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TheScienceandEngineeringof
Materials,4thed
DonaldR.AskelandPradeepP.Phul
Chapter19MagneticMaterials
1
ObjectivesofChapter19
Tostudythefundamentalbasisforresponsesof
certainmaterialstothepresenceofmagnetic
fields.
Toexaminethepropertiesandapplicationsof
differenttypesofmagneticmaterials.
2
ChapterOutline
19.1ClassificationofMagneticMaterials
19.2MagneticDipolesandMagneticMoments
19.3Magnetization,Permeability,andthe
MagneticField
19.4Diamagnetic,Paramagnetic,Ferromagnetic,
Ferrimagnetic,andSuperparamagnetic
Materials
19.5DomainStructureandtheHysteresisLoop
19.6TheCurieTemperature
19.7ApplicationsofMagneticMaterials
19.8MetallicandCeramicMagneticMaterials
3
Section19.1
ClassificationofMagneticMaterials
Ferromagnetism
Ferrimagnetism
Diamagnetism
Antiferromagnetism
Hardmagnet
4
Section19.2Magnetic
DipolesandMagneticMoments
Themagneticbehaviorofmaterialscanbetracedtothe
structureofatoms.
BohrmagnetonThestrengthofamagneticmomentofan
electron(B)duetoelectronspin.
5
2003 Brooks/Cole, a division of Thomson Learning, Inc. Thomson Learning is a trademark used herein under license.
Figure19.1Originofmagneticdipoles:(a)Thespinoftheelectron
producesamagneticfieldwithadirectiondependentonthequantum
numberms.(b)ElectronsElectronsorbitingaroundthenucleuscreatea
magneticfieldaroundtheatom.
6
7
Section19.3
Magnetization,Permeability,andtheMagnetic
Field
MagneticpermeabilityTheratiobetweeninductanceor
magnetizationandmagneticfield.Itisameasureoftheease
withwhichmagneticfluxlinescanflowthroughamaterial.
MagnetizationThetotalmagneticmomentperunitvolume.
MagneticsusceptibilityTheratiobetweenmagnetizationand
theappliedfield.
8
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Figure19.2AcurrentpassingthroughacoilsetsupamagneticfieldHwith
afluxdensityB.Thefluxdensityishigherwhenamagneticcoreisplaced
withinthecoil.
9
10
Example19.1
TheoreticalandActualSaturationMagnetization
inFe
Calculatethemaximum,orsaturation,magnetizationthatweexpectin
iron.ThelatticeparameterofBCCironis2.866.Comparethisvalue
with2.1tesla(avalueofsaturationfluxdensityexperimentallyobserved
forpureFe.)
Example19.1SOLUTION
Basedontheunpairedelectronicspins,weexpecteachironatomto
havefourelectronsthatactasmagneticdipoles.Thenumberofatoms
perm3inBCCironis:
11
Example19.1SOLUTION(Continued)
Themaximumvolumemagnetization(Msat)isthetotalmagnetic
momentperunitvolume:
ToconvertthevalueofsaturationmagnetizationMintosaturationflux
densityBintesla,weneedthevalueof0M.Inferromagneticmaterials
0M>>0Handtherefore,B0M.
Saturationinductionintesla=Bsat=0Msat.
12
Section19.4
Diamagnetic,Paramagnetic,Ferromagnetic,
Ferrimagnetic,andSuperparamagnetic
Materials
FerromagnetismAlignmentofthemagneticmomentsofatoms
inthesamedirectionsothatanetmagnetizationremainsafter
themagneticfieldisremoved.
FerrimagnetismMagneticbehaviorobtainedwhenionsina
materialhavetheirmagneticmomentsalignedinanantiparallel
arrangementsuchthatthemomentsdonotcompletelycancel
outandanetmagnetizationremains.
DiamagnetismTheeffectcausedbythemagneticmomentdue
totheorbitingelectrons,whichproducesaslightoppositionto
theimposedmagneticfield.
13
Section19.4(Continued)
AntiferromagnetismArrangementofmagneticmomentssuch
thatthemagneticmomentsofatomsorionscanceloutcausing
zeronetmagnetization.
HardmagnetFerromagneticorferrimagneticmaterialthathas
acoercivity>104A.m1.
14
2003 Brooks/Cole, a division of Thomson Learning, Inc. Thomson Learning is a trademark used herein under license.
Figure19.3Theeffect
ofthecorematerialon
thefluxdensity.The
magneticmoment
opposesthefieldin
diamagneticmaterials.
Progressivelystronger
momentsarepresentin
paramagnetic,
ferrimagnetic,and
ferromagneticmaterials
forthesameapplied
field.
15
2003 Brooks/Cole, a division of Thomson Learning, Inc. Thomson Learning is a trademark used herein under license.
Figure19.4Thecrystal
structureofMn0consists
ofalternatinglayersof
{111}typeplanesof
oxygenandmanganese
ions.Themagnetic
momentsofthe
manganeseionsinevery
other(111)planeare
oppositelyaligned.
Consequently,Mn0is
antiferromagnetic.
16
Example19.2
Design/MaterialsSelectionforaSolenoid
Wewanttoproduceasolenoidcoilthatproducesaninductance
ofatleast2000gausswhena10mAcurrentflowsthroughthe
conductor.Duetospacelimitations,thecoilshouldbecomposed
of10turnsovera1cmlength.Selectacorematerialforthecoil.
17
18
Example19.2SOLUTION
ThemagneticfieldHproducedbythecoil.
Thepermeabilityofthecorematerialmustbe:
Therelativepermeabilityofthecorematerialmustbeatleast:
FromTable194,wefindthat479permalloyhasamaximum
relativepermeabilityof80,000andmightbeagoodselectionforthe
corematerial.
19
Section19.5Domain
Structureandthe
HysteresisLoop
DomainsSmallregionswithinasingleorpolycrystallinematerial
inwhichallofthemagnetizationdirectionsarealigned.
BlochwallsTheboundariesbetweenmagneticdomains.
SaturationmagnetizationWhenallofthedipoleshavebeen
alignedbythefield,producingthemaximummagnetization.
RemananceThepolarizationormagnetizationthatremainsina
materialafterithasbeenremovedfromthefield.
HysteresisloopThelooptracedoutbymagnetizationina
ferromagneticorferrimagneticmaterialasthemagneticfieldis
cycled.
20
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Figure19.5(a)Aqualitativesketchofmagneticdomainsina
polycrystallinematerial.Thedashedlinesshowdemarcationbetween
differentmagneticdomains;thedarkcurvesshowthegrainboundaries.
(b)Themagneticmomentsinadjoiningatomschangedirection
continuouslyacrosstheboundarybetweendomains.
21
2003 Brooks/Cole, a division of Thomson Learning, Inc. Thomson Learning
is a trademark used herein under license.
Figure19.6Whenamagneticfieldisfirstappliedtoamagneticmaterial,
magnetizationinitiallyincreasesslowly,thenmorerapidlyasthedomains
begintogrow.Later,magnetizationslows,asdomainsmusteventuallyrotate
toreachsaturation.Noticethepermeabilityvaluesdependuponthe
magnitudeofH.
22
Figure19.7(a)TheferromagnetichysteresisMHloopshowingtheeffectofthe
magneticfieldoninductanceormagnetization.Thedipolealignmentleadsto
saturationmagnetization(point3),aremanance(point4),andacoercivefield
(point5).(b)ThecorrespondingBHloop.NoticetheendoftheBHloop,theB
valuedoesnotsaturatesinceB=0H+0M.(Source:AdaptedfromPermanent
Magnetism,byR.SkomskiandJ.M.D.Coey,p.3,Fig.11.EditedbyJ.M.D.Coey
andD.R.Tilley.Copyright1999InstituteofPhysicsPublishing.Adaptedby
permission.)
23
Section19.6The
CurieTemperature
CurietemperatureThetemperatureabove(Tc)which
ferromagneticorferrimagneticmaterialsbecomeparamagnetic.
24
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Figure19.8Theeffectoftemperatureon(a)thehysteresisloopand(b)
theremanance.FerromagneticbehaviordisappearsabovetheCurie
temperature.
25
26
Example19.3
Design/MaterialsSelectionfora
HighTemperatureMagnet
Selectapermanentmagnetforanapplicationinanaerospacevehicle
thatmustreenterEarthsatmosphere.Duringreentry,themagnetmay
beexposedtomagneticfieldsashighas600oerstedandmaybriefly
reachtemperaturesashighas500oC.Wewantthematerialtohavethe
highestpowerpossibleandtomaintainitsmagnetizationafterreentry.
27
28
Example19.3SOLUTION
Itisfirstnecessarytoselectpotentialmaterialshavingsufficient
coercivefieldHcandCurietemperaturethatreentrywillnot
demagnetizethem.
TheCo5SmhasfourtimesthepoweroftheAlnico5and,basedon
performance,mightbeourbestchoice.
29
Section19.7
ApplicationsofMagneticMaterials
SoftMagneticMaterialsFerromagneticmaterialsareoftenused
toenhancethemagneticfluxdensity(B)producedwhenan
electriccurrentispassedthroughthematerial.Applications
includecoresforelectromagnets,electricmotors,transformers,
generators,andotherelectricalequipment.
DataStorageMaterialsMagneticmaterialsareusedfordata
storage.
PermanentMagnetsMagneticmaterialsareusedtomake
strongpermanentmagnets
PowerThestrengthofapermanentmagnetasexpressedby
themaximumproductoftheinductanceandmagneticfield.
30
Figure19.9(a)Comparisonofthehysteresisloopsfor
threeapplicationsofferromagneticandferrimagnetic
materials.
31
Figure19.9(b)Saturationmagnetizationandcoercivityvaluesfordifferent
magneticmaterials.(Source:AdaptedfromMagneticMaterials:An
Overview,BasicConcepts,MagneticMeasurements,Magnetostrictive
Materials,byG.Y.Chinetal.InD.Bloor,M.Flemings,andS.Mahajan
(Eds.),EncyclopediaofAdvancedMaterials,Vol.1,1994,p.1423,Fig.1.
Copyright1994PergamonPress.Reprintedbypermissionoftheeditor.)
32
33
34
35
Figure19.10(a)Thelargestrectangledrawninthesecondorfourthquadrantof
theBHcurvegivesthemaximumBHproduct.(BH)maxisrelatedtothepower,or
energy,requiredtodemagnetizethepermanentmagnet.(b)Developmentof
permanentmagnetmaterials,maximumenergyproductisshownontheyaxis.
(Source:AdaptedfromPermanentMagnetism,byR.SkomskiandJ.M.D.Coey,p.
23,Table12.EditedbyJ.M.D.CoeyandD.R.Tilley.Copyright 1999Instituteof
PhysicsPublishing.Adaptedbypermission.)
36
Example19.4Energy
ProductforPermanentMagnets
2003 Brooks/Cole, a division of Thomson Learning, Inc. Thomson Learning is a trademark used
herein under license.
Determinethepower,orBHproduct,forthemagneticmaterialwhose
propertiesareshowninFigure19.11.
Figure19.11Thefourthquadrant
oftheBHcurveforapermanent
magneticmaterial(forExample
19.4)
37
Example19.4SOLUTION
Severalrectangleshavebeendrawninthefourthquadrantofthe
BHcurve.TheBHproductineachis:
Thus,thepowerisabout4.2 106gauss.oersted.
38
Example19.5
Design/SelectionofMagneticMaterials
Selectanappropriatemagneticmaterialforthefollowingapplications:a
highelectricalefficiencymotor,amagneticdevicetokeepcupboard
doorsclosed,amagnetusedinanammeterorvoltmeter,andmagnetic
resonanceimaging.
Example19.5SOLUTION
Highelectricalefficiencymotor:Tominimizehysteresislosses,
wemightuseanorientedsiliconiron,takingadvantageofits
anisotropicbehavioranditssmallhysteresisloop.
Magnetforcupboarddoors:Themagneticlatchesusedto
fastencupboarddoorsmustbepermanentmagnets;however,lowcost
isamoreimportantdesignfeaturethanhighpower.Aninexpensive
ferriticsteeloralowcostferritewouldberecommended.
39
Example19.5SOLUTION(Continued)
Magnetsforanammeterorvoltmeter:Forthese
applications,Alnicoalloysareparticularlyeffective.Wefindthat
thesealloysareamongtheleastsensitivetochangesin
temperature,assuringaccuratecurrentorvoltagereadingsovera
rangeoftemperatures.
Magneticresonanceimaging:Oneoftheapplicationsfor
MRIisinmedicaldiagnostics.Inthiscase,wewantaverypowerful
magnet.ANd2Fe12Bmagneticmaterial,whichhasanexceptionally
highBHproduct,mightberecommendedforthisapplication.We
canalsomakeuseofverystrongelectromagnetsmadeusing
superconductors.
40
Example19.6Lifting
PowerofaMagnet
CalculatetheforceinkNforonesquaremeterareaofapermanent
magnetwhosesaturationmagnetizationis1.61tesla.
Example19.6SOLUTION
Wehavebeengiventhevalueof0M=1.61tesla.Wecanrewritethe
equationthatprovidestheforceduetoapermanentmagnetasfollows.
41
Section19.8Metallic
andCeramicMagneticMaterials
MagnetocrystallineanisotropyInsinglecrystals,thecoercivity
dependsuponcrystallographicdirectioncreatingeasyandhard
axesofmagnetization.
42
2003 Brooks/Cole, a division of Thomson Learning, Inc. Thomson Learning is a trademark used herein under license.
Figure19.12Informationcanbestoredorretrievedfromamagneticdiskby
useofanelectromagnetichead.Acurrentintheheadmagnetizesdomainsin
thediskduringstorage;thedomainsinthediskinduceacurrentinthehead
duringretrieval.
43
Figure19.13Theinitialmagnetizationcurveforironishighly
anisotropic;magnetizationiseasiestwhenthedirections100
arealignedwiththefieldandhardestalong[111].(Source:From
PrinciplesofElectricalEngineeringMaterialsandDevices,byS.O.
Kasap,p.623,Fig.824.Copyright1997Irwin.Reprintedby
permissionofTheMcGrawHillCompanies.)
44
2003 Brooks/Cole, a division of Thomson Learning, Inc. Thomson Learning is a trademark used herein under license.
Figure19.14DemagnetizingcurvesforCo5SmandCo5Ce,representinga
portionofthehysteresisloop.
45
2003 Brooks/Cole, a division of Thomson Learning, Inc. Thomson Learning is a trademark used herein under license.
Figure19.15(a)Thestructureofmagnetite,Fe304.(b)Thesubcellof
magnetite.Themagneticmomentsofionsintheoctahedralsiteslineup
withthemagneticfield,butthemagneticmomentsofionsintetrahedral
sitesopposethefield.Anetmagneticmomentisproducedbythisionic
arrangement.
46
Example19.7
MagnetizationinMagnetite(Fe3O4)
Calculatethetotalmagneticmomentpercubiccentimeterinmagnetite.
Calculatethevalueofthesaturationfluxdensity(Bsat)forthismaterial.
Figure19.15(b)The
subcellofmagnetite.
47
Example19.7SOLUTION
Intheunitcelloverall,thereareeightsubcells,sothetotalmagnetic
momentis32Bohrmagnetonspercell.Thesizeoftheunitcell,
withalatticeparameterof8.37 108cm,is:
Themagneticmomentpercubiccentimeteris:
ThisexpressionrepresentsthemagnetizationMatsaturation(Msat).
ThevalueofBsat0Msatwillbe=(4 107)(5.1 105)=
0.64Tesla.
48
49
Example19.8
Design/MaterialsSelectionfor
aCeramicMagnet
Designacubicferritemagnetthathasatotalmagneticmomentper
cubicmeterof5.5 105A/m.
50
Example19.8SOLUTION
AssumingthattheadditionofMnionsdoesnotappreciablyaffect
thesizeoftheunitcell,wefindfromExample197that:
LetxbethefractionofMn2+ionsthathavereplacedtheFe2+ions,
whichhavenowbeenreducedto1x.Then,thetotalmagnetic
momentis:
Thereforeweneedtoreplace34.6at%oftheFe2+ionswithMn2+
ionstoobtainthedesiredmagnetization.
51
2003 Brooks/Cole, a division of Thomson Learning, Inc. Thomson Learning is a trademark used herein under license.
Figure19.16
Hysteresiscurvefora
hardmagneticmaterial
(forProblem19.19).
52
2003 Brooks/Cole, a division of Thomson Learning, Inc. Thomson Learning is a trademark used herein under license.
Figure19.17Hysteresiscurveforahardmagneticmaterial(for
Problem19.30).
53
2003 Brooks/Cole, a division of Thomson Learning, Inc. Thomson Learning is a trademark used herein under
license.
Figure19.14(RepeatedforProblem19.36.)Demagnetizingcurvesfor
Co5SmandCo5Ce,representingaportionofthehysteresisloop.
54
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TheScienceandEngineeringofMaterials,4thedDonaldR.AskelandPradeepP.PhulChapter20PhotonicMaterials1ObjectivesofChapter20Topresentasummaryoffundamentalprinciplesthathaveguidedapplicationsofopticalmaterials.Toexploretwoavenuesbywhichwecanusetheoptica
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Constant: K 20log[abs(k)] k>0 0 degrees k<0 -180 degrees Pole at Origin (Integrator) -20 dB/decade passing through 0 dB at w=1 -90 degrees Zero at Origin (Differentiator) +20 dB/decade passing through 0 dB at w=1 +90 degrees Real Pole
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MATLAB Tutorial IRepresentation of transfer function:b0 sm + b1sm,1 + bm:i T s = na0 s + a1 sn,1 + anMATLAB command isnum = b0 b1 bm ;den = a0 a1 an ;s , z1s , z2 s , zmii T s = K:s , p1s , p2 s , pnMATLAB command isK = ;Z = z1 z2 zm ;P =
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Procedure for Skecth of root locus page 260 of text:Example 1: Gs = s + 1=s2= z1 = ,1; p1 = p2 = 0 and n , m = 1.Step 1: Mark the poles and zeros on the s-plane.Step 2: Draw locus on the real axis: left of s = ,1.Step 3: Draw asymptotes: since n , m
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Zero-degree Loci for Negative KWe considersm + b1sm,1 + + bm :KGs = ,jK j sn + a sn,1 + + a1nBy convention, we have1 + KGs = 0; K = 0 ! ,1:The angle of Gs is 0o + 360o lChange: 180o + 360o is replaced by 0o + 360o l.On real axis: the number of p
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x6. Frequency-Response Design Methods1. Frequency Response:We recall inverse Laplace transform:23K5K4L,1 6 s , j! + s + j! 7 = 2jK j cos!ot + 6 K :ooConsider sinusoidal input signalut = Au cos!otapplied to a plant Gs. Then the output in s-dom
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Example Prob. 6.50 on page 456:K:s1 + s=51 + s=20Design a compensator such thatKGs =ess 0:01 for unit ramp input.P.M.= 45o 3o.ess 1=250 for sinusoidal input with !0:2.Noise be attenuated by a factor of 100 for ! 100.Analysis:essto 1=250 for
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Iterative Design AlgorithmWe consider an iterative design method: (a) Design zy , z , and Ky > 0, such that the three zeros of(s) = 0 are in the right locations.z5.67zy5.67 (b) Design Kgy and pg such that the roots of (s) = (s + pg )denp(s) + 3.2
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Solution to Homework 2 of EE4002, Spring 2004
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Solution to Homework 6 of EE4002 Spring 2004
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Solution to Homework 7EE4002, Spring 2004
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Solution to Homework 8 of EE4002 Spring 2004
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Solution to Midterm Test1. For the lead compensator, we havedB20.2220200degree45.2220200For the lag compensator, we havedB20.2220200220200degree.204512. (a) For the gain plot, we choose L = 0.1, and H = 1000. Hence we have at
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Correction to 5-11 of HW4 EE4580 Fall041) The closed-loop transfer function is10 K1Y ( s)Gc ( s ) ==(1)R( s ) s ( s + )( s + 10) + s ( s + ) + 2 K1 s + 10 K1You can use direct computation, Masons rule or block diagram simplification methodto get
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Solution to HW5 of EE4580 Fall04
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6.4a6.4b6.4c6.4d
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6.5a6.5b6.5c6.5d6.5e-GAVE ME A WARNING SIGN6.5f- GAVE ME A WARNING SIGN
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Solution to Homework 6 of EE4580 Fall04
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Solution to Homework 7 of EE4580 Fall04
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Solution to Homework 8 of EE4580 Fall04
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ZOOMED IN PLOTS FROM LAST SEMESTERS HOMEWORK 5.5A,C,E
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Solution7Ch6_5,7,30,316.5 Solution:(a) L ( s ) = #s102110+310s +150P ha se ( d eg)0-50-100-150-20010-110010F r eq uency ((b) L(s) =s110s102+310 s1102r a d/sec)+1-50P hase (deg)-100-150-200-250-30010-1100
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Solution8 Ch6_43,45,(47),50,576.43 Solution:(a) The frequency response is obtained by letting s = j ,D (j ) = KT j + 1T j + 1The phase is given by, = tan1 (T ) tan1 (T )(b) Using the trigonometric relationship,tan(A B ) =tan(A) tan(B )1 + tan(A)
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Solution9 Ch6_18,19,37,396.18 Solution:(a)1s2Note that the portion of the Nyquist diagram on the right side belowthat corresponds to the bode plot is from B to C. The large loopfrom F to A to B arises from the detour around the 2 poles at theorigi
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EEE 480HW # 6 SOLUTIONSProblem 5.21The root-locus asymptotes for pure-gain compensation are at 2:5. Since the required closed-loop polelocations are 1 j , we need to introduce a lag compensator. Observe that asymptotes at 1 are obtained forpoles at 0
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Solution to Homework 6 of EE4002 Spring 2004
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Problem 6.25Using the MATLAB command[GM PM]=margin(sys) we findGM = 1.57 and PM = 100.55From the Bode plot it can be observedthat the gain margin is so small that aslight increase in gain may result inunstable closed loop system. The phase onthe o
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Problem 6Problem 6.25Using theMATLABcommand[GM PM]=margin(sys)we findGM = 1.57 andPM = 100.55From the Bodeplot it can beobserved thatthe gainmargin is sosmall that aslight increasein gain mayresult inunstableclosed loopsystem. Thepha