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Course: CHEM 159 159, Fall 2011School: Rutgers
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Rutgers - CHEM 159 - 159
Chapter 1Keys to the Study ofKeysChemistryChemistry1-1Dr. Wolfs CHM 101Chapter 1 : Keys to the Study of Chemistry1.1 Some Fundamental Definitions1.2 Chemical Arts and the Origins of Modern Chemistry1.3 The Scientific Approach: Developing a Model
Rutgers - CHEM 159 - 159
Chapter 2The Components ofTheMatterMatter2-1Dr. Wolfs CHM 101Chapter 2: The Components of Matter2.1 Elements, Compounds, and Mixtures: An Atomic Overview2.2 The Observations That Led to an Atomic View of Matter2.3 Daltons Atomic Theory2.4 The O
Rutgers - CHEM 159 - 159
Chapter 3Stoichiometry3-1Dr. Wolfs CHM 101Mole - Mass Relationships in Chemical Systems3.1 The Mole3.2 Determining the Formula of an Unknown Compound3.3 Writing and Balancing Chemical Equations3.4 Calculating the Amounts of Reactant and Product3.
Rutgers - CHEM 159 - 159
Chapter 4The Major Classes ofChemical Reactions4-1Dr. Wolfs CHM 101The Major Classes of Chemical Reactions4.1 The Role of Water as a Solvent4.2 Writing Equations for Aqueous Ionic Reactions4.3 Precipitation Reactions4.4 Acid-Base Reactions4.5 Ox
Rutgers - CHEM 159 - 159
Chapter 5Gases and the KineticMolecular Theory5-1Dr. WolfsGases and the Kinetic Molecular Theory5.1 An Overview of the Physical States of Matter5.2 Gas Pressure and Its Measurement5.3 The Gas Laws and Their Experimental Foundations5.4 Further App
Rutgers - CHEM 159 - 159
Chapter 6Thermochemistry:Energy Flow andChemical Change6-1Thermochemistry: Energy Flow and Chemical Change6.1 Forms of Energy and Their Interconversion6.2 Enthalpy: Heats of Reaction and Chemical Change6.3 Calorimetry: Laboratory Measurement of He
Rutgers - CHEM 159 - 159
Chapter 7Quantum Theory andAtomic Structure7- 1Dr. Wolfs CHM 101Quantum Theory and Atomic Structure7.1 The Nature of Light7.2 Atomic Spectra7.3 The Wave-Particle Duality of Matter and Energy7.4 The Quantum-Mechanical Model of the Atom7- 2Dr. Wo
Rutgers - CHEM 159 - 159
Chapter 8Electron Configuration andChemical Periodicity8-1Dr. Wolfs CHM 101Electron Configuration and Chemical Periodicity8.1 Development of the Periodic Table8.2 Characteristics of Many-Electron Atoms8.3 The Quantum-Mechanical Model and the Perio
Rutgers - CHEM 159 - 159
Chapter 9Models of ChemicalBonding9-1Dr. Wolfs CHM 101Models of Chemical Bonding9.1 Atomic Properties and Chemical Bonds9.2 The Ionic Bonding Model9.3 The Covalent Bonding Model9.4 Between the Extremes: Electronegativity and Bond Polarity9.5 An
Rutgers - CHEM 159 - 159
Chapter 10The Shapes of Molecules10-1Dr. Wolfs CHM 101The Shapes of Molecules10.1 Depicting Molecules and Ions with Lewis Structures10.2 Using Lewis Structures and Bond Energies toCalculate Heats of Reaction10.3 Valence-Shell Electron-Pair Repulsi
Rutgers - CHEM 159 - 159
Chapter 11Image Slides**See PowerPoint Lecture Outline for a completeready-madepresentation integrating art and lecture notes.2004 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.ART & PHOTOSFig. 11.1Fig.
Rutgers - CHEM 159 - 159
Chapter 11Theories of Covalent Bonding11-1Theories of Covalent Bonding11.1 Valence Bond (VB) Theory and Orbital Hybridization11.2 The Mode of Orbital Overlap and the Types ofCovalent Bonds11.3 Molecular Orbital (MO)Theory and Electron Delocalizatio
Rutgers - CHEM 159 - 159
Power Point to AccompanyPrinciples and Applications ofInorganic, Organic, and BiologicalChemistryDenniston, Topping, and Caret4th edChapter 11Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.11-Organic Che
Rutgers - CHEM 159 - 159
Chapter 12Image Slides**See PowerPoint Lecture Outline for a completeready-madepresentation integrating art and lecture notes.2004 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.ART & PHOTOSFig. 12.1Fig.
Rutgers - CHEM 159 - 159
Chapter 12Intermolecular Forces:Liquids, Solids, and PhaseChanges12-1Intermolecular Forces:Liquids, Solids, and Phase Changes12.1 An Overview of Physical States and Phase Changes12.2 Quantitative Aspects of Phase Changes12.3 Types of Intermolecul
Rutgers - CHEM 159 - 159
Power Point to AccompanyPrinciples and Applications ofInorganic, Organic, andBiologicalChemistryDenniston, Topping, and CaretChapter 124th edCopyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.12-112.1 Alken
Rutgers - CHEM 159 - 159
Chapter 13Image Slides**See PowerPoint Lecture Outline for a completeready-madepresentation integrating art and lecture notes.2004 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.ART & PHOTOSFig. 13.1Fig.
Rutgers - CHEM 159 - 159
Power Point to AccompanyPrinciples and Applications ofInorganic, Organic, andBiological ChemistryDenniston, Topping, and Caret4th edChapter 13Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.13-1FormulasA
Rutgers - CHEM 159 - 159
Chapter 14Image Slides**See PowerPoint Lecture Outline for a completeready-madepresentation integrating art and lecture notes.2004 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.ART & PHOTOSFig. 14.1Fig.
Rutgers - CHEM 159 - 159
Power Point to AccompanyPrinciples and Applications ofInorganic, Organic, and BiologicalChemistryDenniston, Topping, and Caret4th edChapter 14Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.1Carbonyl Comp
Rutgers - CHEM 159 - 159
Chapter 15Image Slides**See PowerPoint Lecture Outline for a completeready-madepresentation integrating art and lecture notes.2004 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.ART & PHOTOSFig. 15.1Fig.
Rutgers - CHEM 159 - 159
Power Point to AccompanyPrinciples and Applications ofInorganic, Organic, and BiologicalChemistryDenniston, Topping, and Caret4th edChapter 15Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.15-1Functional
Rutgers - CHEM 159 - 159
Chapter 16Image Slides**See PowerPoint Lecture Outline for a completeready-madepresentation integrating art and lecture notes.2004 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.ART & PHOTOSFig. 16.1Fig.
Rutgers - CHEM 159 - 159
Power Point to AccompanyPrinciples and Applications ofInorganic, Organic, and BiologicalChemistryDenniston, Topping, and Caret4th edChapter 16Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.16-116.1 Amine
Rutgers - CHEM 159 - 159
Chapter 17Image Slides**See PowerPoint Lecture Outline for a completeready-madepresentation integrating art and lecture notes.2004 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.ART & PHOTOSCO17Fig. 17.1
Rutgers - CHEM 159 - 159
Power Point to AccompanyPrinciples and Applications ofInorganic, Organic, andBiological ChemistryDenniston, Topping, and Caret4th edChapter 17Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.17-1Introducti
Rutgers - CHEM 159 - 159
Chapter 18Image Slides**See PowerPoint Lecture OutlineFor a completeready-madepresentation integrating art and lecture notes.2004 Copyright The McGraw-Hill Companies, Inc. Permission requiredFor reproduction or display.ART & PHOTOSFig. 18.1Fig. 18
Rutgers - CHEM 159 - 159
Power Point to AccompanyPrinciples and Applications ofInorganic, Organic, andBiological ChemistryDenniston, Topping, and Caret4th edChapter 18Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.18-118.1 Lipid
Rutgers - CHEM 159 - 159
Chapter 19Image Slides**See PowerPoint Lecture OutlineFor a completeready-madepresentation integrating art and lecture notes.2004 Copyright The McGraw-Hill Companies, Inc. Permission requiredFor reproduction or display.ART & PHOTOSFig. 19.1Fig. 19
Rutgers - CHEM 159 - 159
Power Point to AccompanyPrinciples and Applications ofInorganic, Organic, andBiological ChemistryDenniston, Topping, and Caretth4 edChapter 19Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.19-1Introduct
Rutgers - CHEM 159 - 159
Chapter 20Image Slides**See PowerPoint Lecture Outline for a completeready-madepresentation integrating art and lecture notes.2004 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.ART & PHOTOSCO20Fig. 20.1
Rutgers - CHEM 159 - 159
Power Point to AccompanyPrinciples and Applications ofInorganic, Organic, and BiologicalChemistryDenniston, Topping, and Caret4th edChapter 20Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.20-1Introducti
Rutgers - CHEM 159 - 159
Chapter 21Image Slides**See PowerPoint Lecture Outline for a completeready-madepresentation integrating art and lecture notes.2004 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.ART & PHOTOSCO21Fig. 21.1
Rutgers - CHEM 159 - 159
Power Point to AccompanyPrinciples and Applications ofInorganic, Organic, andBiologicalChemistryDenniston, Topping, and Caretth4 edChapter 21Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.21-1Introducti
Rutgers - CHEM 159 - 159
Chapter 22Image Slides**See PowerPoint Lecture Outline for a completeready-madepresentation integrating art and lecture notes.2004 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.ART & PHOTOSFig. 22.2Fig.
Rutgers - CHEM 159 - 159
Power Point to AccompanyPrinciples and Applications ofInorganic, Organic, and BiologicalChemistryDenniston, Topping, and Caret4th edChapter 22Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.22-122.1 The M
Rutgers - CHEM 159 - 159
Chapter 23Image Slides**See PowerPoint Lecture Outline for a completeready-madepresentation integrating art and lecture notes.2004 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.ART & PHOTOSCO23Fig. 23.1
Rutgers - CHEM 159 - 159
Power Point to AccompanyPrinciples and Applications ofInorganic, Organic, and BiologicalChemistryDenniston,Topping, and Caret4th edChapter 23Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.23-1Introductio
Rutgers - CHEM 159 - 159
Power Point to AccompanyPrinciples and Applications ofInorganic, Organic, andBiological ChemistryDenniston, Topping, and Caret4th edChapter 24Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.24-124.1Struct
Rutgers - CHEM 159 - 159
Chapter 26LipidsDr. Wolf's CHM 42426- 1LipidsLipids are naturally occurring substancesLipidsgrouped together on the basis of a commonpropertythey are more soluble in nonpolarsolvents than in water.solventsSome of the most important of themthe o
Rutgers - CHEM 159 - 159
Chapter 27Amino Acids, Peptides,Aminoand ProteinsandDr. Wolf's CHM 42427- 127.1Classification of Amino AcidsDr. Wolf's CHM 42427- 2FundamentalsWhile their name implies that amino acids areWhilecompounds that contain an NH2 group and acompou
Rutgers - CHEM 159 - 159
Chapter 28Nucleosides, Nucleotides,and Nucleic AcidsDr. Wolf's CHM 42428- 128.1Pyrimidines and PurinesDr. Wolf's CHM 42428- 2Pyrimidines and PurinesIn order to understand the structure andInproperties of DNA and RNA, we need to look attheir s
Rutgers - CHEM 159 - 159
1. Structure and BondingBased on McMurrys Organic Chemistry, 6th edition, Chapter 1 2003 Ronald Kluger Department of Chemistry University of TorontoOrganic Chemistry Organic until mid 1800s referred to compoundsfrom living sources (mineral sources wer
Rutgers - CHEM 159 - 159
1. Structure and BondingBased on McMurrys Organic Chemistry, 8th editionWhat is Organic Chemistry? Living things are made of organic chemicals Proteins that make up hair DNA, controls genetic make-up Foods, medicines Examine structures below23Or
Rutgers - CHEM 159 - 159
2. Polar Covalent Bonds: Acids and BasesBased on McMurrys Organic Chemistry, 6th edition, Chapter 2 2003 Ronald Kluger Department of Chemistry University of Toronto2.1 Polar Covalent Bonds: Electronegativity Covalent bonds can have ionic character Thes
Rutgers - CHEM 159 - 159
2. Polar Covalent Bonds:Acids and BasesBased on McMurrys Organic Chemistry, 8th editionWhy this chapter? Description of basic ways chemists accountfor chemical reactivity. Establish foundation for understandingspecific reactions discussed in subseq
Rutgers - CHEM 159 - 159
3. Organic Compounds: Alkanes and CycloalkanesBased on McMurrys Organic Chemistry, 6th edition, Chapter 3 2003 Ronald Kluger Department of Chemistry University of TorontoFamilies of Organic Compounds Organic compounds can be grouped into familiesby th
Rutgers - CHEM 159 - 159
3. Organic Compounds:Alkanes and TheirStereochemistryBased on McMurrys Organic Chemistry, 7th editionWhy this Chapter Alkanes are unreactive, but provide useful vehicle tointroduce important ideas about organic compounds Alkanes will be used to dis
Rutgers - CHEM 159 - 159
4. Stereochemistry of Alkanes and CycloalkanesBased on McMurrys Organic Chemistry, 6th edition, Chapter 4 2003 Ronald Kluger Department of Chemistry University of TorontoThe Shapes of Molecules The three-dimensional shapes of molecules resultfrom many
Rutgers - CHEM 159 - 159
6. Alkenes: Structure and ReactivityBased on McMurrys Organic Chemistry, 6th edition 2003 Ronald Kluger Department of Chemistry University of TorontoAlkene - Hydrocarbon With CarbonCarbon Double Bond Also called an olefin but alkene is better Includes
Rutgers - CHEM 159 - 159
7. Alkenes: Reactions and SynthesisBased on McMurrys Organic Chemistry, 6th edition 2003 Ronald Kluger Department of Chemistry University of TorontoDiverse Reactions of Alkenes Alkenes react with many electrophiles to give usefulproducts by addition (
Rutgers - CHEM 159 - 159
Alkynes: An Introduction to Organic SynthesisBased on McMurrys Organic Chemistry, 6th edition, Chapter 82003 Ronald Kluger Department of Chemistry University of TorontoAlkynes Hydrocarbons that contain carbon-carbontriple bonds Acetylene, the simples
Rutgers - CHEM 159 - 159
John E. McMurrywww.cengage.com/chemistry/mcmurryChapter 8Alkenes: Reactions andSynthesisPaul D. Adams University of ArkansasDiverse Reactions of AlkenesAlkenes react with many electrophiles to give useful productsby addition (often through special
Rutgers - CHEM 159 - 159
9. StereochemistryBased on McMurrys Organic Chemistry, 6th edition2002 Ronald Kluger Department of Chemistry University of TorontoStereochemistry Some objects are not the same as their mirrorimages (technically, they have no plane of symmetry) A righ
Rutgers - CHEM 159 - 159
10. Alkyl HalidesBased on McMurrys Organic Chemistry, 6th edition2003 Ronald Kluger Department of Chemistry University of TorontoWhat Is an Alkyl Halide An organic compound containing at least one carbon-halogen bond (C-X) X (F, Cl, Br, I) replaces H
Rutgers - CHEM 159 - 159
11. Reactions of Alkyl Halides:Nucleophilic Substitutions andEliminationsBased on McMurrys Organic Chemistry, 6thedition2003 Ronald KlugerDepartment of ChemistryUniversity of TorontoAlkyl Halides React with Nucleophilesand Bases Alkyl halides ar
Rutgers - CHEM 159 - 159
12. Structure Determination: MassSpectrometry and InfraredSpectroscopyBased onMcMurrys Organic Chemistry, 6th edition2003 Ronald KlugerDepartment of ChemistryUniversity of TorontoDetermining the Structure of anOrganic Compound The analysis of th
Rutgers - CHEM 159 - 159
13. Structure Determination:Nuclear Magnetic ResonanceSpectroscopyBased onMcMurrys Organic Chemistry, 6th edition2003 Ronald KlugerDepartment of ChemistryUniversity of TorontoThe Use of NMR Spectroscopy Used to determine relative location of atom