - 2006
The Joule-Thomson expansionThe Joule-Thomson experiment is deceptively easy to describe and correspondingly difficult to perform. The experiment consists of forcing a gas at constant backing pressure through a porous plug and measuring the change in
Oregon - CH - 418
The Joule-Thomson expansionThe Joule-Thomson experiment is deceptively easy to describe and correspondingly difficult to perform. The experiment consists of forcing a gas at constant backing pressure through a porous plug and measuring the change in
Oregon - CH - 2007
Ohm's LawE = IRwhere E is the electromotive force (voltage) applied to the circuit I is the current through the circuit, and R is the resistance of the circuit.Series resistorsIf resistors are placed in series in a circuit, the overall resistan
Oregon - CH - 417
Ohm's LawE = IRwhere E is the electromotive force (voltage) applied to the circuit I is the current through the circuit, and R is the resistance of the circuit.Series resistorsIf resistors are placed in series in a circuit, the overall resistan
Oregon - CH - 2006
Acid phosphatase catalyzed hydrolysis of p-nitrophenol phosphateMonitor p-nitrophenol vs. time Convert p-nitrophenol concentration to a reaction rate Perform the Lineweaver-Burk fit Compare with literatureMonitoring p-nitrophenolIn the p-nitrophe
Oregon - CH - 418
Acid phosphatase catalyzed hydrolysis of p-nitrophenol phosphateMonitor p-nitrophenol vs. time Convert p-nitrophenol concentration to a reaction rate Perform the Lineweaver-Burk fit Compare with literatureMonitoring p-nitrophenolIn the p-nitrophe
Oregon - CH - 2007
Semiconductor diodesDiodes are devices which do not obey Ohm's law. They may be thought of as one-way gates for electric current which will allow current to flow in one direction but not the other. A diode has the symbol:The "arrowhead" points in
Oregon - CH - 417
Semiconductor diodesDiodes are devices which do not obey Ohm's law. They may be thought of as one-way gates for electric current which will allow current to flow in one direction but not the other. A diode has the symbol:The "arrowhead" points in
Oregon - CH - 2006
What a poster session is likea hot, congested room lled with people who are there to socialize, not to look at posters. And, because poster sessions are often concurrent with the "wine and beer" session, chaos is further increased by hundreds of dru
Oregon - CH - 418
What a poster session is likea hot, congested room lled with people who are there to socialize, not to look at posters. And, because poster sessions are often concurrent with the "wine and beer" session, chaos is further increased by hundreds of dru
Oregon - CH - 2007
Given two periodic functionsy=Asin1t Determine whether 1=2 First, multiply the functions together:1 yz = Asin 1t sin 2 t = A{cos ( 1t 2 t) cos( 1t + 2 t )} 2z=sin2t Next, average over the signals for a long time If 1 and 2>0, cos(1t+2t) ave
Oregon - CH - 417
Given two periodic functionsy=Asin1t Determine whether 1=2 First, multiply the functions together:1 yz = Asin 1t sin 2 t = A{cos ( 1t 2 t) cos( 1t + 2 t )} 2z=sin2t Next, average over the signals for a long time If 1 and 2>0, cos(1t+2t) ave
Oregon - CH - 2007
The nature of logic circuitsA logic circuit is an electronic device used to mimic the operations of symbolic logic. Symbolic logic consists of expressions which contain variables and operations, and which may assume values of "true" or"false." In th
Oregon - CH - 417
The nature of logic circuitsA logic circuit is an electronic device used to mimic the operations of symbolic logic. Symbolic logic consists of expressions which contain variables and operations, and which may assume values of "true" or"false." In th
Oregon - CH - 417
Writing a lab reportThe first thing to realize in preparing a technical paper is that there is a prescribed literary form for such a document. Like a haiku or a sonnet, a scientific paper must adhere to certain standards of organization and presenta
Oregon - CH - 2007
Active and passive circuit elementsThe circuit elements we have encountered up to now have been, for the most part, passive circuit elements. These include, for example, resistors and capacitors. They alter the flow of electrons through a circuit, b
Oregon - CH - 417
Active and passive circuit elementsThe circuit elements we have encountered up to now have been, for the most part, passive circuit elements. These include, for example, resistors and capacitors. They alter the flow of electrons through a circuit, b
Oregon - CH - 2007
Compressibility of a real gasThe compressibility factor of a gas (and, by extension, any fluid) is defined asPVm Z= RTFor an ideal gas, the compressibility factor is always 1. For a real gas, the deviation of the compressibility factor from 1 is
Oregon - CH - 417
Compressibility of a real gasThe compressibility factor of a gas (and, by extension, any fluid) is defined asPVm Z= RTFor an ideal gas, the compressibility factor is always 1. For a real gas, the deviation of the compressibility factor from 1 is
Oregon - CH - 2006
An overview of GC/MSAutomatic liquid sampler (ALS) Mass spectrometerGas chromatographThe autosamplerThis is the only part of the apparatus that actually appears to do anything. Its function is to inject a measured sample onto the GC column.Th
Oregon - CH - 418
An overview of GC/MSAutomatic liquid sampler (ALS) Mass spectrometerGas chromatographThe autosamplerThis is the only part of the apparatus that actually appears to do anything. Its function is to inject a measured sample onto the GC column.Th
Oregon - CH - 2006
Base catalyzed ester hydrolysisWe start with what you learned in organic chemistry:R C O + OHkOR' k+ O R C OR' OH-activated complexk'R C O + OR'very fastR C O + R'OHOHOBase catalyzed ester hydrolysis.Symbolically,k' AB C + D A + B
Oregon - CH - 418
Base catalyzed ester hydrolysisWe start with what you learned in organic chemistry:R C O + OHkOR' k+ O R C OR' OH-activated complexk'R C O + OR'very fastR C O + R'OHOHOBase catalyzed ester hydrolysis.Symbolically,k' AB C + D A + B
Oregon - CH - 2006
Solutions of rate equationsThe analytic method:dN = kN Write the differential equation dt dN = kdt Rearrange N N Integrate ln = kt N0SimplifyN = N0 e ktThe integration step depends, among other things, on having only one variable on each
Oregon - CH - 418
Solutions of rate equationsThe analytic method:dN = kN Write the differential equation dt dN = kdt Rearrange N N Integrate ln = kt N0SimplifyN = N0 e ktThe integration step depends, among other things, on having only one variable on each
Oregon - CH - 2006
Photochemical processesAbsorption of light (creation of an electronically excited state) Relaxation (thermalization of vibrational energy within that state) Emission from the original excited state (fluorescence) Thermalization of electronic energy
Oregon - CH - 418
Photochemical processesAbsorption of light (creation of an electronically excited state) Relaxation (thermalization of vibrational energy within that state) Emission from the original excited state (fluorescence) Thermalization of electronic energy
Oregon - CH - 2007
The Boltzmann distributionThe Boltzmann distribution predicts the probability that a molecule will be found in a particular state with a given energy if the molecule is in thermal equilibrium with a constant temperature bath: EiPi ! e"kTThe
Oregon - CH - 418
The Boltzmann distributionThe Boltzmann distribution predicts the probability that a molecule will be found in a particular state with a given energy if the molecule is in thermal equilibrium with a constant temperature bath: EiPi ! e"kTThe
Oregon - CH - 2006
Ethyl acetate hydrolysisTo follow the progress of the reactionNa+ + OH + EtOAc EtOH + Na + + OAc conductimetrically, we need to observe two overriding principles: Choose a method of measurement that is linear in concentration so that a minimum
Oregon - CH - 418
Ethyl acetate hydrolysisTo follow the progress of the reactionNa+ + OH + EtOAc EtOH + Na + + OAc conductimetrically, we need to observe two overriding principles: Choose a method of measurement that is linear in concentration so that a minimum
Oregon - CH - 2006
Phosphatase-catalyzed hydrolysisIn this experiment you will monitor the hydrolysis of a phosphate ester. This hydrolysis is catalyzed by a phosphatase enzyme (typically one derived from wheat germ or potatoes). This reaction is extremely important i
Oregon - CH - 418
Phosphatase-catalyzed hydrolysisIn this experiment you will monitor the hydrolysis of a phosphate ester. This hydrolysis is catalyzed by a phosphatase enzyme (typically one derived from wheat germ or potatoes). This reaction is extremely important i
Oregon - CH - 2007
Solutions of rate equationsThe analytic method:dN = ! kN Write the differential equation dt dN = ! kdt Rearrange N N Integrate ln = !kt N0SimplifyN = N0 e! ktThe integration step depends, among other things, on having only one variable on eac
Oregon - CH - 418
Solutions of rate equationsThe analytic method:dN = ! kN Write the differential equation dt dN = ! kdt Rearrange N N Integrate ln = !kt N0SimplifyN = N0 e! ktThe integration step depends, among other things, on having only one variable on eac
Oregon - CH - 2006
Adjustment handle Diaphragm (elastomer or metal)The RegulatorSpringMain valve (essentially a bicycle valve)outletinletThe RegulatorDiaphragm (elastomer or metal) inlet outlet Main valve (essentially a bicycle valve)The RegulatorStainl
Oregon - CH - 418
Adjustment handle Diaphragm (elastomer or metal)The RegulatorSpringMain valve (essentially a bicycle valve)outletinletThe RegulatorDiaphragm (elastomer or metal) inlet outlet Main valve (essentially a bicycle valve)The RegulatorStainl
Oregon - CH - 2007
Acid phosphatase catalyzed hydrolysis of p-nitrophenol phosphateMonitor p-nitrophenol vs. time Convert p-nitrophenol concentration to a reaction rate Perform the Lineweaver-Burk t Compare with literatureMonitoring p-nitrophenolIn the p-nitropheno
Oregon - CH - 418
Acid phosphatase catalyzed hydrolysis of p-nitrophenol phosphateMonitor p-nitrophenol vs. time Convert p-nitrophenol concentration to a reaction rate Perform the Lineweaver-Burk t Compare with literatureMonitoring p-nitrophenolIn the p-nitropheno
Oregon - CH - 2006
EtOAc.nb1The basic integral:In[9]:=Out[9]=1 x Ha - xL Hb - xLLog@-a + xD - Log@-b + xD a-bEvaluate at the limits of integration:In[10]:= Out[10]=Log@-a + xD - Log@-b + xD Log@-a + 0D - Log@-b + 0D - a-b a-b Log@-aD -
Oregon - CH - 418
EtOAc.nb1The basic integral:In[9]:=Out[9]=1 x Ha - xL Hb - xLLog@-a + xD - Log@-b + xD a-bEvaluate at the limits of integration:In[10]:= Out[10]=Log@-a + xD - Log@-b + xD Log@-a + 0D - Log@-b + 0D - a-b a-b Log@-aD -
Oregon - CH - 2006
Modeling Reaction RatesThe procedure for modeling chemical reaction rates generally follows these steps: Postulate a chemical modeln1 R1 + n2 R2 + ProductWrite the related rate equationd[Product] n1 n2 = [R1 ] [R2 ] dtIntegrate the differe
Oregon - CH - 418
Modeling Reaction RatesThe procedure for modeling chemical reaction rates generally follows these steps: Postulate a chemical modeln1 R1 + n2 R2 + ProductWrite the related rate equationd[Product] n1 n2 = [R1 ] [R2 ] dtIntegrate the differe
Oregon - CH - 2008
A gas chromatogram/mass spectrumObject of the exerciseWe would like to unravel the chemistry that occurs within the ionization source. The information available is The masses of the ions that survive the mass lter Their relative abundanceWhat we
Oregon - CH - 418
A gas chromatogram/mass spectrumObject of the exerciseWe would like to unravel the chemistry that occurs within the ionization source. The information available is The masses of the ions that survive the mass lter Their relative abundanceWhat we
Oregon - CH - 2008
Adsorption of a gas onto a surface Importance Study of intermolecular forces Chemical catalysis Gas storage Cryopumping Material study (and modification) Fluid purification Prototypes of other chemical processesCommon surfaces used "Ac
Oregon - CH - 418
Adsorption of a gas onto a surface Importance Study of intermolecular forces Chemical catalysis Gas storage Cryopumping Material study (and modification) Fluid purification Prototypes of other chemical processesCommon surfaces used "Ac
Oregon - CH - 2006
triggerstrobe driverTriplet lifetime experiment samplephotomultiplier tubestrobe lamp computeroscilloscopetriggerstrobe driverTriplet lifetime experiment samplephotomultiplier tubestrobe lamp computeroscilloscopeStrobe lampfast
Oregon - CH - 418
triggerstrobe driverTriplet lifetime experiment samplephotomultiplier tubestrobe lamp computeroscilloscopetriggerstrobe driverTriplet lifetime experiment samplephotomultiplier tubestrobe lamp computeroscilloscopeStrobe lampfast
Oregon - CH - 419
Molecular Vibrations We start with the Hamiltonian for a diatomic molecule:p e = + + + 2mN j 2mi rij rik2 i2 pN jZj e 22Z jZ l e 2 riland quickly abandon the effort. Instead, we make the Born-Oppenheimer approximation:=e+v+