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MCE 230 - Corrosion and Cathode Tests American University of Sharjah MECHANICAL 223,224,22
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  • Title: MCE 230 - Corrosion and Cathode Tests
  • Type: Notes
  • School: American University of Sharjah
  • Course: MECHANICAL 223,224,22
  • Term: Spring

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230 MCE L Materials Science Corrosion Test Gagan Gururaj ID: 8526 Group 2 Date of Experiment: 9/11/03 2 Table of Contents 1) Abstract........................................................................3 2) Part A: Introduction....................................................3 3) Theory..........................................................................3 4) Experimental procedure...............................................4 5) Data..............................................................................5 6) Calculations.................................................................6 7) Part B: Introduction....................................................6 8) Theory..........................................................................7 9) Experimental procedure...............................................7 10) Data............................................................................7 11) Calculations...............................................................8 12) Discussion and conclusion.........................................8 13) References (Part A)...................................................9 14) References (Part B)....................................................9 3 Abstract: There were two parts to this experiment. In the first part, samples of aluminum, copper and iron were immersed in concentrated sulfuric acid for ten minute intervals. After each ten minute interval, the weight of the samples were recorded. This process was done four times after which the corrosion rates were then found. Finally the corrosion rates versus the time were then plotted on a graph. In the second part of the experiment, a magnesium sample was connected to the apparatus and readings of the current were taken at regular intervals after which the graph of current versus time was plotted. Finally, the expected life of the magnesium anode was calculated for each reading. Part A (Corrosion) Introduction: Corrosion is a spontaneous degradation that a metal undergoes when exposed to an environmental factor such as air, water, corrosive chemicals or soil. Corrosion is caused by an electrochemical reaction that takes place between the metal and the environment. Many of the severe corrosion problems encountered in the chemical and processing industries involve acids. However, in some cases, electrochemical cells may be useful when it is used to deliberately create an electro-protective coating on materials. In this experiment, concentrated sulfuric acid was used. Theory: R=W At R: corrosion rate (cm / hr). W: weight loss (in gm to the nearest mg). A: area to the nearest 0.01cm2. t: the time of exposure in hours to the nearest 0.01 hr. 4 Experimental procedure: 1) Place 250 ml of hydrochloric acid into a beaker in a fume hood with extreme care. 2) Weigh the copper specimen. 3) Use a suitable wire to hang the specimen and clamp it to a stand (hold the specimen through the wire). 4) Immerse the steel specimen in the acid and make sure that the entire specimen is immersed in the acid solution. 5) After 10 minutes, take the sample out of the acid, wash it and then dry it thoroughly. 6) Weigh the sample. 7) Repeat steps 2-6 for the sample 3 more times. 8) Repeat all the above steps for samples of aluminum and iron. 5 Data: Metal Aluminum Copper Iron Length (cm) 4 4.08 2.94 Width (cm) 2.15 2.15 1.06 Thickness (cm) 0.3 0.52 0.0 Surface Area, A (cm2) 20.89 10.39 17.54 Aluminum Area (m2) Weight weight loss (g) (g) 6.62 0 6.619 0.001 6.618 0.001 6.617 0.001 6.616 0.001 20.89 Time (min) 0 10 20 30 40 corrosion rate 0.000281587 0.00014506 9.57396E-05 7.14475E-05 time (hrs) 0 0.17 0.33 0.5 0.67 Iron Area (m2) Weight (g) 6.359 6.358 6.358 6.358 6.358 weight loss (g) 0 0.001 0 0 0 17.54 Time (min) 0 10 20 30 40 corrosion rate 0.000335368 0 0 0 time (hrs) 0 0.17 0.33 0.5 0.67 Copper Area 2 (m ) Weight (g) 12.483 12.483 12.482 12.481 12.481 loss weight (g) 0 0 0.001 0.001 0 10.39 Time (min) 0 10 20 30 40 corrosion rate 0 0.000291656 0.000192493 0 time (hrs) 0 0.17 0.33 0.5 0.67 6 Corrosion rate Vs time 0.0004 0.00035 0.0003 Corrosion rate 0.00025 0.0002 0.00015 0.0001 0.00005 0 -0.00005 0 0.2 0.4 Time(hrs) 0.6 0.8 Aluminum Iron Copper Calculations: (Sample calculation) Corrosion rate of aluminum after 10 minutes is calculated by: R= 0.001 (20.89)(0.17) = 0.000281587 The corrosion rates of the other times and samples can be found in a similar manner by using the given formula. Part B (Cathodic protection) Introduction: Cathodic protection is one of a number of corrosion control practices that includes the application of protective coatings, and improved metallurgical techniques. To prevent corrosion, a common procedure is to introduce a piece of another metal, as a sacrificial anode, in contact with the metal to be protected. The sacrificial anode is composed of a metal, which has a greater tendency to corrode than does the metal to be protected; as a result, the sacrificial anode corrodes instead of the protected metal. The sacrificial anode can then be replaced periodically to maintain the protection. 7 Theory: Lm = 42.81*W I Lm = Life of magnesium anode, year W = Weight of anode, pounds i = milliampere output of anode Experimental procedure: 1) Set up the apparatus. 2) Put a weak salt solution in the beaker. 3) Record the current with each interval of time. As the cell becomes polarized the current will drop. 4) Do not disturb the corrosion products. These products will be seen to be distributed in the direction of current flow. The magnesium will dull and the unprotected pipe will corrode whilst the cathodic pipe remains protected. Data: Time (s) 0 20 40 60 80 100 120 140 160 180 200 Current (mA) 68 66 64 63 62 61 61 60 57.5 57 59 Life 0.009695 0.009989 0.010301 0.010465 0.010633 0.010808 0.010808 0.010988 0.011466 0.011566 0.011174 Weight of the magnesium sample = 0.0154lb 8 Cathodic protection 70 68 Current(mA) 66 64 62 60 58 56 0 100 Time (s) 200 300 Cathodic protection Calculations: (Sample calculation) L = 42.81(0.0154) = 0.011566 57 Discussion and Conclusion: In part (A), the more time the copper, aluminum and iron samples spend in the concentrated sulfuric acid, the more the weights of these three samples decrease. The graphs for the rate of corrosion versus time are all similar. The graphs and the readings clearly show that as the time increases, the corrosion rates for each sample decreases. Thus the conclusion is that the more time that the samples spend in the acid, the more the corrosion rate and weight increase. In part (B) of the experiment, a magnesium sample was used in the cathodic protection experiment and for every increase in time, the corresponding value of the current in milli-amperes was recorded after which a graph of current versus time was plotted. As can be seen from the graph and the table, it was concluded that as the time increased, there was a subsequent decrease in current. The expected life of the sample also increases along with the time. 9 References (Part A): 1) William D. Callister, Jr., "Materials Science & Engineering (An Introduction)", 3rd edition, Wily, USA, 1994. 2) MCE CHE 230 ,,Corrosion of Metals Lab Handout. References(Part B): 1. Donald R. Askeland, The science and engineering of materials, Third edition, PWS publishing Co., 1994. 2. Kenneth A. Solen, John N. Harb, Introduction to chemical process, Fundamentals and design, Third edition, The McGraw-Hill book Co., 1998 3. Corrosion SPE Reprint Series No. 46, 1997 published by the Society of Petroleum Engineers, Richardson, Texas 4. Denny A. Jones " Principles and prevention of corrosion" Second edition, Prentice Hall international, United State of America, 1996. 5. J R.Davis, Corrosion understanding the basics, ASM international, United State of America, 2000.

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Path: American University of Sharjah >> MECHANICAL >> 223,224,22 Spring, 2008

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Path: American University of Sharjah >> MECHANICAL >> 223,224,22 Spring, 2008
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Path: American University of Sharjah >> MECHANICAL >> 223,224,22 Spring, 2008
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Path: American University of Sharjah >> MECHANICAL >> 223,224,22 Spring, 2008
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Path: American University of Sharjah >> MECHANICAL >> 223,224,22 Spring, 2008
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Path: American University of Sharjah >> ARA >> 101,102 Spring, 2008
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Path: American University of Sharjah >> ARA >> 101,102 Spring, 2008
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Description: American University of Sharjah College of Engineering Mechanical Engineering Department Spring 2008 Due Date: Tuesday, February 12th, 2008. Statics MCE 220 Assignment # 3 Solve the following problems from the textbook (Engineering Mechanics: Stati...
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Description: American University of Sharjah College of Engineering Mechanical Engineering Department Spring 2008 Due Date: Sunday, February 10, 2008. Statics MCE 220 Assignment # 2 Solve the following problems from the textbook (Engineering Mechanics: Statics ...
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Description: American University of Sharjah College of Engineering Mechanical Engineering Department Spring 2008 Due Date: Sunday, March 2nd, 2008. Statics MCE 220 Assignment # 7 Solve the following problems from the textbook (Engineering Mechanics: Statics by...
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Description: CHAPTER 1 KEY EQUATIONS Equation Number Key Equation dq (t ) 1.1 i (t ) = 1.2 1.6 1.7 q (t ) = i (t )dt + q (t 0 ) p (t ) = v (t )i (t ) t0 t dt = t2 t1 p (t )dt 1 v = iR v ab = iab R 1.8 G = 1.9 1.10 1.12 1.13 R i = Gv L R= A p = Ri 2 v...
Chapter 02
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Description: CHAPTER 2 KEY EQUATIONS Equation Number Key Equation Req = R1 + R2 + R3 2.7 1 2.15 Req = 1 R1 + 1 R2 + 1 R3 1 2.17 Req = 1 R1 + 1 R2 + 1 R3 + 1 R4 1 2.18 Req = 1 R1 + 1 R2 2.19 2.22 2.23 2.24 2.27 2.28 Req = 2.63 2.68 R1 v R1 + R2 + R3 total R2 ...
Chapter 03
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Description: CHAPTER 3 KEY EQUATIONS Equation Number 3.1 3.3 3.5 3.8 3.14 Key Equation q = Cv i =C dv dt q (t ) = v (t ) = w (t ) = t 0 t i (t )dt + q (t0 ) C 1 t 0 t i (t )dt + v (t0 ) 3.15 3.16 3.23 3.25 3.26 1 Cv 2 (t ) 2 1 w (t ) = v (t )q (t )...
Chapter 04
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Description: CHAPTER 6 KEY EQUATIONS Equation Number Key Equation V 6.2 H (f ) = out Vin 1 6.8 fB = 2RC 1 6.9 H (f ) = 1 + j (f fB ) 1 6.10 H (f ) = 2 1 + (f fB ) 6.11 6.12 6.13 6.16 6.21 6.22 6.23 6.24 6.30 6.31 6.32 6.33 H (f ) = H 1 (f ) H 2 (f ) H (f ) = ...
Chapter 07
Path: American University of Sharjah >> MECHANICAL >> 223,224,22 Spring, 2008
Description: CHAPTER 7 KEY EQUATIONS Equation Number 7.1 7.2 7.3 7.4 7.5 7.6 Key Equation AA = A A1 = A A0 = 0 AB = BA A (BC ) = (AB )C = ABC AA =0 A =A (A + B ) + C = A + (B + C ) = A + B + C A (B + C ) = AB + AC 7.7 7.8 7.9 7.10 7.11 7.12 7.13 7.19 7.20 A+0=...
Statics HW _16, Spring 2008
Path: American University of Sharjah >> MCE >> 240 Spring, 2008
Description: American University of Sharjah College of Engineering Mechanical Engineering Department Spring 2008 Due Date: Thursday, May 8th, 2008. Statics MCE 220-01 Assignment # 16 Solve the following problems from the textbook (Engineering Mechanics: Static...
Statics HW _17, Spring 2008
Path: American University of Sharjah >> MCE >> 240 Spring, 2008
Description: American University of Sharjah College of Engineering Mechanical Engineering Department Spring 2008 Due Date: Sunday, May 11th, 2008. Statics MCE 220-01 Assignment # 17 Solve the following problems from the textbook (Engineering Mechanics: Statics...
Static Bending Test - 45 Scratches
Path: American University of Sharjah >> MECHANICAL >> 223,224,22 Spring, 2008
Description: Test Type Name: Company: Lab name: Test date: Geometry: Specimen Specimen name: Width: Thickness: Support span: Fixture type: Comment: Flexure Fall 2003 Gourp 2 AUS Materials Science 11/16/2003 Rectangular 1 Wood 25 25 360 3-point With 45 Scratches ...
Review_poblems_MTH205_Exam2_F07
Path: American University of Sharjah >> MCE >> 240 Spring, 2008
Description: MTH205: Practice Problems Exam 2 / Fall 07 Q1. Find an interval around x 0 for which the initial value problem 1 ( x 1) y\' \' y\' y sin( x) , y(0) 1 , y\' (0) 0 4 x2 has a unique solution. Q2. Consider the differential equation y 4y e2 x a) Find th...
Compression Test - 3 (Perpendicular)
Path: American University of Sharjah >> MECHANICAL >> 223,224,22 Spring, 2008
Description: Test Type Name: Company: Lab name: Test date: Geometry: Specimen Specimen name: Width: Thickness: Length: Compression Test with Perpendicular Sample Fall 2003-Group 2 AUS Material Sc. Lab 10/19/2003 Rectangular 1 Wood 50 mm 50 mm 150 mm Extension mm...
Chapter 09
Path: American University of Sharjah >> MECHANICAL >> 223,224,22 Spring, 2008
Description: CHAPTER 9 KEY EQUATIONS Equation Number Key Equation v sensor = Km 9.1 Error = x m - x true 9.3 9.4 9.5 9.6 Percentage error = vd = v1 - v 2 x m - x true 100% x full v cm = 9.8 9.9 1 (v + v 2 ) 2 1 N = 2k Nqrms = 2 3 ...
Chapter 14
Path: American University of Sharjah >> MECHANICAL >> 223,224,22 Spring, 2008
Description: CHAPTER 14 KEY EQUATIONS Equation Number Key Equation 1 v icm = (v 1 + v 2 ) 2 v id = v 1 - v 2 14.5 14.21 14.23 14.25 14.30 14.31 14.32 14.34 14.35 14.36 14.37 14.38 14.42 14.43 14.44 14.45 R vo =- 2 v in R1 R v Av = o = 1 + 2 v in R1 A 0OL A OL (...
Nfinal research paper biofuel
Path: American University of Sharjah >> MCE >> 240 Spring, 2008
Description: Biofuel: \"A better substitute or not\" Research Essay Final draft Umer S. Iqbal b00025744 Dr Khawlah Ahmed American University of Sharjah December 12, 2007 Biofuel: \"A better substitute or not\" 1 Biofuel: \"A better substitute or not\" There is a sig...
Chapter 08
Path: American University of Sharjah >> MECHANICAL >> 223,224,22 Spring, 2008
Description: Chapter 8 There are no key equations in Chapter 8. ...
Review poblems Final Fall05
Path: American University of Sharjah >> MCE >> 240 Spring, 2008
Description: MTH205: Review Problems / Final / Fall 05 Q1. Consider the differential equation: y\' y x x a) Does the differential equation possess a unique solution through the point (0,0) ? Give reasons. b) Find the general solution, c) Find the solution that...
Syllabus2
Path: American University of Sharjah >> MCE >> 240 Spring, 2008
Description: American University of Sharjah Mechanical Engineering Department MCE 234 Computer Applications in Mechanical Engineering (2-3-3) Instructor: Dr. Mamoun F. Abdel-Hafez mabdelhafez@aus.edu Office ER130 Tel. 515 2910 Fall 2007 Lecture: MW 9:30 am - 10:2...

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