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Course: CHEM 327, Fall 2009School: Rutgers
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EXAM I MATERIAL ExamI on Monday, October 4, will cover the material in Chapter 18: Sections 1-11, 16 and 17. You may ignore the &quot;derivation&quot; of the <a href="/keyword/heisenberg-uncertainty-principle/" ><a href="/keyword/heisenberg-uncertainty/" >heisenberg uncertainty</a> principle</a> on pages...
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EXAM I MATERIAL ExamI on Monday, October 4, will cover the material in Chapter 18: Sections 1-11, 16 and 17. You may ignore the "derivation" of the <a href="/keyword/heisenberg-uncertainty-principle/" ><a href="/keyword/heisenberg-uncertainty/" >heisenberg uncertainty</a> principle</a> on pages 605/606; the "derivation" involving the time-independent vs. time-dependent SE's on pages 612/613. You should know, however, what the <a href="/keyword/heisenberg-uncertainty-principle/" ><a href="/keyword/heisenberg-uncertainty/" >heisenberg uncertainty</a> principle</a> is, what "stationary states" are and why they are called "stationary" (eq. 18.25). From Section 16, you need to know (and be able to use) the properties of Hermitian operators....ignore proofs and the sub-section on "Complete Sets". The Exam will be offered during the regular Lecture period. Please, be prompt and bring a calculator....a calculator that works ....:-)
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Rutgers - CHEM - 327
PHYSICAL CHEMISTRY I, 01:160:327, SUMMER 2005 General InformationLecturerProfessor K. Krogh-Jespersen Office: Wright-Rieman Labs, Room A206; Phone: 732-445-4241 Office Hours: After Class or by Appointment (M-Th). E-mail: krogh@rutchem.rutgers.edu
Rutgers - CHEM - 327
PHYSICAL CHEMISTRY I, 01:160:327, SUMMER 2005 General InformationLecturerProfessor K. Krogh-Jespersen Office: Wright-Rieman Labs, Room A206; Phone: 732-445-4241 Office Hours: After Class or by Appointment (M-Th). E-mail: krogh@rutchem.rutgers.edu
Rutgers - CHEM - 327
Tentative "Grade Distribution" for EXAMII, Chem 327, Fall 2005 A course histogram of the scores on Exam II shows the following distribution: Score 100-90 89-80 79-70 69-60 59-50 49-40 Below 40 #Students 4 7 16 14 11 12 11Class Average was 63.Iff
Rutgers - CHEM - 327
Tentative "Grade Distribution" for EXAM II, Chem 327, Fall 2004A course histogram of the scores on Exam II shows the following distribution: Score 100-90 89-80 79-70 69-60 59-50 49-40 Below 40 #Students 7 19 19 17 9 8 8Class Average was 68; 88 stu
Rutgers - CHEM - 327
"Grade Distribution" for EXAM 1, Chem 327, Fall 2004 A histogram of the scores on Exam 1 shows the following distribution: Score 100-90 89-80 79-70 69-60 59-50 Below 50 #Students 26 18 20 12 9 6Class Average was 77. IFF I had to give grades based s
Campbell - MAIL - 1162
A taste of Campus LifeStudents will reside in Barker Hall apartments on the Campbell University campus in Buies Creek. Each student will have a private room with internet access. Meals are included in the tuition for the program. Banquets for partic
Rutgers - CHEM - 327
Lecture 11 Many-Electron Atoms, He in particularThe H-like atomic orbitals provide a complete description of the properties of the one electron present in an H-like atom: = (-2/2)2 - Ze2/(4o)r Hnm(r, , ) = Ennm(r, , ) nm(r,) = Rn(r)Ym(, ) = Rn(r)m(
Rutgers - CHEM - 327
Lecture 12z x x y xAxMA mexxq = -e xx x x x xrxx xxRxCBCxQB = +ZBeBorn-Oppenheimer ApproximationN = number of nuclei; each nucleus described by 3 geometrical variables (RN), a mass (MN), and a nuclear core charge
Rutgers - CHEM - 327
Lecture 12 (could also be labeled "wrap it up", "miscellaneous" or some such) But why is the ground state configuration for Li 1s22s1 and not 1s22p1? Shielding(screening) and Penetration H-like: R(r) = Rn,(r) ~ r exp(-Zr/na)[polynomial in r of power
Rutgers - CHEM - 327
Lecture 12Classical/Quantum View of Electromagnetic Radiation Interaction of light (absorption/emission/scattering) and matter. Information about energy levels of atoms, molecules, polymers, etc. Molecular structure: X-ray, NMR, rotational spectrosc
Rutgers - CHEM - 327
Lecture 1Classical Physics, pre ~1900: Kepler (~1500), Galileo (~1600), Newton (Father of Classical Mechanics, 1680's), Maxwell (Father of E&M Equations, 1860's). Electricity (Faraday, Volta, Ampere, Ohm -18th and 19th centuries) Basic Foundations o
Rutgers - CHEM - 327
Lecture 2.(2) Atomic and Molecular Spectra, Continued(ii) Atomic Line SpectraUV-Vis spectra of atoms consist of sharp, distinct lines (as opposed to continuous, broad absorption/emission). Atoms have characteristic spectra (H Li Na K.; very d
Rutgers - CHEM - 327
Lecture 2.(2) Photoelectric Effect (Hertz 1886) (a) No electrons are emitted from solid unless frequency () of incoming radiation exceeds a certain value (threshold frequency, o), even for high light intensities. o differs from metal to metal (2 - 7
Rutgers - CHEM - 327
Lecture 3Classical Mechanics vs Quantum Mechanics Classical Mechanics: Motion of macroscopic systems (particles), given forces acting on particles and a set of initial conditions (positions, velocities of all particles at t = t0); Newton's Laws (~16
Rutgers - CHEM - 327
Lecture 3Classical Mechanics vs Quantum Mechanics Classical Mechanics: Properties of macroscopic systems (particles); Newton's Laws (~1680). Quantum Mechanics: Properties of microscopic systems; Schroedinger Equation (1926). Quantum Chemistry = Quan
Rutgers - CHEM - 327
Lecture 5 Particle-in-a-BoxHamiltonian for a single particle of mass m: = K + V = (-2/2m) [2/x2 + 2/y2 + 2/z2] + V(x,y,z) In one dimension: = (-2/2m)2/x2 + V(x) = (-2/2m)d2/dx2 + V(x) Particle-in-a-box problem is defined by V(x) = constant = 0 for
Rutgers - CHEM - 327
Lecture 5 Particle-in-a-Box; (Engel Sect 4.2)Hamiltonian for a single particle of mass m: = K + V = (-2/2m) [2/x2 + 2/y2 + 2/z2] + V(x,y,z) In one dimension: = (-2/2m)2/x2 + V(x) = (-2/2m)d2/dx2 + V(x) Particle-in-a-box problem is defined by V(x)
Rutgers - CHEM - 327
Lecture 6 (Engel 3.4, 4.4)Eigenfunctions; Eigenvalues; Measurement Given a general QM operator , its normalized eigenfunctions and eigenvalues: n(x) = n n(x) n = 1,2,3,4,5,6,.Postulate 3: In any single measurement of the observable that correspon
Rutgers - CHEM - 327
Lecture 7Eigenfunctions; Eigenvalues; Measurement Given a general QM operator , its normalized eigenfunctions and eigenvalues: n = n n n = 1,2,3,4,5,6,.[ Levine: M = c ]Postulate III: When a single measurement of the property represented by t
Rutgers - CHEM - 327
Lecture 7If a wavefunction (x) is written as a superposition of wavefunctions n(x) [(x) = bnn(x) ] where the n(x) are normalized eigenfunctions of some operator with eigenvalues n [ n(x) = n n(x)], thenbn2 = 1 and < > = < a > = bn2n. bn2is the
Rutgers - CHEM - 327
Lecture 6 Two-Particle Rigid RotorTwo-Particle Motion Consider two particles with masses m1 and m2 and coordinates r1 = (x1,y1,z1) and r2 = (x2,y2,z2). The relative coordinates and velocities are defined by r = r2 - r1 x = x2 - x1 y = y2 - y1 z = z2
Rutgers - CHEM - 327
Recitation, Chem 327, Sept 01/02Possible Items for Discussion: 1. Electromagnetic spectrum (energy units) 2. Problem 18.1, parts a and b.R() = a3/[exp(b/T) - 1] a = 2h/c2 b = h/kBR() = a3/[exp(h/kBT) - 1] Find max, the frequency at which the ener
Rutgers - CHEM - 327
Recitation, Chem 327, Sept 28/29Brief discussion of Quiz I. Old Exam/Quiz problems we may look at:1. The total energy expression for the system known as the "one-dimensional harmonic oscillator" is in classical mechanics given by the expression E =
Rutgers - CHEM - 327
Recitation, Chem 327, Oct 5/6Quiz2 will cover the basic material from Lectures 3-6(incl.); that means Chapters 2-4 but no time-dependence and no 2D,3D boxes and no superposition of wavefunctions. The Quiz will be offered at the beginning of the reci
Rutgers - CHEM - 327
Radiation; Selection RulesClassical/Quantum View of Electromagnetic Radiation Interaction of light (absorption/emission/scattering) and matter. Information about energy levels of atoms, molecules, polymers, etc. Molecular structure: X-ray, NMR, rota
Rutgers - CHEM - 327
PHYSICAL CHEMISTRY I, 01:160:327, SUMMER 2005 SYLLABUSLect 1, 2 3,4 5,6 7,8 9,10 11,12 13,14 15,16 17,18 19,20 21,22 23 Date(s) Day(s) 5/31, 6/1 Tu, W 6/2, 6/6 Th, M 6/7, 6/8 Tu, W 6/9, 6/13 Th, M 6/14, 6/15 Tu, W 6/16, 6/20 Th, M 6/21, 6/22 Tu, W 6
Rutgers - CHEM - 327
PHYSICAL CHEMISTRY I, 01:160:327, FALL 2005SYLLABUS, WEEKS 1-7FacultyProfessor Karsten Krogh-Jespersen E-mail: krogh@rutchem.rutgers.edu Office: Wright-Rieman Labs, Room A206; Phone: 445-4241 Office Hours Mondays 11:45 AM and 8:00 PM, WR A206, BUS
Rutgers - CHEM - 327
Answers to Problems Assigned from Engel, Chapter 1P1.1: Plug in: max = hc/5kT = [6.626x10(-34)Js x 3x10(8)m/s]/[5 x 1.38x10(-23)J/K x T] = 2.88x10(-3)m K/T = 2.88x10(6) nm K/T = 6400 nm for T = 450 K; 1920 nm for T = 1500 K; and 640 nm for T = 4500
Rutgers - CHEM - 327
Answers to Chapter 4 Problems Assigned From Engel(continued)P4.16 n n ( x, y ) = N sinx yn y n x x sin y . a bN = (2/a)1/2(2/b)1/2 by "inspection". If the box is square, then a = b and N = (4/a2)1/2. Plug in and "simplify":2 h2 2 4 n x
Rutgers - CHEM - 327
Answers to Chapter 5 and 6 Problems Assigned From EngelP5.5Use the Boltzmann distribution expressionnconduction g conduction - E / kT and isolate T on one side. e = nvalence g valenceFor silicon, we obtain - E -1.12eV 1.602 10-19J/eV TSi = = = 9
Rutgers - CHEM - 327
Answers to Chapter 8 Problems Assigned From Engel(1)(tilde) = 2170 cm-1 In Hz: = 2170 cm-1 x 3.00x1010 cm/s = 6.5x1013 Hz T= 1 = 1.54 10-14s 6.51 1013s -1 1 1 6.241 1018eV E = h = 6.626 10-34 Js 6.51 1013s -1 = 2.16 10-20 J = 0.134eV 2 2
Rutgers - CHEM - 327
Hi, You are getting this e-mail, because you are registered for Chem 327, "Physical Chemistry I", for the Fall 2006 semester at RU. The text we will be using in the course is "Quantum Chemistry and Spectroscopy" by Thomas Engel. It is "purple/violet"
Rutgers - CHEM - 327
PHYSICAL CHEMISTRY I, 01-160:327, Fall 2006EXAM IANSWERS1. (5 pts) The work function for Cu metal is 4.80 eV. If a piece of Cu is bombarded by violet light ( = 4,000 ), will electrons be ejected? "YES" or "NO" with supporting argument/calculatio
Rutgers - CHEM - 327
PHYSICAL CHEMISTRY I, 01:160:327, FALL 2005 EXAM IAInstructions: This exam contains 9 pages (incl. cover) with questions; one blank page for scrap usage; and one page with useful information (formulas, conversion factors, integrals.). The latter tw
Rutgers - CHEM - 327
Lecture 3Classical Mechanics vs Quantum Mechanics Classical Mechanics: Properties of macroscopic systems (particles); Newton's Laws (~1680). Quantum Mechanics: Properties of microscopic systems; Schroedinger Equation (1926). Quantum Chemistry = Quan
Rutgers - CHEM - 327
Lecture 7If a wavefunction (x) is written as a superposition of wavefunctions n(x) [(x) = bnn(x) ], where the n(x) are normalized eigenfunctions of some operator with eigenvalues n [ n(x) = n n(x)], thenbn2 = 1 and < > = < a > = bn2n. bn2 is t
Rutgers - CHEM - 327
Lecture 8 Electronic Transitions in Polyenes All-trans polyenes: ethylene, butadiene, hexatriene, octatetraene. (retinal, 11 double bonds): En = n2h2/8ma2 n = 1,2,3,.Particle in a box model: 2 electrons per energy level (Pauli principle; one electr
Rutgers - CHEM - 327
Recitation, Chem 327, Sept 11/13Possible Items for Discussion: 1. Electromagnetic spectrum; energy units. 2. Problem P1.1: The distribution in wavelengths of the light emitted from a radiatingblackbody is a sensitive function of the temperature. Th
Rutgers - CHEM - 327
Recitation, Chem 327, Sept 18/20QuizI will cover the material in Chapter 1, Sections 1.1-1.5 and 1.7; that is, material covered in the first two lectures. The Quiz will be offered at the beginning of the Recitation Period and will last about 20 minu
Rutgers - CHEM - 327
Lecture 10Rotational Motion on a sphere (3D); Rigid Rotor Consider a particle of mass , now moving on the surface of a sphere of radius ro. (Let particle 1 be the coordinate origin, particle 2 is moving anglewise relative to 1, but their distance of
Rutgers - CHEM - 327
Lecture 11 Classical/Quantum View of Electromagnetic Radiation Interaction of light (absorption/emission/scattering) and matter. Information about energy levels of atoms, molecules, polymers, etc. Molecular structure: X-ray, NMR, rotational spectrosc
Rutgers - CHEM - 327
PHYSICAL CHEMISTRY I, 01:160:327, FALL 2006SYLLABUS, WEEKS 1-7FacultyProfessor Karsten Krogh-Jespersen E-mail: krogh@rutchem.rutgers.edu Office: Wright-Rieman Labs, Room A106; Phone: 445-4241 Office Hours: Monday 5:00 PM, Wednesday 8:00 PM, WR A10
Rutgers - CHEM - 327
PHYSICAL CHEMISTRY I, 01-160:327, SUMMER 2006 EXAM IVInstructions: This exam contains 8 pages (incl. cover) with questions; one blank page for scrap usage; and two pages with information likely to be useful (formulas, conversion factors, integrals.)
Rutgers - CHEM - 327
PHYSICAL CHEMISTRY I, 01:160:327, SUMMER 2008 General InformationLecturerProfessor Karsten Krogh-Jespersen Office: Wright-Rieman Labs, Room A106; Phone: 732-445-4241 Office Hours: After Class or by Appointment (M-Th). E-mail: krogh@rutchem.rutgers.
Rutgers - CHEM - 327
PHYSICAL CHEMISTRY I, 01:160:327, SUMMER 2007 SYLLABUSLect1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23Date/Day5/29, Tu 5/30, W 6/31, Th 6/4, M 6/5, Tu 6/6, W 6/7, Th 6/11, M 6/12, Tu 6/13, W 6/14, Th 6/18, M 6/19, Tu 6/20, W 6/21,
Rutgers - CHEM - 327
PHYSICAL CHEMISTRY I, 01:160:327, SUMMER 2008 SYLLABUSLect1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23Date/Day5/27, Tu 5/28, W 5/29, Th 6/2, M 6/3, Tu 6/4, W 6/5, Th 6/9, M 6/10, Tu 6/11, W 6/12, Th 6/16, M 6/17, Tu 6/18, W 6/19,
Campbell - MAIL - 364
Campbell - MAIL - 364
Campbell - MAIL - 364
Campbell - MAIL - 364
Campbell - MAIL - 364
PolicyLetter#10AttendanceATOEDNCCU 16JUN2006MEMORANDUMFORCAMPBELLBATTALIONCADREANDCADETSSUBJECT: PolicyLetter#10,Class,Lab,PhysicalTraining(P.T.),andFieldTrainingExercise(FTX) Attendance1. ClassattendancewillbeconductedataminimumIAWthecollegeo
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PolicyLetter#13CadetCounselingATOEDNCCU 16JUN2006MEMORANDUMFORCAMPBELLBATTALIONCADREANDCADETSSUBJECT: PolicyLetter#13,CadetCounseling1. Reference: CadetCommandPamphlet(CCP)1454.2. WeasleadersarechargedwithcertainveryspecificCadetcounselingre
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Campbell - MAIL - 984
The Teaching Fellows ProgramDr. Carolyn H. Maidon Director Program Approved Fall 2006 First Cohort Fall 2007Table of ContentsPage Teaching Fellows Program Program Overview Experiential Education Series Activities and Field Trips Cultural Experie
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CAMPBELL UNIVERSITY SCHOOL OF EDUCATION*GRADUATE SCHEDULE, SUMMER 2009*Summer Session I and II Tuesday May 26, 2009 Friday, July 31, 2009Education 641 Lifespan Development This class runs 10 weeks. This is a blended class format. Much of the clas
Rutgers - CHEM - 542
Special Topics in Physical Chemistry: Computational Chemistry.Course 16:160:542, Section 01. Index No: 49242Course also offered to Advanced Undergraduates as 01:160:438, Intro to Comp. Chem. Index No: 51444; Special Permission required. Time and Pl
Rutgers - CHEM - 542
Introduction to Computational ChemistryKarsten Krogh-Jespersen(krogh@rutchem.rutgers.edu) Department of Chemistry and Chemical Biology Rutgers, the State University of New Jersey New Brunswick, NJ 08903O H 3C N O N CH3CH3 NN. .Spring 2005
Rutgers - CHEM - 542
Intro to Computational Chemistry 01:160:438 and 16:160:542 Spring 2005FacultyProfessor Karsten Krogh-Jespersen E-mail: krogh@rutchem.rutgers.edu Office: Wright-Rieman Labs, Room A206; Phone: 732-445-4241 Office Hours: All day Thursdays, WR A206, BU
Campbell - MAIL - 1170
College for a Day, Success. for TomorrowDirections to Barker Residence Hall:From Lillington, US 421/NC27: Turn left on W. Leslie Campbell Memorial Avenue. Barker Residence Hall is the brick V-shaped building on your right. From Dunn, US 421/NC27:
Rutgers - CHEM - 327
EXAM 2 EXAM2 will be held Wednesday, June 15, 9:00 -10:15 AM. The EXAM Questions will be taken from the material covered in Chapter 18, Sections 6-14. You should know and be able to use what is in Section 18.16 up to "Complete Sets of Eigenfunctions