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Macon State - CHEM - 1211
PowerPoint Lecture Presentation by J. David Robertson University of MissouriChemical Bonding II: Molecular Geometry and Hybridization of Atomic OrbitalsChapter 10Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or d
Macon State - CHEM - 1211
PowerPoint Lecture Presentation by J. David Robertson University of MissouriIntermolecular Forces and Liquids and SolidsChapter 11Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.A phase is a homogeneou
Macon State - CHEM - 2241
Syllabus For Chemistry 2241K Fundamental Organic Chemistry I Fall Semester , 2007Lecture: ITEC 212, TR 11:00 - 12:15 p.m. Lab: Jones 352, Section 51 Section 52 Tuesday 1:00 - 3:50 p.m. Thursday 1:00 - 3:50 p.m.Instructor: Dr. N. C. Yang Office: Jo
Macon State - CHEM - 2241
Chapter 10 Alkyl Halides: Nucleophilic Substitutions and Eliminations 2006 Thomson Higher EducationAlkyl HalidesAlkyl halide or haloalkanes Compounds with a halogen atom bonded to a saturated sp3-hybridized carbon atom Widespread in natureC
Neumont - CSC - 1987
Reference re Bill 30, An Act to Amend the Education Act (Ont.), [1987] 1 S.C.R. 1148IN THE MATTER OF A REFERENCE to the Court of Appeal pursuant to Section 19 of the Courts of Justice Act, 1984, Statutes of Ontario, 1984, Chapter 11, by Order-in-Co
Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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Macon State - CHEM - 2241
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UNL - I - 386
-BEGIN PGP SIGNED MESSAGE-Hash: SHA1SHORT PACKAGE INFOName:openal-0.0.9-0.7.20060204cvs.el4Summary:Open Audio LibraryGroup:System Environment/LibrariesCHANGELOG (recent): * Mon Aug 21 2006 Andreas Bierfert <andreas.bierfert[AT]lowlatency.de
Grinnell - BIO - 150
Bio. 150 - Population Density ExperimentTotal number of gametophytes in dish A 230 734 1040 711 1075 338 1135 441 B 464 540 671 428 310 517 554 266 C 454 446 410 306 327 322 383 315 % Males A 50 55 51 40 53 48 53 60 B 31 52 47 42 46 45 52 42 C 50 49
Grinnell - BIO - 150
Bio. 150 - Population Density ExperimentTotal number of gametophytes in dish A 230 734 1040 711 1075 338 1135 441 B 464 540 671 428 310 517 554 266 C 454 446 410 306 327 322 383 315 % Males A 50 55 51 40 53 48 53 60 B 31 52 47 42 46 45 52 42 C 50 49
UMass (Amherst) - CHEM - 4680
Organometallic Chemistrybetween organic and inorganicPeter H.M. BudzelaarCourse Roadmap A real example: the Monsanto Acetic Acid process Introduction: what is organometallic chemistry, and why should you care? Electron counting: the
UMass (Amherst) - CHEM - 4680
Electron Countingunderstanding structure and reactivityRh = 9 3* P = 6 Cl = 1 + e-count 16 tot. charge 0 3*P Cl -1 - ox state +1 Cr = 2*Bz = 6 12 + e-count 18 tot. charge 0 2*Bz - ox state 0Peter H.M. BudzelaarWhy count electrons ?
UMass (Amherst) - CHEM - 4680
Organometallic Chemistryan overview of structures and reactionsPeter H.M. BudzelaarBetween organic and inorganic.Organic chemistry: more or less covalent C-X bonds rigid element environments fixed oxidation states (better: valencies) ?Organo
UMass (Amherst) - CHEM - 4680
Organometallic Chemistryan overview of structures and reactionsPeter H.M. BudzelaarBetween organic and inorganic.Organic chemistry: more or less covalent C-X bonds rigid element environments fixed oxidation states (better: valencies) ?Organo
UMass (Amherst) - CHEM - 4680
OrganoLithium CompoundsPeter H.M. BudzelaarOrgano-lithium compounds Ionic character, electron-deficient oligomeric or polymeric structures Strongly basic and nucleophilic applications in organic synthesis Reducing unwanted side reactions
UMass (Amherst) - CHEM - 4680
OrganoMagnesium CompoundsPeter H.M. BudzelaarOrgano-Mg and Be compoundsLike Organolithium compounds, but milder: Ionic character, electron-deficient oligomeric or polymeric structures Basic and nucleophilic Mg: applications in organic synth
UMass (Amherst) - CHEM - 4680
OrganoSilicon CompoundsPeter H.M. BudzelaarOrganosilicon compoundsSilicon is just like carbon, but: Larger five- and six-coordinate structures positive More electropositive easier attack by nucleophiles Does not want to form multiple bond
UMass (Amherst) - CHEM - 4680
III-V Cluster CompoundsPeter H.M. BudzelaarSemiconductorsThe most common semiconductor is silicon, which forms a diamond lattice.2III-V ClustersSemiconductorsSemiconductors based in III-V combinations (Al/Ga/In with N/P/As) are becoming m
UMass (Amherst) - CHEM - 4680
Characterization of Organometallic CompoundsPeter H.M. BudzelaarCharacterization of organometallicsMain characterization methods: Xray diffraction (static) structure bonding NMR structure en dynamic behaviour EA assessment of purity (cal
UMass (Amherst) - CHEM - 4680
Ligand SubstitutionReactivity of Coordinated LigandsCl Cl Pd 2Cl Cl C2H4 Cl Cl Pd H2O Cl Cl H2O Pd Cl OH Cl OH OHPd(0) +H + H2O + 2 Cl+- 2 e (CuCl2 CuCl) H ClCl H2O PdCl H2O Pd CH3CHO- ClCl H2O PdClCl H2O Pd O "-H elim" H Cl H2O Pd OH in
UMass (Amherst) - CHEM - 4680
Ligand SubstitutionReactivity of Coordinated LigandsCl Cl Pd 2Cl Cl C2H4 Cl Cl Pd H2O Cl Cl H2O Pd Cl OH Cl OHPd(0) + H+ + H2O + 2 Cl- 2 e (CuCl2 CuCl) H Cl Cl H2O PdCl H2O Pd CH3CHO- ClCl H2O Pd OHClCl H2O Pd O "-H elim" H Cl H2O Pd OH ins
UMass (Amherst) - CHEM - 4680
Carbenes and Olefin MetathesisM C + C C M C C C M C + C CPeter H.M. BudzelaarMetal-carbon multiple bonds Many transition metals form not only M-C single bonds but also M=C and (more rare) even MC bonds. Complexes containing an M=C bond are cal
UMass (Amherst) - CHEM - 4680
CHEM4680 - Organometallic ChemistryMid-term test: electron counting, main group metals and NMRGeneral remarks: Don't forget the back of the first page. You get marks for your arguments, not for the answers themselves. A correct answer without th
UMass (Amherst) - CHEM - 4680
CHEM4680 - Organometallic ChemistryMid-term test: electron counting, main group metals and NMRRough answers(your real answers should be a bit more detailed here and there)1. Counting.a. FeO4 Assuming four Fe=O bonds: Fe(8+), 16-e. The count co
UMass (Amherst) - CHEM - 4680
CHEM4680 - Organometallic ChemistryFinal examGeneral remarks: Don't forget the back of the first page. You get marks for your arguments, not for the answers themselves. A correct answer without the relevant argument doesn't get you any marks. A
UMass (Amherst) - CHEM - 4680
CHEM4680 - Organometallic ChemistryRough answers1. Counting.Ph2 P OH2 Fe Pd P Ph2 OH2 2+You have to decide where the "2+" charge belongs. First (arbitrarily) assign one "+" charge to each metal atom. This will give FeIII, 17-e and PdI, 17-e. Th
UMass (Amherst) - CHEM - 4680
CHEM4680 - Organometallic ChemistryMid-term test: electron counting, main group metals and NMRGeneral remarks: You get marks for your arguments, not for the answers themselves. A correct answer without the relevant argument doesn't get you any ma
UMass (Amherst) - CHEM - 4680
CHEM4680 - Organometallic ChemistryMid-term test: electron counting, main group metals and NMR Rough answers1. Counting (48 marks).Fe = C4H4 =Fe OC OC CO8 4 6 18Fe(0) if you count C4H4 as neutral (cyclobutadiene). But assuming C4H42- or C4H4
UMass (Amherst) - CHEM - 4680
CHEM4680 - Organometallic ChemistryFinal exam, April 22, 2008General remarks: Don't forget the back of the first page. You get marks for your arguments, not for the answers themselves. A correct answer without the relevant arguments doesn't get
UMass (Amherst) - CHEM - 4680
CHEM4680: Organometallic Chemistry Mid-term examination, February 26, 2009. Duration: 75 minutes. Give motivated answers to the questions below. Your arguments count for more than the answers themselves. Question 1 counts for 6 marks (1 for each of a
UMass (Amherst) - CHEM - 4680
CHEM4680: Organometallic Chemistry Mid-term examination, February 26, 20091a) Mo 6 Cp*5 Me1 2*O= 4 -total 16 c) Various ways of counting depending on where you put the positive charge and how you draw the bonds (dative vs covalent) to the bridging
Case Western - EMSE - 201
EMSE 201 - Introduction to Materials Science & Engineering Name:8 November 2006SOLUTIONTest #2 - 75 minutes; 150 points; 6 questions; 6 pages; 15% of course gradePartial credit will be given for correct set-ups and reasoning. Give units on num
Case Western - EMSE - 426
EMSE 426, SPRING 20091.HOMEWORK : # 6DUE:03/02NAME:a) Briefly explain each term in the Nabarro-Herring and Coble creep equations. b) What is exactly the meaning of these two types of creep? Clearly explain the differences between the two t
UMass (Amherst) - CHEM - 4680
Assignments for Organometallic Chemistry (1) (CHEM4680)(1) Electron counting Give electron count and formal oxidation for the central metal atom in the following complexes, and try to draw conclusions about the stability of the complex. If you think
UMass (Amherst) - CHEM - 4680
Assignments for Organometallic Chemistry (1) (CHEM4680)(1) Electron counting Give electron count and formal oxidation for the central metal atom in the following complexes, and try to draw conclusions about the stability of the complex. If you thin
UMass (Amherst) - CHEM - 4680
Assignments for Organometallic Chemistry (2) (CHEM4680)(4) Hydrogenation catalysisThe Wilkinson catalyst Rh(PPh3)3Cl catalyzes olefin hydrogenation. Crabtree mentions a mechanism for this reaction:H H Cl Rh L L H2 A Cl Rh L L H Cl Rh L HLLL
UMass (Amherst) - CHEM - 4680
Assignments for Organometallic Chemistry (2) (CHEM4680)(4) Hydrogenation catalysisThe Wilkinson catalyst Rh(PPh3)3Cl catalyzes olefin hydrogenation. Crabtree mentions a mechanism for this reaction:H Cl Rh L H2 L A Cl L Rh L L H L B C H Cl Rh L L