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685 Flammable Liquids 2003

Course: CHEMISTRY 685, Fall 2009
School: National Taiwan University
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Liquids Flammable Flammable Liquids and Fire Codes John Herrington Department of Chemistry Chemistry 685 Flammable Liquids Lecture for 30 minutes or so q Three Demonstrations q Chemistry 685 Flammable Liquids Hands-On Fire Extinguisher Training Thursday, March 11 q Meet in Room 1015 McPherson at 5:30 q Watch Fire Extinguisher Video q Turn in Quiz q Go to Evans/Celeste Loading Dock for hands-on...

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Liquids Flammable Flammable Liquids and Fire Codes John Herrington Department of Chemistry Chemistry 685 Flammable Liquids Lecture for 30 minutes or so q Three Demonstrations q Chemistry 685 Flammable Liquids Hands-On Fire Extinguisher Training Thursday, March 11 q Meet in Room 1015 McPherson at 5:30 q Watch Fire Extinguisher Video q Turn in Quiz q Go to Evans/Celeste Loading Dock for hands-on training...weather permitting. Dress appropriately! Chemistry 685 Flammable Liquids q q q Thursday, March 11 Check the Safety Page to make sure I have all of your quizzes We will also talk about the final exam (Tuesday, March 16 at 5:30 in this room). Also check the Safety Page for details on final exam (after Thursday's class). Quizzes need to be in by Thursday, March 18, at 4:00PM!!!!!!!!!!!!!!!!!!!! Chemistry 685 Flammable Liquids Properties of Flammable Liquids Invisible Vapor is the Main Concern! Chemistry 685 Flammable Liquids Properties of Flammable Liquids Definitions: FLASH POINT The temperature at which a liquid gives off sufficient vapors to form an ignitable mixture with air... near the surface of the liquid. Chemistry 685 Flammable Liquids Properties of Flammable Liquids Definitions: Ignition Temperature The minimum temperature required to initiate or cause selfsustained combustion without ignition from an external source. Also called auto ignition temp. Chemistry 685 Flammable Liquids Properties of Flammable Liquids Definitions: Upper and Lower Explosive Limits The range of concentration of a flammable gas or vapor (% volume in air) in which a explosion can occur upon ignition in a confined area. Chemistry 685 Flammable Liquids Compound Acetone Benzene CS2 FP(F) LEL(%) 0 2.6 12 1.5 22 1 3 3.6 2 0.5 4 75 100 36 3 UEL 13 8 50 19 Ethanol 55 Et. Oxide 0 Ether 49 Octane 60 Hydrogen Chemistry 685 Flammable Liquids Compound Ignition Vapor Temp Density Chemistry 685 Vapor Press. Acetone Benzene CS2 1000F 2 240 mm 1044 2.77 100 212 2.64 400 1.59 40 2.56 442 3.86 10 Ethanol 793 Ether 356 Octane 428 Hydrogen 1075 0.069 Flammable Liquids The Phenomenon of Fire Energy Source Fuel Chain Reaction Oxygen or Oxidizer Chemistry 685 Flammable Liquids Fire Codes Who Regulates Flammables? State Fire Marshal (NFPA, OBBC, and Ohio Fire Code) q OSHA (Occupational Safety) q DOT (Transportation) q EPA (Flammable Waste) q Chemistry 685 Flammable Liquids Fire CodesNFPA q Flammable liquids have a flash point of less than 100F Combustible liquids have a flash point of 100F or greater q Chemistry 685 Flammable Liquids Fire CodesNFPA Flammable Liquid Classification Class IA FP<73F, BP<100F Class IB FP<73F, BP>100F Class IC 73F <FP< 100F Class II 100F <FP< 140F Class IIIa 140F <FP< Class 200F IIIb FP> 200F Chemistry 685 Flammable Liquids Fire CodesNFPA Flammable Liquid Classification Common Class IA Solvents Acetaldehyde v Ethyl Ether v Ethylene Oxide v Pentane v Chemistry 685 Flammable Liquids Fire CodesNFPA Flammable Liquid Classification Common Class IB Solvents Acetone Acetonitrile Benzene Cyclohexane THF Ethyl Acetate Ethanol Gasoline Hexane Methanol MEK Pyridine Toluene Carbon Disulfide Chemistry 685 Flammable Liquids Fire CodesNFPA Flammable Liquid Classification Common Class IC Solvents Cumene Propanol Xylene Chemistry 685 Hydrazine Styrene Flammable Liquids Fire CodesNFPA Flammable Liquid Classification Common Class II Solvents Acetic Acid q Decalin q N,NDimethylformamide q Chemistry 685 Flammable Liquids Fire CodesNFPA Flammable Liquid Classification Common Class III Solvents Aniline q Phenol q Cresol q Chemistry 685 Flammable Liquids Fire CodesNFPA Flammable Liquid Storage Not more than 10 Gallons of Class I and II liquids outside of a storage cabinet q Not more than 25 Gallons if stored in Safety Cans q Chemistry 685 Flammable Liquids Fire CodesNFPA Flammable Liquid Storage Safety Cabinets Chemistry 685 Flammable Liquids Proper Flammable Liquid Storage Chemistry 685 Flammable Liquids Chemistry 685 Proper Flammable Liquid Storage Flammable Liquids Chemistry 685 Proper Flammable Liquid Storage Flammable Liquids Chemistry 685 Proper Flammable Liquid Storage Flammable Liquids Improper Flammable Liquid Storage Chemistry 685 Flammable Liquids Chemistry 685 Improper Flammable Liquid Storage Flammable Liquids Improper Flammable Liquid Storage Ch...

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