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Reaction mechanisms-02
Course: CHEM 220, Fall 2009School: Wisc Stevens Point
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Mechanisms Reaction 1) A reaction mechanism portrays a reaction in a series of simple steps called elementary processes or elementary steps. 2) A reaction mechanism must account for the experimentally determined overall rate law for the reaction. 3) A reaction mechanism must be consistent with the overall stoichiometry of the overall or net reaction. Elementary Steps 1) An elementary step in which a single...
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Mechanisms Reaction 1) A reaction mechanism portrays a reaction in a series of simple steps called elementary processes or elementary steps. 2) A reaction mechanism must account for the experimentally determined overall rate law for the reaction. 3) A reaction mechanism must be consistent with the overall stoichiometry of the overall or net reaction.
Elementary Steps 1) An elementary step in which a single molecule dissociates is called unimolecular. One in which two molecules must collide in an effective fashion is termed bimolecular, and three molecules colliding be would (improbable) called termolecular. 2) Elementary steps are reversible. 3) Species generated in one step and consumed in another are called intermediates. Intermediates are not (can not) be shown in the overall reaction. 4) One elementary step may be much slower than than the others. This is the crucial step in the reactio...
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