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Chapter1_2010

Course: SCE 5201, Spring 2010
School: Carleton University
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1 Chapter Introduction A note on the use of these ppt slides: Were making these slides freely available to all (faculty, students, readers). Theyre in PowerPoint form so you can add, modify, and delete slides (including this one) and slide content to suit your needs. They obviously represent a lot of work on our part. In return for use, we only ask the following: If you use these slides (e.g., in a class) in...

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1 Chapter Introduction A note on the use of these ppt slides: Were making these slides freely available to all (faculty, students, readers). Theyre in PowerPoint form so you can add, modify, and delete slides (including this one) and slide content to suit your needs. They obviously represent a lot of work on our part. In return for use, we only ask the following: If you use these slides (e.g., in a class) in substantially unaltered form, that you mention their source (after all, wed like people to use our book!) If you post any slides in substantially unaltered form on a www site, that you note that they are adapted from (or perhaps identical to) our slides, and note our copyright of this material. Thanks and enjoy! JFK/KWR All material copyright 1996-2009 J.F Kurose and K.W. Ross, All Rights Reserved 5th edition. Jim Kurose, Keith Ross Addison-Wesley, April 2009. Computer Networking: A Top Down Approach , Introduction 1-1 Chapter 1: Introduction Our goal: get feel and terminology more depth, detail later in course approach: use Internet as example Overview: whats the Internet? whats a protocol? network edge; hosts, access net, physical media network core: packet/circuit switching, Internet structure performance: loss, delay, throughput protocol layers, service models Introduction 1-2 Chapter 1: roadmap 1.1 What is the Internet? 1.2 Network edge end systems, access networks, links 1.3 Network core circuit switching, packet switching, network structure 1.4 Delay, loss and throughput in packet-switched networks 1.5 Protocol layers, service models Introduction 1-3 Whats the Internet: nuts and bolts view PC server wireless laptop cellular handheld hosts = end systems running network apps communication links millions of connected computing devices: Mobile network Global ISP Home network Regional ISP access points wired links router fiber, copper, radio, satellite transmission rate = bandwidth routers: forward packets (chunks of data) Institutional network Introduction 1-4 Cool internet appliances Web-enabled toaster + weather forecaster IP picture frame http://www.ceiva.com/ Worlds smallest web server http://www-ccs.cs.umass.edu/~shri/iPic.html Internet phones Introduction 1-5 Whats the Internet: nuts and bolts view protocols control sending, receiving of msgs Mobile network Global ISP e.g., TCP, IP, HTTP, Skype, Ethernet RFC: Request for comments IETF: Internet Engineering Task Force Internet standards Home network Regional ISP networks Internet: network of loosely hierarchical public Internet versus private intranet Institutional network Introduction 1-6 Whats the Internet: a service view communication distributed applications: Web, VoIP, email, games, e-commerce, file sharing communication services provided to apps: reliable data delivery from source to destination best effort (unreliable) data delivery Introduction 1-7 infrastructure enables Whats a protocol? a human protocol and a computer network protocol: Hi Hi Got the time? TCP connection request TCP connection response Get http://www.awl.com/kurose-ross 2:00 time Q: Other human protocols? <file> Introduction 1-8 Whats a protocol? human protocols: whats the time? I have a question introductions specific msgs sent specific actions taken when msgs received, or other events network protocols: machines rather than humans all communication activity in Internet governed by protocols protocols define format, order of msgs sent and received among network entities, and actions taken on msg transmission, receipt Introduction 1-9 Chapter 1: roadmap 1.1 What is the Internet? 1.2 Network edge end systems, access networks, links 1.3 Network core circuit switching, packet switching, network structure 1.4 Delay, loss and throughput in packet-switched networks 1.5 Protocol layers, service models Introduction 1-10 A closer look at network structure: network edge: applications and hosts access networks, physical media: wired, wireless communication links network core: interconnected routers network of networks Introduction 1-11 The network edge: end systems (hosts): client/server model run application programs e.g. Web, email at edge of network peer-peer peer-peer model: client host requests, receives service from always-on server client/server e.g. Web browser/server; email client/server minimal (or no) use of dedicated servers e.g. Skype, BitTorrent Introduction 1-12 Access networks and physical media Q: How to connect end systems to edge router? residential access nets institutional access networks (school, company) mobile access networks Keep in mind: bandwidth (bits per second) of access network? shared or dedicated? Introduction 1-13 Dial-up Modem central office telephone network Internet home PC home dial-up modem ISP modem (e.g., AOL) Uses existing telephony infrastructure Home is connected to central office up to 56Kbps direct access to router (often less) Cant surf and phone at same time: not always on Digital Subscriber Line (DSL) home phone Existing phone line: 0-4KHz phone; 4-50KHz upstream data; 50KHz-1MHz downstream data Internet DSLAM splitter DSL modem home PC central office telephone network Also uses existing telephone infrastruture up to 1 Mbps upstream (today typically < 256 kbps) up to 8 Mbps downstream (today typically < 1 Mbps) dedicated physical line to telephone central office Residential access: cable modems Does not use telephone infrastructure Instead uses cable TV infrastructure HFC: hybrid fiber coax asymmetric: up to 30Mbps downstream, 2 Mbps upstream network of cable and fiber attaches homes to ISP router homes share access to router unlike DSL, which has dedicated access Introduction 1-16 Residential access: cable modems Diagram: http://www.cabledatacomnews.com/cmic/diagram.html Introduction 1-17 Cable Network Architecture: Overview Typically 500 to 5,000 homes cable headend cable distribution network (simplified) home Introduction 1-18 Cable Network Architecture: Overview server(s) cable headend cable distribution network home Introduction 1-19 Cable Network Architecture: Overview cable headend cable distribution network (simplified) home Introduction 1-20 Cable Network Architecture: Overview FDM (more shortly): V I D E O 1 V I D E O 2 V I D E O 3 V I D E O 4 V I D E O 5 V I D E O 6 D A T A 7 D A T A 8 C O N T R O L 9 Channels cable headend cable distribution network home Introduction 1-21 Fiber to the Home ONT Internet optical fiber optical fibers ONT OLT central office optical splitter ONT Optical links from central office to the home Two competing optical technologies: Passive Optical network (PON) Active Optical Network (AON) Much higher Internet rates; fiber also carries television and phone services Ethernet Internet access 100 Mbps Ethernet switch 100 Mbps Institutional router To Institutions ISP 1 Gbps 100 Mbps Typically used in companies, universities, etc 10 Mbs, 100Mbps, 1Gbps, 10Gbps Ethernet Today, end systems typically connect into Ethernet switch server Wireless access networks shared wireless access network connects end system to router via base station aka access point 802.11b/g (WiFi): 11 or 54 Mbps provided by telco operator ~1Mbps over cellular system (EVDO, HSDPA) next up (?): WiMAX (10s Mbps) over wide area router base station wireless LANs: wider-area wireless access mobile hosts Introduction 1-24 Home networks Typical home network components: DSL or cable modem router/firewall/NAT Ethernet wireless access point to/from cable headend cable modem router/ firewall Ethernet wireless laptops wireless access point Introduction 1-25 Physical Media Bit: propagates between transmitter/rcvr pairs physical link: what lies between transmitter & receiver guided media: Twisted Pair (TP) two insulated copper wires signals propagate in solid media: copper, fiber, coax signals propagate freely, e.g., radio Category 3: traditional phone wires, 10 Mbps Ethernet Category 5: 100Mbps Ethernet unguided media: Introduction 1-26 Physical Media: coax, fiber Coaxial cable: Fiber optic cable: glass fiber carrying light pulses, each pulse a bit high-speed operation: two concentric copper conductors bidirectional baseband: broadband: single channel on cable legacy Ethernet multiple channels on cable HFC high-speed point-to-point transmission (e.g., 10s100s Gps) low error rate: repeaters spaced far apart ; immune to electromagnetic noise Introduction 1-27 Physical media: radio signal carried in electromagnetic spectrum no physical wire bidirectional propagation environment effects: Radio link types: terrestrial microwave e.g. up to 45 Mbps channels 11Mbps, 54 Mbps 3G cellular: ~ 1 Mbps Kbps to 45Mbps channel (or multiple smaller channels) 270 msec end-end delay geosynchronous versus low altitude Introduction 1-28 LAN (e.g., Wifi) wide-area (e.g., cellular) reflection obstruction by objects interference satellite Chapter 1: roadmap 1.1 What is the Internet? 1.2 Network edge end systems, access networks, links 1.3 Network core circuit switching, packet switching, network structure 1.4 Delay, loss and throughput in packet-switched networks 1.5 Protocol layers, service models Introduction 1-29 The Network Core mesh of interconnected routers the fundamental question: how is data transferred through net? circuit switching: dedicated circuit per call: telephone net packet-switching: data sent thru net in discrete chunks Introduction 1-30 Network Core: Circuit Switching End-end resources reserved for call link bandwidth, switch capacity dedicated resources: no sharing circuit-like (guaranteed) performance call setup required Introduction 1-31 Network Core: Circuit Switching network resources (e.g., bandwidth) divided into pieces pieces allocated to calls resource piece idle if not used by owning call dividing link bandwidth into pieces frequency division time division (no sharing) Introduction 1-32 Circuit Switching: FDM and TDM Example: FDM 4 users frequency time TDM frequency time Introduction 1-33 Numerical example How long does it take to send a file of 640,000 bits from host A to host B over a circuit-switched network? All links are 1.536 Mbps Each link uses TDM with 24 slots/sec 500 msec to establish end-to-end circuit Lets work it out! Introduction 1-34 Network Core: Packet Switching each end-end data stream divided into packets user A, B packets share network resources each packet uses full link bandwidth resources used as needed Bandwidth division into pieces Dedicated allocation Resource reservation resource contention: aggregate resource demand can exceed amount available congestion: packets queue, wait for link use store and forward: packets move one hop at a time Node receives complete packet before forwarding Introduction 1-35 Packet Switching: Statistical Multiplexing A B 100 Mb/s Ethernet statistical multiplexing 1.5 Mb/s C queue of packets waiting for output link D E Sequence of A & B packets does not have fixed pattern, bandwidth shared on demand statistical multiplexing. TDM: each host gets same slot in revolving TDM frame. Introduction 1-36 Packet-switching: store-and-forward L R R R takes L/R seconds to transmit (push out) packet of L bits on to link at R bps entire packet must arrive at router before it can transmitted be on next link delay = 3L/R (assuming zero propagation delay) store and forward: Example: L = 7.5 Mbits R = 1.5 Mbps transmission delay = 15 sec more on delay shortly Introduction 1-37 Packet switching versus circuit switching Packet switching allows more users to use network! 1 Mb/s link each user: 100 kb/s when active active 10% of time circuit-switching: N users 1 Mbps link packet switching: 10 users with 35 users, probability > 10 active at same time is less than .0004 Q: how did we get value 0.0004? Introduction 1-38 Packet switching versus circuit switching Is packet switching a slam dunk winner? great for bursty data resource sharing simpler, no call setup excessive congestion: packet delay and loss protocols needed for reliable data transfer, congestion control Q: How to provide circuit-like behavior? bandwidth guarantees needed for audio/video apps still an unsolved problem (chapter 7) Q: human analogies of reserved resources (circuit switching) versus on-demand allocation (packet-switching)? Introduction 1-39 Internet structure: network of networks roughly hierarchical at center: tier-1 ISPs (e.g., Verizon, Sprint, AT&T, Cable and Wireless), national/international coverage treat each other as equals Tier-1 providers interconnect (peer) privately Tier 1 ISP Tier 1 ISP Tier 1 ISP Introduction 1-40 Tier-1 ISP: e.g., Sprint POP: point-of-presence to/from backbone peering . to/from customers Introduction 1-41 Internet structure: network of networks Tier-2 ISPs: smaller (often regional) ISPs Connect to one or more tier-1 ISPs, possibly other tier-2 ISPs Tier-2 ISP pays tier-1 ISP for connectivity to rest of Internet tier-2 ISP is customer of tier-1 provider Tier-2 ISP Tier-2 ISP Tier 1 ISP Tier 1 ISP Tier-2 ISP Tier-2 ISPs also peer privately with each other. Tier 1 ISP Tier-2 ISP Tier-2 ISP Introduction 1-42 Internet structure: network of networks Tier-3 ISPs and local ISPs last hop (access) network (closest to end systems) local ISP Tier 3 ISP Tier-2 ISP local ISP Local and tier3 ISPs are customers of higher tier ISPs connecting them to rest of Internet local ISP local ISP Tier-2 ISP Tier 1 ISP Tier 1 ISP Tier-2 ISP local ISP Tier 1 ISP Tier-2 ISP local ISP Introduction 1-43 Tier-2 ISP local local ISP ISP Internet structure: network of networks a packet passes through many networks! local ISP Tier 3 ISP Tier-2 ISP local ISP local ISP Tier-2 ISP local ISP Tier 1 ISP Tier 1 ISP Tier-2 ISP local ISP Tier 1 ISP Tier-2 ISP local local ISP ISP Tier-2 ISP local ISP Introduction 1-44 Chapter 1: roadmap 1.1 What is the Internet? 1.2 Network edge end systems, access networks, links 1.3 Network core circuit switching, packet switching, network structure 1.4 Delay, loss and throughput in packet-switched networks 1.5 Protocol layers, service models Introduction 1-45 How do loss and delay occur? packets queue in router buffers packet arrival rate to link exceeds output link capacity packets queue, wait for turn packet being transmitted (delay) A B packets queueing (delay) free (available) buffers: arriving packets dropped (loss) if no free buffers Introduction 1-46 Four sources of packet delay 1. nodal processing: 2. queueing check bit errors determine output link time waiting at output link for transmission depends on congestion level of router A B transmission propagation nodal processing queueing Introduction 1-47 Delay in packet-switched networks 3. Transmission delay: R=link bandwidth (bps) L=packet length (bits) time to send bits into link = L/R 4. Propagation delay: d = length of physical link s = propagation speed in medium (~2x108 m/sec) propagation delay = d/s Note: s and R are very different quantities! propagation A B transmission nodal processing queueing Introduction 1-48 Caravan analogy 100 km ten-car caravan toll booth toll booth 100 km cars propagate at 100 km/hr toll booth takes 12 sec to service car (transmission time) car~bit; caravan ~ packet Q: How long until caravan is lined up before 2nd toll booth? Time to push entire caravan through toll booth onto highway = 12*10 = 120 sec Time for last car to propagate from 1st to 2nd toll both: 100km/(100km/hr)= 1 hr A: 62 minutes Introduction 1-49 Caravan analogy (more) 100 km ten-car caravan toll booth toll booth 100 km Cars now propagate at 1000 km/hr Toll booth now takes 1 min to service a car Q: Will cars arrive to 2nd booth before all cars serviced at 1st booth? Yes! After 7 min, 1st car at 2nd booth and 3 cars still at 1st booth. 1st bit of packet can arrive at 2nd router before packet is fully transmitted at 1st router! See Ethernet applet at AWL Web site Introduction 1-50 Nodal delay d nodal d proc d queue d trans d prop dproc = processing delay typically a few microsecs or less depends on congestion = L/R, significant for low-speed links a few microsecs to hundreds of msecs dqueue = queuing delay dtrans = transmission delay dprop = propagation delay Introduction 1-51 Queueing delay (revisited) R=link bandwidth (bps) L=packet length (bits) a=average packet arrival rate traffic intensity = La/R La/R ~ 0: average queueing delay small La/R -> 1: delays become large La/R > 1: more work arriving than can be serviced, average delay infinite! Introduction 1-52 Real Internet delays and routes What do real Internet delay & loss look like? Traceroute program: provides delay measurement from source to router along end-end Internet path towards destination. For all i: sends three packets that will reach router i on path towards destination router i will return packets to sender sender times interval between transmission and reply. 3 probes 3 probes 3 probes Introduction 1-53 Real Internet delays and routes traceroute: gaia.cs.umass.edu to www.eurecom.fr Three delay measurements from gaia.cs.umass.edu to cs-gw.cs.umass.edu 1 cs-gw (128.119.240.254) 1 ms 1 ms 2 ms 2 border1-rt-fa5-1-0.gw.umass.edu (128.119.3.145) 1 ms 1 ms 2 ms 3 cht-vbns.gw.umass.edu (128.119.3.130) 6 ms 5 ms 5 ms 4 jn1-at1-0-0-19.wor.vbns.net (204.147.132.129) 16 ms 11 ms 13 ms 5 jn1-so7-0-0-0.wae.vbns.net (204.147.136.136) 21 ms 18 ms 18 ms 6 abilene-vbns.abilene.ucaid.edu (198.32.11.9) 22 ms 18 ms 22 ms 7 nycm-wash.abilene.ucaid.edu (198.32.8.46) 22 ms 22 ms 22 ms trans-oceanic 8 62.40.103.253 (62.40.103.253) 104 ms 109 ms 106 ms link 9 de2-1.de1.de.geant.net (62.40.96.129) 109 ms 102 ms 104 ms 10 de.fr1.fr.geant.net (62.40.96.50) 113 ms 121 ms 114 ms 11 renater-gw.fr1.fr.geant.net (62.40.103.54) 112 ms 114 ms 112 ms 12 nio-n2.cssi.renater.fr (193.51.206.13) 111 ms 114 ms 116 ms 13 nice.cssi.renater.fr (195.220.98.102) 123 ms 125 ms 124 ms 14 r3t2-nice.cssi.renater.fr (195.220.98.110) 126 ms 126 ms 124 ms 15 eurecom-valbonne.r3t2.ft.net (193.48.50.54) 135 ms 128 ms 133 ms 16 194.214.211.25 (194.214.211.25) 126 ms 128 ms 126 ms 17 * * * * means no response (probe lost, router not replying) 18 * * * 19 fantasia.eurecom.fr (193.55.113.142) 132 ms 128 ms 136 ms Introduction 1-54 Packet loss queue (aka buffer) preceding link in buffer has finite capacity packet arriving to full queue dropped (aka lost) lost packet may be retransmitted by previous node, by source end system, or not at all A B buffer (waiting area) packet being transmitted packet arriving to full buffer is lost Introduction 1-55 Throughput throughput: rate (bits/time unit) at which bits transferred between sender/receiver instantaneous: rate at given point in time average: rate over longer period of time link capacity server, with server sends bits pipe that can carry Rs bits/sec fluid at rate file into pipe (fluid) of F bits Rs bits/sec) to send to client link capacity pipe that can carry Rfluid at rate c bits/sec Rc bits/sec) Introduction 1-56 Throughput (more) Rs < Rc What is average end-end throughput? Rs bits/sec Rc bits/sec Rs > Rc What is average end-end throughput? Rs bits/sec Rc bits/sec bottleneck link link on end-end path that constrains end-end throughput Introduction 1-57 Throughput: Internet scenario per-connection Rs Rs R Rc Rc 10 connections (fairly) share backbone bottleneck link R bits/sec Introduction 1-58 end-end throughput: min(Rc,Rs,R/10) in practice: Rc or Rs is often bottleneck Rs Rc Chapter 1: roadmap 1.1 What is the Internet? 1.2 Network edge end systems, access networks, links 1.3 Network core circuit switching, packet switching, network structure 1.4 Delay, loss and throughput in packet-switched networks 1.5 Protocol layers, service models Introduction 1-59 Protocol Layers Networks are complex! many pieces: hosts routers links of various media applications protocols hardware, software Question: Is there any hope of organizing structure of network? Or at least our discussion of networks? Introduction 1-60 Organization of air travel ticket (purchase) baggage (check) gates (load) runway takeoff airplane routing ticket (complain) baggage (claim) gates (unload) runway landing airplane routing airplane routing a series of steps Introduction 1-61 Layering of airline functionality ticket (purchase) baggage (check) gates (load) runway (takeoff) airplane routing departure airport ticket (complain) baggage (claim gates (unload) runway (land) airplane routing airplane routing airplane routing arrival airport ticket baggage gate takeoff/landing airplane routing intermediate air-traffic control centers Layers: each layer implements a service via its own internal-layer actions relying on services provided by layer below Introduction 1-62 Why layering? Dealing with complex systems: explicit structure allows identification, relationship of complex systems pieces layered reference model for discussion modularization eases maintenance, updating of system change of implementation of layers service transparent to rest of system e.g., change in gate procedure doesnt affect rest of system layering considered harmful? Introduction 1-63 Internet protocol stack application: supporting network applications FTP, SMTP, HTTP application transport network link physical transport: process-process data transfer TCP, UDP network: routing of datagrams from source to destination IP, routing protocols link: data transfer between neighboring network elements PPP, Ethernet Introduction 1-64 physical: bits on the wire ISO/OSI reference model presentation: allow applications to interpret meaning of data, e.g., encryption, compression, machinespecific conventions session: synchronization, checkpointing, recovery of data exchange Internet stack missing these layers! these services, if needed, must be implemented in application needed? application presentation session transport network link physical Introduction 1-65 source datagram Hn Ht message segment Ht M M M M frame Hl Hn Ht application transport network link physical Encapsulation link physical switch destination M Ht Hn Ht Hl Hn Ht M M M application transport network link physical Hn Ht Hl Hn Ht M M network link physical Hn Ht M router Introduction 1-66 Introduction: Summary Covered a ton of material! Internet overview whats a protocol? network edge, core, access network packet-switching versus circuit-switching Internet structure performance: loss, delay, throughput layering, service models You now have: context, overview, feel of networking more depth, detail to follow! Introduction 1-67
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Carleton University - SCE - 5201
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Chapter 3 Transport LayerA note on the use of these ppt slides:Were making these slides freely available to all (faculty, students, readers). Theyre in PowerPoint form so you can add, modify, and delete slides (including this one) and slide content to s
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CHM 2120 Assignment #1 In this assignment: - Lewis structures, formal charge - Electronegativity, dipoles - Resonance - Acid/base 1. Draw the following molecules as full Lewis structures. Many molecules below possess a charge that is not showncalculate th
University of Ottawa - SCIENCE - CHM2120
CHM 2120 Assignment #1 ANSWERS In this assignment: - Lewis structures, formal charge - Electronegativity, dipoles - Resonance - Acid/base 1. Draw the following molecules as full Lewis structures. Many molecules below possess a charge that is not showncalc
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CHM 2120 Assignment #2 In this assignment: - Separation of organic compounds using acid/base techniques - Acids/Bases - SN2, SN1 - E2, E1 1. How would you separate the following mixtures of compounds by extraction? a. Octan-1-ol and octan-1-amine b. Cyclo
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CHM 2120 Assignment #2 ANSWERS In this assignment: - Separation of organic compounds using acid/base techniques - Acids/Bases - SN2, SN1, E2, E1 1. How would you separate the following mixtures of compounds? a. Octan-1-ol and octan-1-amine Dissolve both i
University of Ottawa - CHM - 2120
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University of Ottawa - CHM - 2120
CHM 2120 - Assignment 4 In this assignment: - Drawing and naming aromatic compounds - Drawing resonance structures involving aromatic compounds - Distinguishing aromatic from antiaromatic compounds 1. Supply a clear structure of: a) m-dibromobenzene; b) 3
University of Ottawa - CHM - 2120
CHM 2120 - Assignment 4 ANSWERS In this assignment: - Drawing and naming aromatic compounds - Drawing resonance structures involving aromatic compounds - Distinguishing aromatic from antiaromatic compounds 1. Supply a clear structure of:a) m-dibromobenze
University of Ottawa - CHM - 2120
CHM 2120 Assignment 5 Reactions of aromatic compounds In this assignment: - Electrophilic aromatic substitution - Manipulation of products of aromatic substitution - Acidity/basicity is affected by aromaticity and substituents on aromatic rings - Synthesi
University of Ottawa - CHM - 2120
CHM 2120 Assignment 5 Reactions of aromatic compounds ANSWERS In this assignment: - Electrophilic aromatic substitution - Manipulation of products of aromatic substitution - Acidity/basicity is affected by aromaticity and substituents on aromatic rings -
University of Ottawa - CHM - 2120
CHM 2120 Assignment 6 In this assignment: - NMR spectroscopy - IR spectroscopy - Problem-solving and structure identification 1. Associate each of the following IR spectra with one of the following compounds and justify your answer. a. Propanoic acid b. 2
University of Ottawa - CHM - 2120
CHM 2120 Assignment 6 ANSWERS 1. Associate each of the following IR spectra with one of the following compounds and justify your answer. a. Propanoic acid: look for a carbonyl stretch and a broad OH stretch b. 2-Pentanol: look for an OH peak (broad). No c
University of Ottawa - CHM - 2120
CHM 2120 Assignment 7 In this assignment: - Oxidation of alcohols - Nucleophilic addition to carbonyls - Acetals and derivatives - Wittig reaction - Baeyer-Villiger reaction 1. Provide names for the following compoundsa)Oc) Ob)Od) HO2 C O2. Draw th
University of Ottawa - CHM - 2120
CHM 2120 Assignment 7 ANSWERS In this assignment: - Oxidation of alcohols - Nucleophilic addition to carbonyls - Acetals and derivatives - Wittig reaction - Baeyer-Villiger reaction 1. Provide names for the following compoundsa) ( E )-hept-4-enal b)S S
University of Ottawa - CHM - 2120
CHM 2120 Assignment 8 In this assignment: - The aldol reaction - Haloform reaction - Synthetic applications Note: many questions incorporate earlier material 1. Draw the mechanism for the tautomerization of 1-phenyl-1-butanone (also known as butyrophenone
University of Ottawa - CHM - 2120
CHM 2120 Assignment 8 - ANSWERS In this assignment: - The aldol reaction - Haloform reaction - Synthetic applications Note: many questions incorporate earlier material 1. Draw the mechanism for the tautomerization of 1-phenyl-1-butanone (also known as but
University of Ottawa - CHM - 2120
CHM 2120 Assignment 9 ANSWERS In this assignment: - Esterification - Saponification of esters - Chemistry of carbonyl derivatives - Synthesis of carbonyl compounds (via oxidation of alcohols, etc) For the brainstorming/analysis portions of a synthesis, yo
University of Ottawa - CHM - 1321
CHM 1321 Assignment 11) Draw Lewis structures, showing all unshared electrons, for the following molecules: (a) CH3NH2 (b) CH2CH2 (c) C2H2 (d) CH3CH2CHO (e) CH3CH2OH2+ (f) (CH3)3N (g) CH3CN (h) CH3CH(OH)CH3 (i) CH3NCO (j) CH2CHCH(OH)CH2CO2H (k) NCCH2COCH
University of Ottawa - CHM - 1321
CHM 1321 Assignment #2In this assignment: - Drawing Lewis structures and assigning formal charges - Analyzing the effects of intermolecular forces - Conformational analysis 1) Draw Lewis structures for the following molecules. Identify the hybridization
University of Ottawa - CHM - 1321
CHM 1321 Assignment #2 - Answers1) Draw Lewis structures for the following molecules. Identify the hybridization oft the underlined atoms. a.AlCl3 Cl Cl sp2 The &quot;p &quot; or bital is empty Cl Alf. Propanoic acidHH O C C H C O H HHg. FormaldehydeH CO Hb.
University of Ottawa - CHM - 1321
CHM 1321 Assignment 31) Identify each of the following pairs as constitutional isomers, stereoisomers (configurational isomers), or conformers.a) + d) Br Br + b) + e) Br BrBr Br +BrBrc) + f) Br Br + Br Br2) Draw each structure below along with its
University of Ottawa - CHM - 1321
CHM 1321 Assignment 3 - ANSWERS1) Identify each of the following pairs as constitutional isomers, stereoisomers (configurational isomers), or conformers.a) + Stereoisomers b) + Constitutional isomers c) + Same compound f) Br Br + Br e) Br Br + Br d) Br
University of Ottawa - CHM - 1321
CHM 1321 Assignment 4In this assignment: - Acid/base reactions - Resonance 1) Draw the important resonance forms and show the resonance hybrid structures for the following:(a) H3C O C CH3 (b) H3C O C CH2 H C C H (c) O C OH (d) H C C C CH3 3 H2 CH2 C CH
University of Ottawa - CHM - 1321
CHM 1321 Assignment 4 Answers1) Draw the important resonance forms and show the resonance hybrid structures for the following:(a) H 3C O C CH3 O C O CH3 H 3C + CH 3H3 CO CCH3H3 CO (b) H 3C C CH 2 O C OH 3CO CCH2H3 CO CCH2H3CCH2 H3 C + CH2
University of Ottawa - CHM - 1321
CHM 1321 Assignment #5 In this assignment: - SN2 reactions - SN1 reactions (these occur primarily when there is a tertiary alpha carbonwill be seen in class shortly) 1. Use arrow notation to show the mechanisms of the following reactions. Use your mechani
University of Ottawa - CHM - 1321
CHM 1321 Assignment #5 - ANSWERS 1. Use arrow notation to show the mechanisms of the following reactions. Use your mechanism to predict the product of the reaction. Identify the nucleophile, its nucleophilic atom, the carbon of the electrophile and the le
University of Ottawa - CHM - 1321
CHM 1321 Assignment #6 In this assignment: - Nucleophilic addition to carbonyls - Elimination reactions (E1, E2) 1) Give the products of the following reactions and give mechanisms to show how they are formed:O a) H3CO O b) H 1) NaBH4 2) H3O+ 1) NaBH4 2)
University of Ottawa - CHM - 1321
CHM 1321 Assignment #6 - ANSWERS In this assignment: - Nucleophilic addition to carbonyls - Elimination reactions (E1, E2) To be covered the week of March 24th 1) Give the products of the following reactions and give mechanisms to show how they are formed
University of Ottawa - CHM - 1321
CHM 1321 Assignment 7 In this assignment: - Alkene addition reactions - Synthesis 1. Predict the major product(s) of the following reactions and give a mechanism to account for its formation.a) + HBrb)+ HCl + HClc)1-methylcyclohexened)+ HBrH 2SO4
University of Ottawa - MAT - 2378
Assignment 1Due date: 23 September 2009Total number of points: 33Q1. (2.1 in the textbook) For parts (a) and (b), (i) identify the variables in the study; (ii) for each variable, write the type of variable (cathegorical/ordinal, discrete etc.); (iii) i
University of Ottawa - MAT - 2378
Assignment 2Due date: 7 October 2009Total number of points: 34Q1. The three events are shown on the Venn diagram: '$ '$ A B&amp;% &amp;% '$ C &amp;% Reproduce the gure and shade the region corresponding to the following events: (a) (c) (e) Ac (A and B ) or C (A a
University of Ottawa - MAT - 2378
Assignment 3Due date: 21 October 2009Total number of points: 32Q1. A medical research team wished to evaluate a proposed screening test for Alzheimers disease. The test was given to a random sample of 450 patients with Alzheimers disease, in 436 cases
University of Ottawa - MAT - 2378
Assignment 4Due date: 16 November 2009Total number of points: 27Q1. (6.39) In a natural population of mice near Ann Arbor, Michigan, the coats of some individuals are white-spotted on the belly. In a sample of 580 mice from the population, 28 individua
University of Ottawa - MAT - 2378
Assignment 6Due date: 7 December 2009Total number of points: 22Q1. (12.5, 12.14, 12.21, 12.28) Twenty plots were randomly chosen in a large eld of corn. For each plot, the plant density (number of plants in the plot) and the mean cob weight (g of grain
University of Ottawa - PSY - 2105
Background and TheoriesChapter 1Learning ObjectivesLearning Objective 1.1 Understand the philosophical and historical roots of child psychology. Learning Objective 1.2 How can we understand the influences of nature and nurture, stability and change, an
University of Ottawa - PSY - 2105
Research MethodsChapter 2 ChapterLearning Objectives Learning Learning Objective 2.1 Understand how researchers use the scientific method to study child development. study Learning Objective 2.2 Compare and contrast the research methods commonly used t
University of Ottawa - PSY - 2105
Genetics: The Biological Genetics: Context of Development ContextChapter 3 ChapterLORD THE HUMAN GENOME CODE HAS BEEN DISCOVEREDOH THOSE HACKERS! I WILL HAVE TO CHANGE THE PASSWORD.Learning Objectives Learning Learning Objective 3.1 Identify and desc
University of Ottawa - PSY - 2105
Chapter 5 ChapterPhysical DevelopmentLearning Objectives Learning Learning Objective Discuss the assessment of and factors affecting newborn health. newborn Learning Objective Describe ways in which the infants behaviour appears to be organized at birt
University of Ottawa - PSY - 2105
Chapter 6 ChapterSensory and Perceptual Sensory Development 2nd. part DevelopmentLearning Objectives Learning Learning Objective 6.1 Explain the issues for understanding perceptual development. development. Learning Objective 6.2 Outline the developmen
University of Ottawa - PSY - 2105
Cognitive Development: Cognitive The Piagetian Approach TheChapter 7 ChapterLearning Objectives Learning Learning Objective 7.1 Define the concepts from biology that Piaget used to explain cognitive development and evaluate his theory of stages. of Lea
University of Ottawa - PSY - 2105
Cognitive Development: Cognitive The Piagetian Approach TheChapter 7 ChapterLearning Objectives Learning Learning Objective 7.3 Identify some strengths and limitations of preoperational thought in childrens cognitive development. childrens Learning Obj
University of Ottawa - PSY - 2105
Cognitive Development: Cognitive The Piagetian Approach TheChapter 7 ChapterLearning Objectives Learning Learning Objective 7.3 Identify some strengths and limitations of preoperational thought in childrens cognitive development. childrens Learning Obj
University of Ottawa - PSY - 2105
Chapter 9 ChapterCognitive Development: Cognitive The Sociocultural Approach ApproachLearning Objectives Learning Learning Objective 9.1 Describe the sociocultural approach to child development and compare and contrast it with cognitive-developmental a
University of Ottawa - PSY - 2105
Chapter 11 ChapterLanguage DevelopmentLearning Objectives Learning Learning Objective 11.1 Compare and contrast four major theories of language development. development. Learning Objective 11.2 Trace the developments in the first year of life that esta
University of Ottawa - PSY - 2105
Chapter 12 ChapterEarly Social and Emotional Early Development DevelopmentLearning Objectives Learning Learning Objective 12.1 Understand the major theoretical approaches to early social development. development. Learning Objective 12.2 Understand the