Chem 116 Exam 1 07
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Chem 116 Exam 1 07

Course Number: CHM 116, Fall 2008

College/University: Purdue

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1 Test 11 Name _________________________ Section ____________ TA ___________________________ Chemistry 116-C EXAM I Thursday, 7:00 PM February 8, 2007 1 THIS EXAM IS FOR STUDENTS WITH MONDAY-WEDNESDAY 10:30 LECTURE. YOU SHOULD HAVE AN ORANGE COMPUTER ANSWER SHEET! Total Points = 150 Directions: 1. 2. 3. 4. 5. 16. 7. 8. Each student is responsible for following directions. Read this page carefully. Write your...

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11 Name 1 Test _________________________ Section ____________ TA ___________________________ Chemistry 116-C EXAM I Thursday, 7:00 PM February 8, 2007 1 THIS EXAM IS FOR STUDENTS WITH MONDAY-WEDNESDAY 10:30 LECTURE. YOU SHOULD HAVE AN ORANGE COMPUTER ANSWER SHEET! Total Points = 150 Directions: 1. 2. 3. 4. 5. 16. 7. 8. Each student is responsible for following directions. Read this page carefully. Write your name and other requested information on this page and on the separate answer sheet. CODE your name on the answer sheet using an ordinary (#2) pencil. CODE your correct 10-digit identification number (PUID) on the answer sheet. THIS IS VERY IMPORTANT! CODE your section number on the answer sheet. Please use all four digits, 0101, 0102, 0201, etc. This is also very important! CODE the test number shown in the upper right-hand corner on the answer sheet in the block labeled "Test/Quiz Number". This is Test 11. Put all calculations on the examination pages. DO NOT PUT ANY EXTRA MARKS ON THE COMPUTER ANSWER SHEET! This exam consists of 20 multiple-choice questions worth 7.5 points each. Choose the one best or correct answer for each question and write it both on your exam paper and on the computer answer sheet. The computer answer sheet is the only one that will be graded! This exam consists of 8 pages plus a Periodic Table and a page of Useful Information. Please check to be sure that you have them all! 9. 1END OF EXAM 1) Please make sure that you have entered 20 answers on your scan sheet. 2) Make sure that you have entered your name, ID number, and lab section number (4 digits). 3) You MUST turn the scan sheet in to your TA before leaving the exam! Chem 116-C Exam 1 (Test 11) 2/08/07 _____ 1. Consider the following reaction at 25oC, (CH3)3COH(aq) + HCl(aq) (CH3)3CCl(aq) + H2O(aq) 2 The experimentally determined rate law for this reaction indicates that the reaction is first-order in (CH3)3COH and that the reaction is first-order overall. Which of the following would produce an increase in the rate of this reaction? (a) (b) (c) (d) (e) _____ 2. increasing the concentration of (CH3)3COH increasing the concentration of HCl decreasing the concentration of HCl decreasing the concentration of (CH3)3CCl It is impossible to tell. Enzymes lower the activation energy of a reaction by: (a) (b) (c) (d) (e) orienting the substrate correctly. putting the substrate near important functional groups in the enzyme. stabilizing the transition state. All of the above None of the above _____ 3. 100 mL of 0.113 M NaNO3 is diluted to 175 mL. What is the concentration of NaNO3 in the diluted solution? (a) (b) (c) (d) (e) 0.101 M 0.139 M 0.0523 M 0.134 M 0.0646 M _____ 4. When the following reaction is correctly balanced, how many kilograms of O2 are required to react completely with 4.9 moles of C6H14? C6H14 + O2 CO2 + H2O (a) (b) (c) (d) (e) _____ 5. 0.55 kg 4.9 kg 1.3 kg 0.94 kg 1.5 kg A change in temperature has a significant effect on the value of the: (a) (b) (c) (d) (e) rate constant. activation energy. orientation probability factor. All of the above. None of the above. Chem 116-C Exam 1 (Test 11) 2/8/07 3 _____ 6. Which equation (as written left to right) represents the oxidation of an organic compound? (a) (b) (c) (d) (e) 3 CH3CH2OH + 2Cr6+ 3 CH3CHO + 6 H+ + 2 Cr3+ CH2=CH2 + H2 CH3CH3 CH3-COOH CH3COO- + H+ 2 NaCl(s) + H2SO4() 2 HCl(aq) + Na2SO4(aq) None of the above _____ 7. The following reaction is a/an: (a) (b) (c) (d) _____ 8. elimination reaction. substitution reaction. addition reaction. None of the above. Which of the following statements about chemical kinetics is correct? (a) (b) (c) (d) (e) At constant temperature, the reaction rate for first-order reactions does not change with time after the start of the reaction (t=0). A catalyst increases the rate of a reaction by decreasing the activation energy. For all reactions, the rate law for a reaction involves concentrations of reactants raised to exponents equal to the coefficients of those species in the balanced chemical equation. At constant temperature, the value of the rate constant (k) of a given reaction depends on the initial concentrations of reactants. None of the above statements (A-D) is correct. Chem 116-C Exam 1 (Test 11) 2/8/07 4 _____ 9. Consider the following 2-step mechanism for ozone (O3) destruction by Cl atoms from the decomposition of man-made chlorofluorocarbons. The overall reaction is: O3(g) + O(g) 2 O2(g) Step 1: O3(g) + Cl(g) ClO(g) + O2(g) Step 2: ClO(g) + O(g) Cl(g) + O2(g) In this reaction: (a) (b) (c) (d) (e) _____ 10. Cl is a catalyst and O is an intermediate. ClO is a catalyst and O2 is an intermediate. Cl is a catalyst and ClO is an intermediate. O3 is a catalyst and ClO is an intermediate. ClO is a catalyst and Cl is an intermediate. Given the following initial rate data, determine rate the law for the reaction: CO(g) + Cl2(g) Run 1 2 3 4 5 The rate law is: (a) (b) (c) (d) (e) Rate = k[CO]2 Rate = k[Cl2]2 Rate = k[Cl2] [CO] Rate = k[Cl2]2 [CO] Rate = k[Cl2]2 [CO]2 [CO] (mol/L) 1.00 x 102 2.00 x 102 3.00 x 102 1.00 x 102 2.00 x 102 COCl(g) + Cl(g) [Cl2] (mol/L) 1.00 x 102 1.00 x 102 1.00 x 102 2.00 x 102 3.00 x 102 Rate (mol/Ls) 6.60 x 103 1.32 x 104 1.98 x 104 2.64 x 104 1.19 x 105 Chem 116-C Exam 1 (Test 11) 2/8/07 5 _____ 11. Nitric oxide gas reacts with chlorine gas according to the equation: 2 NO(g) + Cl2(g) 2 NOCl(g) The following data were obtained for this reaction: initial [NO] 0.50 M 1.00 1.00 1.50 initial [Cl2] 0.50 M 0.50 1.00 1.50 initial rate 1.19 mol/L h 4.79 9.59 32.27 The value of the rate constant for the reaction of NO with Cl2 is: (a) (b) (c) (d) (e) _____ 12. 2.38 3.35 4.79 9.59 19.0 For the chemical reaction 2 NO2(g) 2 NO (g) + O2(g), a plot of [NO2] vs. time gives a curved line, a plot of 1/[NO2] gives a straight line with a positive slope, and a plot of ln[NO2] vs. time gives a curved line. What is the order of reaction? (a) (b) (c) (d) (e) Zero order. First order. Second order. A fractional order. Impossible to determine from these data. _____ 13. Consider the following reaction: 2 NOBr(g) 2 NO(g) + Br2(g) The reaction is known to be second order with k = 0.80 L/mol s. If you start with a concentration of 0.086 mol/L of NOBr, what will be its concentration after 22 seconds? (a) (b) (c) (d) (e) 2.0 x 10-9 mol/L 5.4 x 10-2 mol/L 3.4 x 10-2 mol/L 1.7 x 10-1 mol/L 8.7 x 10-1 mol/L Chem 116-C Exam 1 (Test 11) 2/8/07 6 _____ 14. The radioactive element, thallium-201, is used medicinally as a radiotracer to study damage in heart tissue. If a patient is injected with a 0.950 g dose of pure thallium-201, calculate the amount of thallium-201 that would be left after 310 hours. Thallium-201 decays by a firstorder process with a half-life, t1/2 = 73.0 hours. (a) (b) (c) (d) (e) 0.050 g 0.28 g 0.50 g 0.028 g None of the above _____ 15. Chlorine, Cl2, reacts with hydrogen sulfide, H2S, in aqueous solution to produce solid sulfur and hydrogen chloride, HCl: Cl2(aq) + H2S(aq) S(s) + 2 HCl(aq) The rate law for this reaction is found to be: Rate = k[Cl2][H2S]. Which of the following is an acceptable possibility for the mechanism of this reaction? (a) Cl2 Cl+ + Cl- Cl- + H2S HCl + HS- Cl+ + HS- HCl + S (b) Cl2 + H2S HCl + Cl+ + HS- Cl+ + HS- HCl + S (c) (d) _____ 16. slow fast fast slow fast Both of these mechanisms are acceptable possibilities. Neither of these mechanisms are acceptable possibilities. Which of the following is a characteristic of catalysts? (a) (b) (c) (d) (e) They generally increase the activation energy. They are consumed by the reaction. They cannot be used repeatedly. They are permanently changed during the reaction. None of these are characteristics of catalysts. Chem 116-C Exam 1 (Test 11) 2/8/07 7 _____ 17. With respect to the figure below, which choice correctly identifies all of the numbered positions? #1 (a) (b) (c) (d) (e) catalyst reactants reactants reactants reactants #2 transition state intermediate transition state intermediate intermediate #3 intermediate transition state intermediate transition state transition state #4 product product product product catalyst #5 endothermic exothermic endothermic endothermic exothermic _____ 18. Commercial, topical solutions of hydrogen peroxide (H2O2, MW = 34 g/mol) are used for disinfecting wounds because H2O2 is a good oxidizing agent (which kills bacteria). What is the molarity of such a solution if it contains 3.0% by mass of H2O2 in water? The density of the solution is 1.00 g/mL. (a) (b) (c) (d) (e) 0.088 M 0.30 M 0.88 M 1.0 M 1.3 M _____ 19. The following structure contains three circled functional groups. What are these groups? Chem 116-C Exam 1 (Test 11) 2/8/07 (a) (b) (c) (d) (e) ketone, amide, carboxylic acid alcohol, amine, carboxylic acid aldehyde, ketone, ester carboxylic acid, alcohol, aldehyde alcohol, amine, ester 8 _____ 20. The rate of the reaction: S2- + 4 Cl2 + 8 OH- 8 Cl- + SO42- + 4 H2O is measured at a particular moment in time and it is found that -[S2-]/t = 2.0 x 10-2 mol L-1 s-1. At this same moment in time, what is the rate (in mol L-1 s-1) at which Cl- is being formed? (a) (b) (c) (d) (e) 1.0 x 10-2 2.5 x 10-3 2.0 x 10-2 1.6 x 10-1 Unable to determine from the information provided Chem 116-C Exam 1 (Test 11) 2/8/07 1Potentially Useful Information R = 0.08206 L-atm/mol-K R = 8.3145 J/mol-Kelvin 1 atm = 760 torr ln(xn) = n ln(x) ln x ! ln y = ln(x/y) k = AeEa/RT ln k = 9 ! Ea/RT + ln A Rate = ! (1/a)d[A]/dt = ! (1/b)d[B]/dt For aA + bB products, [A] = ! kt +[A]o 1/[A] = kt + 1/[A]o ln[A] = ! kt + ln[A]o t = 0.693/k t = [A]o/2k t = 1/[A]ok [A] ! [A]0 = -kt ln [A]/[A]0 = -kt 1/[A] - 1/[A]0 = kt -d[A]/dt = k[A]n[B]m[C]p...

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