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Great Lakes - MBA - 101
Organizational Behaviour
UGA - CHEM 2212 - 234-54
CHEM2212:FundamentalsinModernOrganicChemistryIIChapter14:ConjugatedDienes&UltravioletSpectroscopyPolyunsaturatedSystemsExamples:1SpecificFocus:Subcategories:1.)NonConjugated:2.)Cojugated:2Subcategories(cont'd):Miscellaneous:Enynes:Enones:3N
UGA - CHEM 2212 - 234-54
ImprovedStabilityExplained:Static1.)ValenceBondTheory:1MolecularOrbitalTheory:Dynamic2MolecularOrbitalTheory(cont'd):3PossibleResonanceStructures:4OK,Iunderstandwhyconjugatedsystemsaremorestable,butwhatpracticalapplicationsarethereforthisinfor
UGA - CHEM 2212 - 234-54
TemperatureandItsInfluenceonReactionProducts:1KineticControl:ThermodynamicControl:2Example3:3TheDielsAlderCycloadditionReaction:Example:4GeneralExamples:5DienophileCharacteristics:6StereospecificityofTheDielsAlderReaction:Thestereochemistry
UGA - CHEM 2212 - 234-54
StereospecificityofTheDielsAlderReaction:Thestereochemistry(cis/trans)ofthedienophileisconservedduringthecourseofaDielsAlderReactionExamples:1OrbitalOverlap:2DieneCharacteristics:Mustbeorientedinascisconformation(cisoid)3NonCisoidExamples:Resul
UGA - CHEM 2212 - 234-54
DienePolymerization:(Review7.10)Example:1UVSpectroscopy:UVVisSpectroscopyprovidesinformationaboutcompoundswithconjugateddoublebondsConjugatedcompoundsabsorblightintheultravioletregionElectronsintheHOMOorbitalundergoatransitiontotheLUMOorbitaldueto
UGA - CHEM 2212 - 234-54
Namingdisubstitutedbenzenes:Generalorientationofgroups:Examples:1Namingbenzeneswithmorethantwosubstituents:Examples:2AssigningCommonNames:Examples:3StructuralCharacteristicsandStabilityofBenzene:PredictedStabilityBasedonHeatsofHydrogenation4O
UGA - CHEM 2212 - 234-54
12Cyclooctatetraeneistubshapednotplanar:UndergoesadditionreactionsTheporbitalsarenotparallelsotheycannotoverlapforconjugation3NonAromaticity:Cyclic,conjugatedmoleculeswhosestabilitycloselyresemblestheiropenchainanalogsThereisnonoticeableincreaseo
UGA - CHEM 2212 - 234-54
PolycyclicAromaticRings:ResonanceStructures:1InfraredSpecificAbsorptions:Monosubstituted:oDisubstituted:mDisubstituted:pDisubstituted:23DeshieldingofAromaticProtons:45Chapter16:ReactionsofBenzeneandItsDerivativesNoelectrophilicadditionreacti
UGA - CHEM 2212 - 234-54
NitrationReaction:GenerationoftheElectrophile:Mechanism:ReductionoftheNitroGroup(AmineFormation):.1SulfonationReaction:GenerationoftheElectrophile:Mechanism:SulfonationisfavoredinstrongacidReversibleinhot,diluteaqueousacid(desulfonation)AlkaliF
UGA - CHEM 2212 - 234-54
FriedelCraftsAcylation:ReactionofanacidchloridewithanaromaticringFormationofPhenylpropylketone:GenerationoftheElectrophile:Mechanism:.1PrimaryDifferencesBetweenFCAlkylationandAcylation:NooveracylationobservedonlysinglesubstitutionsTheringisdeacti
UGA - CHEM 2212 - 234-54
ClassificationofSubstituentEffects:Therearenometadirectingactivators(activatinggroups)1Therearetwoprimaryeffectsthatgovernthereactivityandorientationofelectrophilicaromaticsubstitutionreactions1.InductiveEffects:Thewithdrawalordonationofelectronsthr
UGA - CHEM 2212 - 234-54
Examples:1ReactionsofDisubstitutedBenzeneDerivatives:AdditiveEffects2ReactionsofDisubstitutedBenzeneDerivatives:OpposingDirectingEffectsThemorepowerfulactivatinggrouphasthedominantinfluenceProductmixturesarepossible3ReactionsofDisubstitutedBenze
UGA - CHEM 2212 - 234-54
NucleophilicAromaticSubstitutionExample:Whatisthepropablemechanismforthisreaction?SN1?SN2?1Neitherrouteseemsplausible:Let'sexplainthemechanismbylookingatthereactionrequirements:1.)Thearomaticringmustbeelectrondeficient22.)Anelectronwithdrawin
UGA - CHEM 2212 - 234-54
BrominationofAlkylbenzeneSideChains:AlkylsidechainsarebrominatedatthebenzylicpositioninthepresenseofNBS(Nbromosuccinimide)usingbenzoylperoxide(PhCO2)2asaradicalinitiatorTheintermediateisabenzylicradicalExample:Mechanism:1ReductionReactionsofAromat
UGA - CHEM 2212 - 234-54
ClassifyingandNamingAlcoholsGeneralClassification:PrimaryAlcoholSecondaryAlcoholTertiaryAlcohol1IUPACRulesforNamingAlcohols:Selectthelongestchain(carbon)containingthehydroxylgroupandderivetheparentnamebyreplacingtheewitholNumberthechainfromtheend
UGA - CHEM 2212 - 234-54
AlcoholPreparationReactions:1.)HydrationofAlkenes2.)FormationofDiolsfromAlkenes:1AlcoholsfromtheReductionofCarbonylCompounds:AldehydePrimaryAlcoholExample:KetoneSecondaryAlcoholExample:ReagentComparison:Sodiumborohydride: Safe,stable,lessreact
UGA - CHEM 2212 - 234-54
MechanismReview:E11DehydrationofAlcoholsusingPhosphorusOxychloride:Allowsforthedehydrationofalcoholsatmuchlowertemps(lessharshconditions)Example:Mechanism: *TheBookisIncomplete*2ConversionofAlcoholsintoAlkylHalides:Tertiaryalcohols(review):3Conv
UGA - CHEM 2212 - 234-54
ProtectionofAlcohols:SometimesthereactionconditionsnecessaryfortheconversionofspecificfunctionalgroupsareincompatiblewithothergroupspresentinthemoleculeExample:3GeneralStepsofProtectionGroupChemistry:1.)Introductionofaprotectinggrouptoblockinterfere
UGA - CHEM 2212 - 234-54
ReactionsofEther:2.ClaisenRearrangementSpecifictoallylarylethersGeneralStructure:InitialEtherFormation:ClaisenRearrangement: PericyclicReaction(concerted)1Mechanism:Example:2Epoxides:ATypeofCyclicEther3MemberedringcyclicethersknownasoxiranesTh
UGA - CHEM 2212 - 234-54
ImportantPropertiesandApplications:Theysolvatemetalcationsverywell.Thecenterishighlyelectronegative(erich)Allowforthesolvationofionicsaltsinnonpolarsolvents(aproticconditions)1ThiolsandSulfidesThiolNomenclature:SulfurAnalogsofAlcoholsNamedusingth
UGA - CHEM 2212 - 234-54
EtherNomenclature:Method1:Inthecaseofsimpleetherswithnootherfunctionalgroups,namethetwoorganicgroupsandadd"ether"totheendIfotherfunctionalgroupsarepresent,theetherportionisconsideredMethod2: asubstituent(alkoxygroup)1StructureandPhysicalPropertieso
UGA - CHEM 2212 - 234-54
Chapter19:AldehydesandKetones:NucleophilicAdditionReactionsGeneralStructures:AldehydesKetonesCharacterizedbythepresenceofacarbonylfunctionalgroupCarefullyreadoverthecarbonylcompoundpreviewfoundonpages686694(Mandatory)1Aldehydes:NomenclatureReplac
UGA - CHEM 2212 - 234-54
TypicalOxidativeReactionPathwayFormationofahydrateintermediate:OxidativeCleavageofKetonesKetonesareinerttomostoxidizingagents,but:CleavesaCCbondadjacenttothecarbonylUsedmainlyforcleavingsymmetricalketones.Why?AsymmetricExample:.1NucleophilicAddit
UGA - CHEM 2212 - 234-54
CatalyzationofHydrationReactionsAcidCatalyzedHydrationReactionMechanism:AdditionofHYtoacarbonylcompound(ketones/aldehyde):1NucleophilicAdditionofHCN:CyanohydrinFormationGeneralReaction:UsingHCNasthelonereactantOverallreactionratecanbeincreasedifasma
UGA - CHEM 2212 - 234-54
MechanismofImineFormation:1MechanismofEnamineFormation:2Imine/EnaminePracticeProblems:3NucleophilicAdditionofHydrazineTheWolffKishnerReaction:4TheWolffKishnerMechanism:5
UGA - CHEM 2212 - 234-54
NucleophilicAdditionofAlcohols:AcetalFormationGeneralReactionScheme:Mechanism:1UsesofAcetalsExample:2Acetalsasdiolprotectinggroups:3Thioacetalformation:4Thioketalformation:5NucleophilicAdditionofPhosphorusYlides:TheWittigReactionGeneralReact
UGA - CHEM 2212 - 234-54
WittigReaction:MechanismofAdditionSymmetricalKetone:1WittigReaction:MechanismofAdditionAldehydesandUnsymmetricalKetones:2WittigReactionPracticeProblems:3WittigreactionE/Zselectivity:GeneralRule:Wittigreagentswithanionstabilizingsubstituents,such
UGA - CHEM 2212 - 234-54
TheCannizaroReaction:DisproportionationReactionMechanism:1ConjugateNucleophilicAdditionto,UnsaturatedAldehydesandKetonesOverviewofStructural/ElectronicConsiderations:2ThePresenceoftheCarbonylisEssential:ConjugateAdditionofAmines:Examples:3Conjug
UGA - CHEM 2212 - 234-54
CommonIRCarbonylAbsorptionValuesforAldehydesandKetones:ProtonNMRSpectroscopyofAldehydesandKetones:Aldehydeprotonsgivedistinctabsorptionsnear10Aldehydeprotonsundergospin/spinsplittingwithneighboringhydrogensKetones/aldehydes:protonsoncarbonsdirectlyad
UGA - CHEM 2212 - 234-54
PreparationofCarboxylicAcidsOxidationofanalkylbenzenetoformbenzoicacidOxidativecleavageofanalkene(tri,di,monosubstituted)1PreparationofCarboxylicAcids(cont'd):OxidationofaprimaryalcoholoraldehydeHydrolysisofnitriles2HydrolysisofNitriles:Twosteppr
UGA - CHEM 2212 - 234-54
HydrolysisofNitriles:GeneralReaction:Mechanism:BaseCatalyzed1HydrolysisofNitriles:Mechanism:AcidCatalyzed2ReductionofNitrilestoAmines:GeneralReaction:AlkylationofNitrilestoProduceKetones:GeneralReaction:3AlkylationofNitrilestoProduceKetones:M
UGA - CHEM 2212 - 234-54
Chapter21:CarboxylicAcidDerivativesandNucleophilicAcylSubstitutionsReactionsGeneralOverviewofCarboxylicCompounds:Structure:acylgroupbondedto"Y"(anelectronegativeatom/group)YGroup= Halide,acyloxy,alkoxy,amine,thiolate,phosphateCarboxylicAcidEsterAci
UGA - CHEM 2212 - 234-54
RelativeReactivityofCarboxylicAcidDerivativesNucleophilesreactmorereadilywithunhinderedcarbonylgroups:Moreelectrophiliccarbonylgroupsaremorereactivetoaddition(toformtetrahedralintermediates)Theintermediatewiththebestleavinggroupformsthesubstitutionpro
UGA - CHEM 2212 - 234-54
PreparationandReactivityofAcylHalidesPreparation:PreviouslyEncounteredReaction: FriedelCraftsAcylation1ReactionsofAcylHalidesHydrolysis:ReactwithH2OtoyieldcarboxylicacidsGeneratesHX,amildbaseisaddedtoneutralizethereaction(pH=7)Mechanism:2Reactio
UGA - CHEM 2212 - 234-54
PreparationofEsters:ReactionSummary:1AcyclicandCyclicEsters:ReactionsofEstersHydrolysis:2ReactionsofEsters(cont'd)Hydrolysis:BaseCatalyzedMechanism3ReactionsofEsters(cont'd)Hydrolysis:AcidCatalyzedMechanism4ReactionsofEsters(cont'd)Aminolysi
UGA - CHEM 2212 - 234-54
ReactionofAmidesConversionofAmidesto.?ChangesthecarbonylintoaCH2groupExamples:Mechanism:.1StepGrowthPolymersPolyamides:Polyesters:StepGrowthPolymersComparedtoChainGrowthPolymers(Chapter8and14):.2ExamplesofCommerciallyImportantStepGrowthPoly
UGA - CHEM 2212 - 234-54
Let'sDrawKevlar:StartingMaterials1,4diaminobenzene1,4benzenedicarboxylicacid1SpectroscopyofCarboxylicAcidDerivativesInfraredAbsorptions:2SpectroscopyofCarboxylicAcidDerivativesProtonNMR:ThepresenseofacarbonylgroupdeshieldstheH'sonadjacentcarbons
UGA - CHEM 2212 - 234-54
DieckmannCyclizationMechanism14AlkylationoftheDieckmannCyclizationProductExample:15ConjugateCarbonylAdditions:TheMichaelReactionExample:NewReaction:Example:1MichaelReaction:Mechanism2CarbonylCondensationswithEnamines:TheStorkReactionQuickRevi
UGA - CHEM 2212 - 234-54
BaseCatalysisofEnolizationBronstedLowreybasescatalyzeketoenoltautomerizationbyabstractinganhydrogenandformingareactiveenolateintermediateHydrogensareweaklyacidicMechanism:1GeneralReactivityofEnolsEnolsactasnucleophilesandreactwithelectrophilestop
UGA - CHEM 2212 - 234-54
EnhancedAcidityofBetaCarbonylsWhenahydrogenisflankedbytwocarbonylgroups,itsacidityincreasesTheenolate'snegativechargeisdelocalizedoverbothoftheadjacentcarbonylgroupsExample:12ReactivityofEnolateIonsEnolatesaremorereactivethanenolsEnolatesarebett
UGA - CHEM 2212 - 234-54
MalonicEsterSynthesis(cont'd):HydrolysisandDecarboxylation:Mechanism:1PracticeExamples:2AcetoaceticEsterSynthesis:GeneralReaction:Ethyl3oxobutanoate:StructureandReactivity:Workup:3PracticeExamples:4DirectalkylationofKetones,Esters,andNitrile
UGA - CHEM 2212 - 234-54
Chapter23:CarbonylCondensationReactionsPreviouslydiscussedcarbonylreactivitypatterns:1CarbonylCondensations:TheAldolReactionGeneralReaction:Examples(symmetrical):23CarbonylCondensations:TheAldolReactionMechanism:4TheAldolCondensation:Equilibriu
UGA - HIST 2112 - 2112
PresidentialReconstructionDefine: PresidentialReconstruction was thereconstruction plan inwhich PresidentJohnson beganimplementing his planto restore the union.Congressional(Radical)ReconstructionThe CongressionalReconstruction is theprocess
UGA - HIST 2112 - 2112
Essay: The policy of the containment during the Cold War.To counter Soviet and communist expansion, the Truman and his aides chose a policy of containment in1947. The policy of containment is U.S. policy uniting military, economic, and diplomatic strate
UGA - HIST 2112 - 2112
Bonus Army (pg. 655)Definition: Bonus Army isthe group of unemployedveterans of the First WorldWar gathered inWashington D.C. todemand payment of theirsoldier bonuses.Significance: Bonus Army was significant because itshowed depressions impact on
Thomas Edison State - BIO - 208
24.25.26.27.28.29.30.31.32.33.34.35.36.37.38.39.40.41.42.43.44.45.46.47.Anorexia nervosa can also be characterized as a: binge eating andpurging type disorder.Anthropometric data is collected in order to: compare measurementsto
Thomas Edison State - BIO - 208
48.49.50.51.52.53.54.55.56.57.58.59.60.61.62.63.64.65.66.67.68.69.70.71.72.73.Microwaves should not be used as a preferred cooking method forfoods that are high in vitamin: B12Of all of the compounds listed below, only _ is act
Thomas Edison State - BIO - 208
74.75.76.77.78.79.80.81.82.83.84.85.86.87.88.89.90.91.92.The warning label that appears on Nutrasweet is necessary toprevent problems: for individuals with PKU.Two meals are available, each with equal caloric value, but one hasa calc
Thomas Edison State - BIO - 208
93.Which of the following best describes the action of the pancreaswith respect to digestive secretions?: Bicarbonate is released toneutralize gastric acidity.94.Which of the following clotting disorders has no relationship tovitamin K?: hemophilia
Thomas Edison State - BIO - 208
114.115.116.117.118.119.120.121.122.123.124.125.126.127.128.129.130.131.132.133.134.135.136.4: a 76 yr old male has a family history of heart disease and he is physicallyinactive. How many risk factors for CVD does he have?Canola
Thomas Edison State - BIO - 208
137.138.140.141.142.143.144.145.146.147.148.149.150.151.152.153.154.155.156.157.158.159.Use olive oil in place of saturated fat AND use corn oil in place ofveggie shortening: in an effort to lower LDL you would tell someone to:whic
Thomas Edison State - BIO - 208
160.161.162.163.164.165.166.167.168.169.170.171.172.173.174.175.176.177.178.179.180.181.A person who eats a bowl of oatmeal for breakfast every day wouldbe displaying a food choice most likely based on: habit.A person with a fastin
Thomas Edison State - BIO - 208
182.All of the following are characteristic of a high-fiber diet except:may reduce the risk of lung cancer but increase the risk of breast cancer183. All of the following are characteristics of protein-energymalnutrition except: it almost always exhib
Thomas Edison State - BIO - 208
1.Understanding Nutrition3.A condensation reaction that forms lactose is expressed as: onemolecule of glucose and one molecule of galactoseA distinguishing feature of monosaccharides is: the structuralarrangement of the compounds.A food product tha
Thomas Edison State - BIO - 208
204. All of the following compounds may be synthesized fromcholesterol except: glucose205. All of the following describe associations between protein nutritionand the body's water balance except: excessive protein losses by thekidney may lead to dehyd
Thomas Edison State - BIO - 208
227.At the end of your class presentation on "Protein-EnergyMalnutrition," a student asks you to clarify how the rapid onset ofprotein-energy malnutrition occurs in kwashiorkor. How shouldyou respond?: It is typically seen in patients who are 1-3 year
Thomas Edison State - BIO - 208
249.General features of legumes include all of the following except: theyare high in fat250. Gluconeogenesis is a term that describes the synthesis of: glucosefrom a noncarbohydrate substance251. Glycogen is stored mainly in which of the following ti
Thomas Edison State - BIO - 208
271.In the body, the chemical energy in food can be converted to any ofthe following except: light energy.272. In vegetarians, the RDA is higher for: iron273. In which of the following food groups are legumes found?: Meats274. Inflammation of the lar
Thomas Edison State - BIO - 208
294.People who have frequent regular bouts of heartburn andindigestion have a medical condition known as: gastroesophagealreflux.295. Population groups such as sedentary older men, sedentary youngerwomen, and active older women have a daily energy ne
Thomas Edison State - BIO - 208
322.323.324.325.326.327.328.329.330.331.332.333.334.335.336.337.338.339.340.341.342.343.344.345.346.347.The percentage of kcalorie intakes for protein, fat, andcarbohydrate that are thought to reduce the risk of chronicdiseases