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course announcement S99
Course: EMA 6165, Spring 2011School: University of Florida
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41262640. Adetailedbibliographywillbeprovidedforallpertinentreferencesaddressedinthe lectures. MATERIALSSCIENCEANDENGINEERING SYLLABUS for EMA6165,Sect1713XPOLYMERPHYSICS(3Credits) TPer2&3,RPer2,RoomCSE122 TEXTBOOKREQUIRED: PolymerPhysics,Ulf.W.Gedde(1995)Chapman&Hall,London,UK,ISBN0 Studentswillberesponsibleforadditionalreadingoutsidetherequired textasassignedinclass PROFESSOR:...
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41262640.
Adetailedbibliographywillbeprovidedforallpertinentreferencesaddressedinthe
lectures. MATERIALSSCIENCEANDENGINEERING
SYLLABUS
for
EMA6165,Sect1713XPOLYMERPHYSICS(3Credits)
TPer2&3,RPer2,RoomCSE122
TEXTBOOKREQUIRED:
PolymerPhysics,Ulf.W.Gedde(1995)Chapman&Hall,London,UK,ISBN0 Studentswillberesponsibleforadditionalreadingoutsidetherequired
textasassignedinclass
PROFESSOR:
A.B.Brennan,AssociateProfessor,317DMAE,Tel:(352)3926281,FAX:(352)
3923771,Email:abren@mse.ufl.edu
PREREQUISITES:
PolymerScience/Engineering(EMA3066,equivalentorinstructorspermission)
PhysicalChemistry/Thermodynamicsorequivalentrecommended.
GOALS:
The will course provide a fundamental understanding of the structure/property
relationships of amorphous and semicrystalline polymers. The behavior of
polymersinsolutionandsolidstatewillbecomparedandcontrastedtoprovidea
molecularunderstandingofbulkproperties.Anunderstandingofthermodynamics
isrequired.
EVALUATION:
Homework
ExamI&II
ExamIII
ResearchProposal
50pts
200pts
100pts
100pts
TOPICSTOBECOVERED:
PhaseBehavior
PolymerSolventInteraction
PolymerPolymerInteraction
ChainDimensions(ScalingLaws)
Amorphous/GlassyState
CrystallineState
RubberElasticity
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University of Florida - EMA - 6165
EMA 6165 - Polymer PhysicsCrystallinityLecture 32Professor Anthony BrennanDepartment of Materials Science &EngineeringUniversity of Florida07/21/11EMA 6165 Polymer Physics - Lecture 321Rate of growthIf hf is known one can calculate eHuseby, Ba
Crystallization-PDMSe-effect-of-silica-filler-and-curing-Polymer-vol-39(20)-4897-903-Aranguren-(1998
University of Florida - EMA - 6165
Polymer Vol. 39 No. 20, pp. 4897-4903, 1998PII: S0032-3861(97)10252-XE LSEVIER~) 1998 Elsevier Science LtdP rinted in Great Britain. All rights reserved0 (132-3861/98/519.00+0.00C rystallization of polydimethylsiloxane: effecto f silica filler and
University of Florida - EMA - 6165
Physica Scripta. Vol. T35, 11-16, 1991.Dynamics o f P olymer NetworksS . F . EdwardsCavendish Laboratory, Cambridge CB3 OHE, U.K.Received April 9, 1990: accepted January 3 0, 1991AbstractSimple models of the behaviour of polymers in networks are sho
University of Florida - EMA - 6165
POLYMER PHYSICS - Fall 2008EMA 6165 - EXAM IINSTRUCTIONS:Read the entire exam carefully. Answer every question to the best of your ability,based upon the available information. State all assumptions you use in answers.SECTION I: Polymer Structures/Pr
University of Florida - EMA - 6165
POLYMER PHYSICS Fall 2008EMA 6165 - EXAM ISTUDENT UFID#:_(use the NEW UF ID No.)INSTRUCTIONS: Read the entire exam carefully. Answer every question to the best of your ability, basedupon the available information. State all assumptions you use in ans
University of Florida - EMA - 6165
POLYMER PHYSICS - Fall 2009 (EDGE)EMA 6165 - EXAM IINSTRUCTIONS: Read the entire exam carefully. Answer every question to the best of your ability, based uponthe available information. State all assumptions you use in answers.SECTION I: Polymer Struct
University of Florida - EMA - 6165
POLYMER PHYSICS Fall 2009EMA 6165 - EXAM ISTUDENT UFID#:_(use the NEW UF ID No.)INSTRUCTIONS: Read the entire exam carefully. Answer every question to the best of your ability, basedupon the available information. State all assumptions you use in ans
University of Florida - EMA - 6165
POLYMER PHYSICS - Fall 2009-EdgeEMA 6165 - EXAM 2INSTRUCTIONS:Read the entire exam carefully. Answer every question to the best of your ability,based upon the available information. State all assumptions you use in answers.SECTION I: Polymer Structur
University of Florida - EMA - 6165
POLYMER PHYSICS Fall 2009-EdgeEMA 6165 - EXAM 2STUDENT UFID#:_(use the NEW UF ID No.)INSTRUCTIONS: Read the entire exam carefully. Answer every question to the best of your ability, basedupon the available information. State all assumptions you use i
University of Florida - EMA - 6165
POLYMER PHYSICS - Fall 2009-EdgeEMA 6165 - EXAM 2INSTRUCTIONS:Read the entire exam carefully. Answer every question to the best of your ability,based upon the available information. State all assumptions you use in answers.SECTION I: Polymer Structur
University of Florida - EMA - 6165
POLYMER PHYSICS Fall 2009-EdgeEMA 6165 - EXAM 3120 points totalSTUDENT UFID#:_(use the NEW UF ID No.)INSTRUCTIONS: Read the entire exam carefully. Answer every question to the best of your ability, basedupon the available information. State all assu
University of Florida - EMA - 6165
Student Number:_INSTRUCTIONS: Read the entire exam carefully. Answer every question to the best of yourability, based upon the available information. State all assumptions in answers.SECTION I: Polymer Structures/Properties. (4 pts each/24 pts total)1
University of Florida - EMA - 6165
Student Number:_INSTRUCTIONS: Read the entire exam carefully. Answer every question to the best of yourability, based upon the available information. State all assumptions in answers.SECTION I: Polymer Structures/Properties. (4 pts each/24 pts total)1
University of Florida - EMA - 6165
Student Number:_INSTRUCTIONS: Read the entire exam carefully. Answer every question to the best of yourability, based upon the available information. State all assumptions in answers.SECTION I: Polymer Structures/Properties. (4 pts each/24 pts total)1
University of Florida - EMA - 6165
Student Number:_INSTRUCTIONS: Read the entire exam carefully. Answer every question to the best of yourability, based upon the available information. State all assumptions in answers.SECTION I: Polymer Structures/Properties. (4 pts each/24 pts total)1
University of Florida - EMA - 6165
Student Number:_INSTRUCTIONS: Read the entire exam carefully. Answer every question to the best of yourability, based upon the available information. State all assumptions in answers.SECTION I: Polymer Structures/Properties. (1 pt each/36 pts total)1.
University of Florida - EMA - 6165
POLYMER PHYSICAL SCIENCE - FALL 2010NAME: PUT ON LAST PAGE and SIGN HONOR CODEEMA 6165 Exam 3 Rev BSTUDENT ID NUMBER:_INSTRUCTIONS: Read the entire exam carefully. Answer every question to the best of yourability, based upon the available information
University of Florida - EMA - 6165
Student Number:_INSTRUCTIONS: Read the entire exam carefully. Answer every question to the best of yourability, based upon the available information. State all assumptions in answers.SECTION I: Polymer Structures/Properties. (1 pt each/36 pts total)1.
University of Florida - EMA - 6165
POLYMER PHYSICAL SCIENCE - FALL 2010EMA 6651C Exam 3NAME: PUT ON LAST PAGE and SIGN HONOR CODESTUDENT ID NUMBER:_INSTRUCTIONS: Read the entire exam carefully. Answer every question to the best of yourability, based upon the available information. Sta
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
POLYMER PHYSICS - Spring 2005EMA 6165 - EXAM ISTUDENT UFID#:_(use the NEW UF ID No. )INSTRUCTIONS: Read the entire exam carefully. Answer every question to the best of your ability, basedupon the available information. State all assumptions you use i
University of Florida - EMA - 6165
POLYMER PHYSICS - Spring 2005EMA 6165 - EXAM ISTUDENT UFID#:_(use the NEW UF ID No. )INSTRUCTIONS: Read the entire exam carefully. Answer every question to the best of your ability, basedupon the available information. State all assumptions you use i
University of Florida - EMA - 6165
POLYMER PHYSICS - Spring 2005EMA 6165 - EXAM 2STUDENT UFID#:_(use the NEW UF ID No. )INSTRUCTIONS: Read the entire exam carefully. Answer every question to the best of your ability, basedupon the available information. State all assumptions you use i
University of Florida - EMA - 6165
POLYMER PHYSICS - Spring 2007EMA 6165 - EXAM ISTUDENT UFID#:_(use the NEW UF ID No.)INSTRUCTIONS: Read the entire exam carefully. Answer every question to the best of your ability, basedupon the available information. State all assumptions you use in
University of Florida - EMA - 6165
POLYMER PHYSICS - Spring 2007EMA 6165 - EXAM 2STUDENT UFID#:__(UF ID No.)INSTRUCTIONS: Read the entire exam carefully. Answer every question to thebest of your ability, based upon the available information. Stateall assumptions used to answer/solve
University of Florida - EMA - 6165
POLYMER PHYSICS - Spring 2007EMA 6165 - EXAM 3STUDENT UFID#:__(UF ID No.)INSTRUCTIONS: Read the entire exam carefully. Answer every question to thebest of your ability, based upon the available information. Stateall assumptions used to answer/solve
University of Florida - EMA - 6165
EVALUATIONFORMforEMA6165,SPRING2001POLYMERPHYSICSProfessorA.B.BrennanOffice:317DMAETel: 39262813CreditsMWFPeriod5Room:CSEE118ANSWEREACHQUESTIONTOTHEBESTOFYOURABILITY!YouHave10Minutes1.DefinetheFloryHugginsEquation:2.DefineaGaussianChain:3.G
University of Florida - EMA - 6165
EMA6165,Section1713SPRING1999POLYMERPHYSICSRESEARCHPROPOSALProfessorA.B.BrennanOffice:317DMAETel: 39262813CreditsMWF,PERIOD4Room:CSE118BTheobjectiveofaresarchproposalistodemonstrateaproficiencyinaparticulartechnicalarea. Thisparticularproposalis
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
University of Florida - EMA - 6165
Polymer Physical ScienceEMA 6165 Sections DEPT, EDGEProfessor Anthony B. BrennanUniversity of FloridaMaterials Science & Engineering1. Polymer Physics2. Pre-requisites: Baccalaureate degree or equivalent Chemistry,Engineering, Physics, or equivalen
University of Florida - EMA - 6165
Polymer Physical ScienceEMA 6165 Sections DEPT, EDGEProfessor Anthony B. BrennanUniversity of FloridaMaterials Science & Engineering1. Polymer Physics2. Pre-requisites: Baccalaureate degree or equivalent Chemistry,Engineering, Physics, or equivalen
University of Florida - EMA - 6165
Equations for Polymer Physics/ProcessingRubber Elasticity:Thermodynamics of Mixing = NV kT ( 2 )==RT 2 M C 1 ( 2 )MC Mo RT 13 ( 2 )MC( 0x = N v kT x x 3y 20 x0 x2 H m = N 1 2 1, 2 k T 12G mix = RT ln(1 2 ) + 1 2 + 1 2 x)1= x 2
University of Florida - EMA - 6165
Rubber Elasticity:[]Thermodynamics of MixingCrystallization & KineticsPhysical Aging Behavior/ViscoelasticityGeneral ThermodynamicsChain Dimensions/Molecular Weight2[] =2.5 4 Reo3 M32M123Viscoelasticity and MechanicsFluid Dynamics (Rheolo
University of Florida - EMA - 6165
H = E + PV HE V P = + + l T, P l T, P l T, P l T, P V 10 4 for a good elastomer l =1 V V T P ,lP= 1 V V P l ,T P = T V ,lV = 0E ~ f ( l ,V ) E E dV + dldE = V l ,T l T ,V E E V E l = + l T ,P V l ,T l T , P l T