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### Assignment5

Course: CHEM 458, Fall 2009
School: Virgin Islands
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Word Count: 143

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Set Problem #5 CHEM 458/55 Statistical Thermodynamics Spring 2009 Due: March 16, 2009 #1. Using the Grand Canonical Ensemble determine the order of magnitude of fluctuations in particle number of a vessel containing on average one mole of particles when in contact with a reservoir. Hint: It will make the math a little easier if you define = /kT. Boltzmann Statistics (a) Calculate the de Broglie wavelength for...

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Set Problem #5 CHEM 458/55 Statistical Thermodynamics Spring 2009 Due: March 16, 2009 #1. Using the Grand Canonical Ensemble determine the order of magnitude of fluctuations in particle number of a vessel containing on average one mole of particles when in contact with a reservoir. Hint: It will make the math a little easier if you define = /kT. Boltzmann Statistics (a) Calculate the de Broglie wavelength for a Helium atom at STP. Will it obey Boltzmann Statistics under conditions? these Justify your answer. (b) Assuming ideal gas-like behavior, estimate the de Broglie wavelength for an electron in a typical metal at STP, Copper for instance. Will it obey Boltzmann Statistics under these conditions? Justify your answer. #2. #3. From IR spectros...

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