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University of Texas - CH - 302
Version 001 Exam 4 vanden bout (51640)This print-out should have 31 questions.Multiple-choice questions may continue onthe next column or page nd all choicesbefore answering.ChemPrin3e T17 19001 10.0 pointsBombarding 54 Fe with a neutron results in
University of Texas - CH - 302
Version 001 Exam 3 vanden bout (51640)This print-out should have 31 questions.Multiple-choice questions may continue onthe next column or page nd all choicesbefore answering.Msci 21 1208001 10.0 pointsConsider the following electrode reactions:Fe3
University of Texas - CH - 302
Version 001 Exam 2 vanden bout (51640)This print-out should have 32 questions.Multiple-choice questions may continue onthe next column or page nd all choicesbefore answering.Msci 20 0317001 10.0 pointsHow many mL of a 0.001 M chloride solutionmust
University of Texas - CH - 302
Version 001 Exam 1 vanden bout (51640)VDB Phase Change Thermo Signs 001001 10.0 pointsSubstance A has undergone a phase transition (under constant pressure) whereH = 10kJ/mol and S = 36J/K mol.What phase transition could have occurred?1. freezing2.
UGA - CHEM 2212 - 234-54
Chapter12:IdentifyingOrganicCompoundsMassSpectrometryInfraredSpectroscopyNuclearMagneticResonanceSpectroscopy(NMR)MassSpec:1.Sampleisvaporizedintothespectrometer2.SampleisbombardedbyhighenergyelectronsResults:Title:Jul2711:07AM(1of11)Title:Nov154
UGA - CHEM 2212 - 234-54
Chapter13:NuclearMagneticResonanceSpectroscopy(NMR)MapofthecarbonhydrogenframeworkwithinamoleculeHydrogen(H1)andCarbon13(C13)nucleiare:Thesenucleicanbeinfluencedbyanexternalmagneticfield(Bo)LakeandStreamAnalogyTherearetwowaystoaligntoamagneticfield:
UGA - CHEM 2212 - 234-54
CHEM2212:FundamentalsinModernOrganicChemistryIIChapter14:ConjugatedDienes&UltravioletSpectroscopyPolyunsaturatedSystemsExamples:1SpecificFocus:Subcategories:1.)NonConjugated:2.)Cojugated:2Subcategories(cont'd):Miscellaneous:Enynes:Enones:3N
UGA - CHEM 2212 - 234-54
Chapter15:BenzeneandAromaticityAromaticCompounds:UnsaturatedcyclicsystemsthatundergosubstitutionratherthanadditionExamples:1I.Nomenclature:IUPACSystemMonosubstitutedbenzenes:Examples:Ifthealkylsubstituentisthesamesizeorsmallerthanthering(sixorfew
UGA - CHEM 2212 - 234-54
Chapter16:ReactionsofBenzeneandItsDerivativesNoelectrophilicadditionreactionsoccurDuetoalossofaromaticstabilizationenergyUndergoelectrophilicaromaticsubstitutionreactions(EAS)Benzenepielectronsactasalewisbase(edonor)Electrophilicspeciesactsasalewisac
UGA - CHEM 2212 - 234-54
Chapter17:AlcoholsandPhenolsGeneralDefinitions:Alcohols: ContainanOHgroupattachedtoasp 3carbonatomExample:Phenols: ContainanOHgroupattacheddirectlytoabenzeneringExample:Enols: ContainanOHgroupattachedtoavinyliccarbonatomExample:Title:Jun268:56AM(1
UGA - CHEM 2212 - 234-54
Chapter18:Ethers,Epoxides,Thiols,andSulfidesEthers:Relativelyunreactive/stable.Goodforsolvents.Canformexplosiveperoxides(ROOR')QuickStructuralComparisons:Alcohols:Ethers:Thiols:Sulfides:1EtherNomenclature:Method1:Inthecaseofsimpleetherswithnoo
UGA - CHEM 2212 - 234-54
Chapter19: AldehydesandKetones:NucleophilicAdditionReactionsGeneralStructures:AldehydesKetonesCharacterizedbythepresenceofacarbonylfunctionalgroupCarefullyreadoverthecarbonylcompoundpreviewfoundonpages686694(Mandatory)Title:Page0of0Aldehydes:Nomen
UGA - CHEM 2212 - 234-54
Chapter20:CarboxylicAcidsandNitrilesCarboxlyicAcids:NomenclatureTherearetwowaystonamecarboxylicacids.Thesystemuseddependsonthecomplexityofthecompound1. Replacethe"e"ofthealkanenamewith"oicacid"Thecarbonylcarboniscarbon1fortheparentchainExamples:2.
UGA - CHEM 2212 - 234-54
Chapter21:CarboxylicAcidDerivativesandNucleophilicAcylSubstitutionsReactionsGeneralOverviewofCarboxylicCompounds:Structure:acylgroupbondedto"Y"(anelectronegativeatom/group)YGroup= Halide,acyloxy,alkoxy,amine,thiolate,phosphateCarboxylicAcidEsterAci
UGA - CHEM 2212 - 234-54
Chapter22CarbonylAlphaSubstitutionReactionsGeneralOverview:Thecarbonadjacenttoacarbonylisdesignatedasthealpha()carbonElectrophilicsubstitutionoccursatthealpha()positionviaoneoftwopossibleintermediates:GeneralReactionScheme:1KetoEnolTautomerismAcar
UGA - CHEM 2212 - 234-54
Chapter23:CarbonylCondensationReactionsPreviouslydiscussedcarbonylreactivitypatterns:1CarbonylCondensations:TheAldolReactionGeneralReaction:Examples(symmetrical):2CarbonylCondensations:TheAldolReactionMechanism:3TheAldolCondensation:Equilibrium
UGA - CHEM 2212 - 234-54
Answers to IR/NMR Sample Problems4:O6:OO14:OO18:OO20:OO23:O29:OO
UGA - CHEM 2212 - 234-54
Detailed Answer to Question 18:Singlet at 6.1HOCH3OHCH3Singlet at 3.7Singlet at 5.5Singlet at 1.9
UGA - CHEM 2212 - 234-54
Two simple rules in order to determine whichTwo simple rules in order to determine whichgroup will dominate the directing effects1. ortho-para directors always beat meta-directors2. Strong activators always beat weak activators2. Strong activators al
UGA - CHEM 2212 - 234-54
Leaving group order approximately in decreasing ability to leave*R-N2+diazonium saltsR-OR'2+R-OSO2C4F9nonaflatesR-OSO2CF3triflatesR-OSO2FfluorosulfonatesR-OTs, R-OMs, etc.tosylates, mesylatesR-IiodidesR-BrbromidesR-OH2+conjugate acid o
UGA - CHEM 2212 - 234-54
MW = 72CH3CHCH2CH3MW = 72CH3CH2CH2CH2CH3Vs.CH3(72-15)(72-15)5757MW = 72MW = 72CH3CHCH2CH3CH3CH3CH2CH2CH2CH3Vs.(72-29)(72-29)(72-15)(72-15)43435757MW = 72MW = 72CH3CHCH2CH3CH3CH3CH2CH2CH2CH3Vs.(72-29)(72-29)(72-14-14-15)(72
UGA - CHEM 2212 - 234-54
SN1SN 2MechanismTwo steps: R-LR+Kinetics1st order (unimolecular)Rate = k[R-L]Ionization is the rate determiningstep2nd order (bimolecular)Rate = k[R-L][Nu:]StereochemistryRacemizationInversionCarbon (sp3)electrophileFavored by electrophil
UGA - CHEM 2212 - 234-54
Summary of likely mechanism:HaloalkanePoornucleophile(ex. H2O)Weakly basicgoodnucleophile(ex. I-)Strongly basicunhindered(ex. CH3O-)Stronglybasic,hindered (ex.(CH3)3CO-)MethylNo rxnSN2SN2SN2PrimaryUnhinderedNo rxnSN2SN2E2Primary
UGA - CHEM 2212 - 234-54
DistillationDistillation is a physical separations technique based on differences in componentvolatilities within a mixture. We will utilize it in two ways this semester:to separate/isolate two volatile and miscible liquids (Exp #2)to isolate a volati
UGA - CHEM 2212 - 234-54
Heating a Solution without a Loss of Solvent (Reflux):Heat is often applied to solutions in the organic chemistry lab in order to accelerate/catalyze achemical reaction or a unit operation (physical separation). When heating a mixture to theboiling poi
UGA - CHEM 2212 - 234-54
How to Write a Lab Report:This is a brief explanation of how to write a proper organic lab report. As previously stated, yourlab reports will be divided into three main sections: The Pre, In, and Post labs. Lets take a lookat how these sections are org
UGA - CHEM 2212 - 234-54
Liquid/Liquid Extraction:Liquid/liquid extractions come in two general forms: organic solvent extractions andacid/base extractions. These types of separations are performed using two immiscible liquids topartition the components of a mixture. The typic
UGA - CHEM 2212 - 234-54
Melting Point DeterminationYou will find that most of the products generated in your organic chemistry lab thissemester are either white or yellow crystalline solids at room temperature. It can be difficult totell them apart based solely on physical ap
UGA - CHEM 2212 - 234-54
RecrystallizationThe following is a graphical representation of the recrystallization process:Figure 1: Recrystallization Flow ChartThe five steps of recrystallization:1. Choose an appropriate solvent for the recrystallization2. Dissolve the impure m
UGA - HIST 2112 - 2112
Executive Order 9066 During WWII there was a great amount of discriminationtowards other races. People were worried about Japanese in California because ofvulnerability to attack on the West Coast and demanded that the region be rid ofsupposed Japanese
UGA - HIST 2112 - 2112
Alger Hiss- Communist. Richard Nixon was suspicious of him and dug up dirton him with the help of Whittaker Chambers. Chambers produced microfilms ofdocuments (Pumpkin Papers- because Hiss hid documents in a pumpkin patch).Accused in 1948 of having be
UGA - HIST 2112 - 2112
HIST2112 HamiltonFinal Exam Study GuideTerms to Know:Kitchen Debate (1959): conversation between U.S. vice president Richard Nixon and Soviet premier NikitaKhrushchev as they walked through the American National Exhibition in Moscow in July 1959. Nixo
UGA - HIST 2112 - 2112
History FinalsExecutive Order 9066Definition: It is an order that Roosevelt issued in 1942, which gave the War Department theauthority it needed for its plan to evacuate Japanese Americans from the West Coast and intern them inrelocation camps for the
UGA - HIST 2112 - 2112
RECONSTRUCTION1865-1877Whats in a name?1861-1865The War Between the StatesThe War of Northern AggressionThe War for Southern IndependenceThe War of the RebellionThe Freedom WarThe Civil WarWhat was Reconstruction?A tragic imposition of illegiti
UGA - HIST 2112 - 2112
TAASSIGNMENTSGroupI:AFSHARI,A.CHENG,G.oGroupII:COLBERT,M.HOLSOMBACK,S.oMichaelCarson:LeConteHall,Room122W12pm;TH23pm.GroupIV:MCKENZIE,S.SHETH,P.oTBA:GroupIII:HOLT,K.MCKENZIE,C.oCatAriail:LeConteHall,Room114M11am12pm;TH1:302:30pm.MadelinePatric
UGA - HIST 2112 - 2112
TheWestTheWestasfrontierFrontier:Alineofwhitesettlement,shiftingwestwardovertimeNineteenthcenturyAmericansequatedtheWestwiththefrontierTheimaginedWestTheWildWestLate19thanxietiesinthemidstofindustrialization,urbanization,andimmigration Whatwoul
UGA - HIST 2112 - 2112
IndustrialRevolutionImportantMeetingofSmokemakers5characteristicsofindustrialcapitalismTechnologicalinnovationGovernmentassistedgrowthofbusinessNewformsofbusinessorganizationAmbitious,talented,andruthlessentrepreneursSteadysupplyofcheaplaborTech
UGA - HIST 2112 - 2112
Labor WarsWhat was at stake in the labor wars?1) Control over the conditions of workFrederick Winslow Taylor, The Principles of Scientific ManagementThe Principles of ScientificManagement . . . [I]f you are a high-priced man, you will do exactly as
UGA - HIST 2112 - 2112
The Perils and Promise ofCity LifeUrbanization of America1870: 20% urban1900: 33% urban1920: +50% urban1870: Fewer than 20 cities with 100,000; NYCless than one million1900: 40 cities with more than 100,000; 3 citieswith more than 1 million (NY,
UGA - HIST 2112 - 2112
Youcometousandtellusthatthegreatcitiesareinfavorofthegoldstandard.Itellyouthatthegreatcitiesrestuponthesebroadandfertileprairies.Burndownyourcitiesandleaveourfarms,andyourcitieswillspringupagainasifbymagic.Butdestroyourfarmsandthegrasswillgrowinthes
UGA - HIST 2112 - 2112
The Era of Jim CrowJim Crow 1890s-1950s/60s De Jure segregation Disenfranchisement Industrial education LynchingWhite backlash Conditions for African Americansworsened in the SouthWhy? Opposition to black progressMaggie Lena Walker (b.1867)Fi
UGA - HIST 2112 - 2112
UptonSinclair,TheJungle,1906DiversityofissuesConcentrationofcorporatepowerandwealthAlarge,andrebelliousworkingclassCrowded,unsafecitiesCorruptionofmachinepoliticsAssimilationofmillionsofimmigrantsOngoinglaborconflictJimCrowpracticesRiseofradical
UGA - HIST 2112 - 2112
Womens FightFor the Right to VoteSeneca Falls, NY 1848First U.S. womansrights conventionDeclaration ofSentiments, 1848Authored byElizabeth CadyStantonReconstructionPost-Civil Wardebates over blackmale suffrageEqual RightsAssociation 1866De
UGA - HIST 2112 - 2112
U.S. ImperialismImperialism The practice of onecountry extending itscontrol over anothercountryeconomically,politically, and/orterritorially. How and why did the U.S.become an imperial powerat the dawn of the 20thcentury?19th century foundatio
UGA - HIST 2112 - 2112
World War IParadox and WWIWar to end all warsWar for democracyBrutalityAmbiguous legacy forAfrican AmericansWar in Europe 1914 France, Russia, GreatBritain, Japan vs.Germany, AustriaHungary, (Bulgaria),(Turkey)Could/should the U.S. remainneu
UGA - HIST 2112 - 2112
1920sMass CultureCommercialized leisure andentertainment, 1920sRecap of early 1900s: dance halls,amusement parks, nickelodeonsMass consumer culture as nationalizing forceWhat does it mean to be American?Eating Kellogs cornflakes and making toast w
UGA - HIST 2112 - 2112
The Onset of the GreatDepressionThe 1920sCREDITBUBBLEGREEDSTOCK MARKETCRASH (FALL1929)STATISTICSmarket declines by 80%GNP cut by almost 9,000 banks bankrupt100,000 businesses failUnemployment 25%Personal incomes down by 1/2The Negro wasbo
UGA - HIST 2112 - 2112
The New DealRevised reading schedule 10/18: A New Deal for America? Chap. 27and document Share Our Wealth 10/20: World War II Chapter 27 anddocument A Japanese AmericanRecalls . . . Film screening (unchanged) Sunday, 10/23,7-9 pm, Miller Learning
UGA - HIST 2112 - 2112
World War IIMobilizationRosie the RiveterEconomicexpansionGov. spends 321billion, 1941-1945Bonds, taxes, jobsWhere will wartimeworkers comefrom?Women180 degree turn
UGA - HIST 2112 - 2112
The Cold WarRecap: The Life and Times ofRosie the Riveter Cold WarWWII-1991 Why the Cold War? How was it fought?Proxy wars/confictsKorean WarVietnam WarIran 1953Guatemala 1954Chile 1972Guatemala, 1954Central Intelligence Agency (CIA)Jacobo A
UGA - HIST 2112 - 2112
The 1950sAffluence and AnxietyPopular images of the 1950struth or fiction?Economic prosperityExpanding (white) middle classEconomic growth, high employmentHome buildingGNP nearly doubledU.S. producing and consuming 2/3 ofworlds goods (at 6% of wo
UGA - HIST 2112 - 2112
Civil Rights MovementJoanne Gibson RobinsonFannie Lou HamerDiane NashDr. Martin Luther King, Jr.Montgomery Bus Boycott 1955-56 Nonviolentresistance/civildisobedience Highlander FolkSchool, TN Dr. Martin LutherKing, Jr. Rosa Parkslegendvs. r
UGA - HIST 2112 - 2112
Twentieth-Century LiberalismLiberalism: Shifting definitions 19th century meaning:laissez-faireeconomics andlimited government Twentieth century Dominant political culture,1930s-1980s embracedby majority of Americans Franklin D.Roosevelt/New De
UGA - HIST 2112 - 2112
The Vietnam WarLasting legacies Americas longest war 2.5 million Americansfought 58,000 Americans died Cost in U.S. dollars150 billion National conflict,disharmony, cynicism 1.5 Vietnamese killed;10 million refugees;economy destroyed Failure