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Course: CEM 251, Spring 2008
School: Michigan State University
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#3 Quiz (20 points) CEM252 Name:_______________ PID:_________________ Section:______________ Mark your answers in the box below (only answers in the box will be graded) Q1. b Q2. a Q3. b Q4. a Q5. a Q6. c Q7. b Q8. a Q9. b Q10. d 1. What is the commonly used name for the following compound? (2 points) O a. 1,4-Dioxane b. Tetrahydrofuran c. Ethylene Oxide d. Furan e. none of the above 2. What is the name of the...

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#3 Quiz (20 points) CEM252 Name:_______________ PID:_________________ Section:______________ Mark your answers in the box below (only answers in the box will be graded) Q1. b Q2. a Q3. b Q4. a Q5. a Q6. c Q7. b Q8. a Q9. b Q10. d 1. What is the commonly used name for the following compound? (2 points) O a. 1,4-Dioxane b. Tetrahydrofuran c. Ethylene Oxide d. Furan e. none of the above 2. What is the name of the following compound? (2 points) a. 3-methylbutyl phenyl ether b. Benzyl isopropyl ether c. Benzyl 3-methylbutyl ether d. Isopropyl phenyl ether e. Benzyl pentyl ether O 3. Which structure corresponds to the following name? (2 points) 4-allyl-2-ethoxyphenol OH O a b OH O c OH O d OH O e O O 4. Which of the following structures is mCPBA? (2 points) O a Cl OOH b Cl O H c O OOH d CH3 O OOH e Cl O OH 5. What is the name of the following compound? (2 points) O a. 2,3 epoxy-5 hexane cyclopentyl b. 4,5 epoxy-2 cyclopentyl hexane c. 3,4 epoxy-5 cyclopentyl-5 methyl pentane d. 3,4 epoxy-5 cyclopentyl hexane e. 2,3 epoxy-5 cyclopentyl-5 methyl pentane 6. Which of the following reagents will afford the following ether? (2 points) O O c Cl OH a Cl b O e O d O HO Cl Cl + H 2O 7. What is the product of the following reaction? (2 points) 1. Hg(OAc)2, CH3CH2OH 2. NaBH4 O a b O c d O O e product O O 8. What are the correct conditions for the following transformation? (2 points) ? OH O a. i. CH3CH2O-Na+; ii. H3O+ b. i. CH3CH2MgBr; ii. H3O+ c. i. CH3CH2Li; ii. H3O+ d. H+, CH3CH2OH e. Both (b) and (c) O 9. What is the product of the following reaction? (2 points) 250 oC O OH a OH b OH c d product OH e OH 10. What is the name of the reaction described in Question 9? (2 points) a. Grignard b. Friedel-Crafts c. Jones d. Claisen e. Williamson
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Michigan State University - CEM - 251
Quiz #4 (20 points) CEM252Name:_ PID:_ Section:_Mark your answers in the box below (only answers in the box will be graded) Q1. b Q2. a Q3. b Q4. a Q5. b Q6. a Q7. b Q8. d Q9. c Q10. b(2 points each question)1. What is the name of the followin
Michigan State University - CEM - 251
Quiz #5 (20 points) CEM252Name:_ PID:_ Section:_Mark your answers in the box below (only answers in the box will be graded) Q1. c Q2. e Q3. d Q4. b Q5. c Q6. c Q7. c Q8. b Q9. d Q10. e(2 points each question)1. What is the name of the followin
Michigan State University - CEM - 251
Problem Set #1: Chapters 15, 161. Provide the products of the following transformationsHNO3 H2SO4 H2, PdCH3Cl, AlCl3Br2 FeBr3Cl AlCl3 NBS H2O2O Cl AlCl3 H2SO4 heat H2, PdCl AlCl3KMnO4 NaOH heat I2 CuCl2H2SO4 heat1. NaOH 2. H3O+HNO
Michigan State University - CEM - 251
Problem Set #2: Chapters 17, 181. Provide the products and/or the conditions for the following transformations:1. NaBH4 2. H3O+ 3. SOCl2OClO O1. CH3MgBr (2 eq) 2. H3O+ 3. POCl3, pyrOH1. PCC 2. PhMgBr 3. H3O+OHHOO1. LiAlH4 2. H3O
Michigan State University - CEM - 251
Problem Set #3: Chapters 191. Provide the products and/or the conditions for the following transformations:OCH3 OCH3 1. H3O+ 2. Ph3P CH2O HCH3NH2 H+(cat)OOOHONH H+ (cat)O O OBr1. Ph3P 2. n-BuLi 3, acetaldehydeOH NH O OH
Texas A&M - PHYS - 208
E A (14 N/C) (0.250 m 2 ) cos 60 1.75 Nm 2 C. 22.1: a) b) As long as the sheet is flat, its shape does not matter. ci) The maximum flux occurs at an angle 0 between the normal and field. cii) The minimum flux occurs at an angle 90 between the norma
Texas A&M - PHYS - 208
22.4: E A(75 .0 N C) (0.240 m 2 ) cos 706.16 Nm 2 C.
Texas A&M - PHYS - 208
22.3: a) Given that E^ ^ Bi C^ Dk , j ^ ^ n jS1^ nS 2 ^ nS3 ^ nS 4 ^ nS5 ^ nS 66 i 1 i^ k ^ j ^ k ^ i ^ i E A, edge length L, and ^ E AnS1 CL2 . 1 ^ E AnS2 DL2 . 2 ^ E AnS3 CL2 . 3 ^ E AnS4 DL2 . 4 ^ E AnS5 BL2 . 5 ^ E AnS6 BL2 . 6
Texas A&M - PHYS - 208
22.5: a) E A2 0r(2rl )l 0( 6.00 106C/m) (0.400 m) 02.71 105 Nm2 C.b) We would get the same flux as in (a) if the cylinder's radius was made larger-the field lines must still pass through the surface. c) If the length was increased
Texas A&M - MATH - 308
ContentsCHAPTER 1: Introduction EXERCISES 1.1: Background, page 5 . . . . . . . . . . . . . . . . . . EXERCISES 1.2: Solutions and Initial Value Problems, page 14 . . . EXERCISES 1.3: Direction Fields, page 22 . . . . . . . . . . . . . . . EXERCISES
Texas A&M - MATH - 308
INSTRUCTOR'S RESOURCE GUIDEEDWARD B. SAFFVanderbilt UniversityA. DAVID SNIDERUniversity of South FloridaFUNDAMENTALS OF DIFFERENTIAL EQUATIONSSIXTH EDITIONFUNDAMENTALS OF DIFFERENTIAL EQUATIONS AND BOUNDARY VALUE PROBLEMSFOURTH EDITION R.
Michigan State University - BS - 111
FYI The final: December 11 time: 10:00 to NOON People with conflict email me with your schedule of exams so I can coordinate. I have the names, but want confirmation. [A male student who said he was coming to my office to pick up the last exam he d
Michigan State University - BS - 111
Dr. Steve SeiboldRes. Asst. Professor Chemistry Department Chemistry Building Room ? (help room 83-new annex) Contact: angel.msu.eduGTA: Jameel Al-HaddadEmail: Jameel@msu.edu Office hours: 4:00-6:00 Room 331b North Kedzie Review session: Wednesda
Michigan State University - BS - 111
No Make up Quizzes. Make up exams are NOT given You MAY BE eligible for a waiver provided a) you have a valid reason for missing the exam (major illness in family, illness), and b) you notify the BioSci office (432-1316 ext 144) AND the lecture
Michigan State University - BS - 111
Lecture Two Main Themes Electronic configurations gives rise to chemical properties: Covalent Bonds/Geometric Shapes Ionic Bonds Hydrophobic interactions van der Waals Hydrogen Bonding Inter/intra molecular Forces made up of chemical properti
Michigan State University - BS - 111
Main Themes Lecture Three Water's essential properties H-bonding High Heat of evaporation High Heat capacity Aqueous Reactions Precipitation Acid-Base ( Buffers) Redox1Macromolecules Chapter 3Molecules in living organisms: proteins, carb
Michigan State University - BS - 111
Functions of proteins: Structural support Protection Transport Catalysis Defense Regulation MovementMain Themes1Main Themes Lecture four Macromolecular Molecules-proteins, lipids, carbohydrates and nucleic acids. Monomers to polymers (la
Michigan State University - BS - 111
Energy, Enzymes, and Metabolism1I. Energy Unlike matter Energy cannot be seen, touched and weighted. Measure Energy's effects:Interchanging Types of Energy/Worke.g. Gravitational to electrical2A. Energy/Work in ChemistryChemical energy
Michigan State University - BS - 111
Summary of Lecture Eight Energy Types of energy/work in chemistry/biology Potential and Kinetic energy & Conversion between them First Law of Thermodynamics Second Law of Thermodynamics Enthalpy & Entropy equation= Gibbs free energy1 Energy
Michigan State University - BS - 111
Review of Lecture Nine Enzymes Enzymes and energy Their substrates How enzymes lower barrier Types of catalysis Cofactors1I. Lecture TenE=enzymeAE1BE2CE3DE4EA=product from other enzyme rxRegulation of enzymes and thus
Michigan State University - BS - 111
Summary of Lecture Ten Allosteric effects Inhibitors/activators sigmoidal Fluid Mosaic model: protein, lipid, carbohydrates Cell recognition/adhesion: Specificity Cell junctions( stability and communication) Tight Junctions Desmosomes Gap ju
Michigan State University - BS - 111
Summary Lecture eleven Membrane Transport/ diffusion, rate Simple diffusion: e.g Lipid membranes-Osmosis Facilitated diffusion Channel (gated) and carrier protein. Active Transport (Takes ATP hydrolysis) Primary Secondary Endo/Exocytosis1
Michigan State University - BS - 111
16C2CO2 absent6C 2C2I. Oxidative PhosphorylationA. Electron transport chain B. ChemiosmosisStructure of the mitochondrion3A. Electron transport "chain"Why does the electron transport chain have so many steps? Why notNADHH12
Michigan State University - BS - 111
*Jessica Miller *Brett Diffin *Yelena Kleshchik *Laura Van Putten * *Dina Valeeva * *Jennifer Vanvleet *Young Woo On *Audrey Karogosian *Nicole Butler *Rachel Young *Robert Vinney *Peter Wilson *Andrew Robertson *Bradley Gauthier *Ryan Burke *Yelnea
Michigan State University - BS - 111
1Chapter 15 Cell Signaling and Communication2I. Cell Signals and their response All cells process information from the environment. The information can be a physical stimulus, such as light; or chemical. Signals (information) can come from o
Michigan State University - BS - 111
Chapter 2: The Chemistry of LifeOVERVIEW The chapter describes the nature of atoms and elements. It continues by explaining chemical interactions such as covalent bonding, hydrogen bonding, ionic bonding, and hydrophobic interaction that will play a
Michigan State University - CEM - 251
Photosynthesis: Energy from SunlightPrebiotic: Hot springs1Photosynthesis: Energy from Sunlight2What exactly is photosynthesis ?3Electron-Transport Chain redox: Energy for synthesisGlycolysis/TCA NADH+ H+ & ATP-Used to synthesize biom
Michigan State University - CEM - 251
Lecture Seventeen Chapter 11 so far.I. II. III. DNA Discovery and Its Role. DNA Tertiary Structure. DNA Replication.1III. DNA ReplicationWatson/Crick: Proposed that each strand is replicated (acts as a template) and has a daughter strand.A. I
Michigan State University - CEM - 251
Lecture Sixteen Chapter 11I. II. III. DNA Discovery and Its Role. DNA Tertiary Structure. DNA Replication.1I. DNA Discover and its role in carrying genetic information. A. Fredrich Miesher 1869 NucleinNucleic AcidsB. Transformation of propert
Michigan State University - CEM - 251
Problem Set #1: Chapters 15, 161. Provide the products of the following transformations:HNO3 H2SO4 NO2 H2, Pd NH2CH3Cl, AlCl3 NH2 NH2+Br2 FeBr3BrCl AlCl3Br +BrNBS H2O2 Br + Br Br BrO Cl AlCl3O H2SO4 heat HO3SOH2, Pd HO3SCl
Michigan State University - CEM - 251
SAMPLE TEST 2 1. Nomenclature: a. AcetophenoneOb. 2-phenylhexanenitrileCN Phc. 2-methylbutyl pentanoateO ON Cl ON,N-dimethyl-3-chloropentanamideO OO butanoic 4-methylpentanoic anhydrideH O 3-methylcycloheptane carbaldehydeO Cl Cl 2
Michigan State University - CEM - 251
1 1) (6 Points, 2pts. each) Give the correct IUPAC name for the following structures:Br H3CH2C H CH2CH2CH3 Cla)H3Cb)CH3Include cis/trancec)ClCl2) (6 Points, 2pts. each) Give the correct structure for the following names:a) (Z)-3-ch
Michigan State University - CEM - 251
1 1. (6 Points, 2 points total each) Give the correct IUPAC name for the following structures:Bra)Include R/SH3CC CC(CH3)3b)c)F2. (6 Points, 2 points total each) Give the correct structure for the following names:a) Isobutyl bromideb
Michigan State University - CEM - 251
CEM 251Spring 20081st Problem Set(Chapters 1-6)1. For the following molecule:O Br C Nthe number of sp3 carbons is: the number of sp2 carbons is: the number of sp carbons is: the hybridization of N is: the hybridization of O is: the number of
Michigan State University - CEM - 251
Michigan State University - CEM - 251
Michigan State University - CEM - 251
Name: _ Date: _ Form B1. Ionic bonds are A) attractions between oppositely charged ions. B) the result of electron sharing. C) the strongest of the chemical bonds. D) dependent upon hydrophobic interactions.2. The more acidic of two solutions has
Michigan State University - CEM - 251
DNA Replication, Cont`dB. C. D. E. F. Three possible modes of DNA replication Melselson Stahl Experment Basic Mechanics of DNA Replication Stages in Replication DNA replication Fidelity.1From DNA to Protein: Genotype to Phenotype (chapter 12)I.
Michigan State University - CEM - 251
CEM 252 NMR-Session Problems 09-05-07Determine the structures of the molecules with the following spectra: 1. C6H13Cl6Cl32 1 14132 PPM1H NMR: 0.91 ppm (d, 6H); 1.49 ppm (t, 2H); 1.60 ppm (d, 3H); 1.62 ppm (m, 1H); 3.64 ppm (sextet
Michigan State University - CEM - 251
Problem Set #2: Chapters 17, 181. Provide the products and/or the conditions for the following transformations:1. NaBH4 2. H3O+ 3. SOCl2OO O1. CH3MgBr (2 eq) 2. H3O+ 3. POCl3, pyrOH OHHOO1. LiAlH4 2. H3O+ 3. PBr3O Ph Ph OHOH1. S
Michigan State University - CEM - 251
1. Complete the following reactions:1. O 1. LDA 2. PhSeCl 3. H2O2 N O 2. H3O+ O OO OHO 1. Br2, NaOH 2. H3 O+ Cl2 H3O+O ClO OH1. Br2, PBr3 2. H3O+ BrO OHO1. LDA (>1 eq.) 2. PhCH2Br PhO1. LDA (<1 eq.) 2. PhCH2BrPhOO CH3O 1.
Michigan State University - CEM - 251
Quiz #6 (20 points) CEM252Name:_ PID:_ Section:_Mark your answers in the box below (only answers in the box will be graded) Q1. d Q2. b Q3. c Q4. b Q5. b Q6. e Q7. d Q8. a Q9. a Q10. b(2 points each question)What are the starting materials / p
Michigan State University - CEM - 251
Quiz #7 (20 points) CEM252Name:_ PID:_ Section:_Mark your answers in the box below (only answers in the box will be graded; 2 points per question) Q1. c Q2. b Q3. d Q4. b Q5. e Q6. b Q7. c Q8. e Q9. c Q10. ea. N-ethyl, N-methyl cyclohexyl amine
Michigan State University - CEM - 251
CEM 252 Sample Final Exam1. Draw an example of any compound containing the indicated functional groupN H3CCH3 CH3O O CH3 many othersmany othersany imineany esterOOmany others many othersany etherany ketoneN O many othersH2
Michigan State University - CEM - 251
CEM 252 NMR-Session Problems 09-05-07Determine the structures of the molecules with the following spectra: 1. C6H13Cl632 1 14132 PPM1H NMR: 0.91 ppm (d, 6H); 1.49 ppm (t, 2H); 1.60 ppm (d, 3H); 1.62 ppm (m, 1H); 3.64 ppm (sextet, 1H
Michigan State University - CEM - 251
Michigan State University - CEM - 251
Name: _ Date: _FORM A1. The Z scheme is A) the characteristic path of electrons when both photosystems are utilized for the production of ATP and NADPH + H+. B) the characteristic path of electrons when only photosystem II is involved and only AT
Michigan State University - CEM - 251
Michigan State University - CEM - 251
Michigan State University - CEM - 251
Michigan State University - CEM - 251
Michigan State University - CEM - 251
Michigan State University - CEM - 251
Michigan State University - CEM - 251
Michigan State University - CEM - 251
Name: _ Date: _ Form A1. Structures that contain networks of keratin fibers and provide mechanical stability to epithelial tissues are called A) extracellular matrices. B) glycoproteins. C) gap junctions. D) desmosomes. E) phospholipid bilayers.2
Michigan State University - CEM - 251
Mean=68.8%A8060Frequency40200 40 50 60 70 80 90 100Percent37.5 42.5 47.5 52.5 57.5 62.5 67.5 72.5 77.5 82.5 87.5 92.5 97.52 13 15 29 51 68 80 90 81 44 24 11 02 15 30 59 110 178 258 348 429 473 497 508 5080.3937 2.95276 5.90551
Michigan State University - CEM - 251
I.The Role of Cell Division in Asexual/Sexual Life CyclesA. Asexual reproduction is based on mitotic division of the nucleus.It may be a unicellular organism reproducing itself, or: Cells of multicellular organisms that break off to form a new i
Michigan State University - CEM - 251
1FIANL EXAM CONFLICTFriday December 7th 3:00pm to 5:00pm at E100. Jessica Miller Brett Diffin Yelena Kleshchik Laura Van Putten * Kristina Rose * Dina Valeeva *Make-up exam: Thursday (Dec13th) 10:00am-noon2The Eukaryotic Genome and Its
Michigan State University - CEM - 251
Lecture NineteenReview of overall process The molecular structures in Translation III. Stages in Translation IV. Protein trafficking V. Replication Errors I. II.1I. Review: Overall process2II. The molecular structures in TranslationA. Messe
Michigan State University - CEM - 251
Photosythesis: Energy from sunlight Similar to the electron train transport system in mitochondria. Uses high energy electron to drive a electrochemical gradient and generates NADPH + H+ and ATP for biosynthesis1Plants take in CO2 and release O
Michigan State University - CEM - 251
Lecture twenty Chapter nineI. Basics of Cell Division II. The Cell Cycle (~preparation for cell division.sort of) III. DNA/proteins and Microtubules in Mitosis (nuclear division) IV. Phases in Mitoses1I. Cell DivisionFour events must occur for