UGA - CHEM 2212 - 234-54

UGA - CHEM 2212 - 234-54

UGA - CHEM 2212 - 234-54

UGA - CHEM 2212 - 234-54

Answers to IR/NMR Sample Problems4:O6:OO14:OO18:OO20:OO23:O29:OO

UGA - CHEM 2212 - 234-54

Detailed Answer to Question 18:Singlet at 6.1HOCH3OHCH3Singlet at 3.7Singlet at 5.5Singlet at 1.9

UGA - CHEM 2212 - 234-54

Two simple rules in order to determine whichTwo simple rules in order to determine whichgroup will dominate the directing effects1. ortho-para directors always beat meta-directors2. Strong activators always beat weak activators2. Strong activators al

UGA - CHEM 2212 - 234-54

UGA - CHEM 2212 - 234-54

Leaving group order approximately in decreasing ability to leave*R-N2+diazonium saltsR-OR'2+R-OSO2C4F9nonaflatesR-OSO2CF3triflatesR-OSO2FfluorosulfonatesR-OTs, R-OMs, etc.tosylates, mesylatesR-IiodidesR-BrbromidesR-OH2+conjugate acid o

UGA - CHEM 2212 - 234-54

MW = 72CH3CHCH2CH3MW = 72CH3CH2CH2CH2CH3Vs.CH3(72-15)(72-15)5757MW = 72MW = 72CH3CHCH2CH3CH3CH3CH2CH2CH2CH3Vs.(72-29)(72-29)(72-15)(72-15)43435757MW = 72MW = 72CH3CHCH2CH3CH3CH3CH2CH2CH2CH3Vs.(72-29)(72-29)(72-14-14-15)(72

UGA - CHEM 2212 - 234-54

SN1SN 2MechanismTwo steps: R-LR+Kinetics1st order (unimolecular)Rate = k[R-L]Ionization is the rate determiningstep2nd order (bimolecular)Rate = k[R-L][Nu:]StereochemistryRacemizationInversionCarbon (sp3)electrophileFavored by electrophil

UGA - CHEM 2212 - 234-54

Summary of likely mechanism:HaloalkanePoornucleophile(ex. H2O)Weakly basicgoodnucleophile(ex. I-)Strongly basicunhindered(ex. CH3O-)Stronglybasic,hindered (ex.(CH3)3CO-)MethylNo rxnSN2SN2SN2PrimaryUnhinderedNo rxnSN2SN2E2Primary

UGA - CHEM 2212 - 234-54

UGA - CHEM 2212 - 234-54

DistillationDistillation is a physical separations technique based on differences in componentvolatilities within a mixture. We will utilize it in two ways this semester:to separate/isolate two volatile and miscible liquids (Exp #2)to isolate a volati

UGA - CHEM 2212 - 234-54

UGA - CHEM 2212 - 234-54

Heating a Solution without a Loss of Solvent (Reflux):Heat is often applied to solutions in the organic chemistry lab in order to accelerate/catalyze achemical reaction or a unit operation (physical separation). When heating a mixture to theboiling poi

UGA - CHEM 2212 - 234-54

How to Write a Lab Report:This is a brief explanation of how to write a proper organic lab report. As previously stated, yourlab reports will be divided into three main sections: The Pre, In, and Post labs. Lets take a lookat how these sections are org

UGA - CHEM 2212 - 234-54

Liquid/Liquid Extraction:Liquid/liquid extractions come in two general forms: organic solvent extractions andacid/base extractions. These types of separations are performed using two immiscible liquids topartition the components of a mixture. The typic

UGA - CHEM 2212 - 234-54

Melting Point DeterminationYou will find that most of the products generated in your organic chemistry lab thissemester are either white or yellow crystalline solids at room temperature. It can be difficult totell them apart based solely on physical ap

UGA - CHEM 2212 - 234-54

RecrystallizationThe following is a graphical representation of the recrystallization process:Figure 1: Recrystallization Flow ChartThe five steps of recrystallization:1. Choose an appropriate solvent for the recrystallization2. Dissolve the impure m

UGA - HIST 2112 - 2112

Executive Order 9066 During WWII there was a great amount of discriminationtowards other races. People were worried about Japanese in California because ofvulnerability to attack on the West Coast and demanded that the region be rid ofsupposed Japanese

UGA - HIST 2112 - 2112

Alger Hiss- Communist. Richard Nixon was suspicious of him and dug up dirton him with the help of Whittaker Chambers. Chambers produced microfilms ofdocuments (Pumpkin Papers- because Hiss hid documents in a pumpkin patch).Accused in 1948 of having be

UGA - HIST 2112 - 2112

HIST2112 HamiltonFinal Exam Study GuideTerms to Know:Kitchen Debate (1959): conversation between U.S. vice president Richard Nixon and Soviet premier NikitaKhrushchev as they walked through the American National Exhibition in Moscow in July 1959. Nixo

UGA - HIST 2112 - 2112

History FinalsExecutive Order 9066Definition: It is an order that Roosevelt issued in 1942, which gave the War Department theauthority it needed for its plan to evacuate Japanese Americans from the West Coast and intern them inrelocation camps for the

UGA - HIST 2112 - 2112

RECONSTRUCTION1865-1877Whats in a name?1861-1865The War Between the StatesThe War of Northern AggressionThe War for Southern IndependenceThe War of the RebellionThe Freedom WarThe Civil WarWhat was Reconstruction?A tragic imposition of illegiti

UGA - HIST 2112 - 2112

TAASSIGNMENTSGroupI:AFSHARI,A.CHENG,G.oGroupII:COLBERT,M.HOLSOMBACK,S.oMichaelCarson:LeConteHall,Room122W12pm;TH23pm.GroupIV:MCKENZIE,S.SHETH,P.oTBA:GroupIII:HOLT,K.MCKENZIE,C.oCatAriail:LeConteHall,Room114M11am12pm;TH1:302:30pm.MadelinePatric

UGA - HIST 2112 - 2112

TheWestTheWestasfrontierFrontier:Alineofwhitesettlement,shiftingwestwardovertimeNineteenthcenturyAmericansequatedtheWestwiththefrontierTheimaginedWestTheWildWestLate19thanxietiesinthemidstofindustrialization,urbanization,andimmigration Whatwoul

UGA - HIST 2112 - 2112

IndustrialRevolutionImportantMeetingofSmokemakers5characteristicsofindustrialcapitalismTechnologicalinnovationGovernmentassistedgrowthofbusinessNewformsofbusinessorganizationAmbitious,talented,andruthlessentrepreneursSteadysupplyofcheaplaborTech

UGA - HIST 2112 - 2112

Labor WarsWhat was at stake in the labor wars?1) Control over the conditions of workFrederick Winslow Taylor, The Principles of Scientific ManagementThe Principles of ScientificManagement . . . [I]f you are a high-priced man, you will do exactly as

UGA - HIST 2112 - 2112

The Perils and Promise ofCity LifeUrbanization of America1870: 20% urban1900: 33% urban1920: +50% urban1870: Fewer than 20 cities with 100,000; NYCless than one million1900: 40 cities with more than 100,000; 3 citieswith more than 1 million (NY,

UGA - HIST 2112 - 2112

Youcometousandtellusthatthegreatcitiesareinfavorofthegoldstandard.Itellyouthatthegreatcitiesrestuponthesebroadandfertileprairies.Burndownyourcitiesandleaveourfarms,andyourcitieswillspringupagainasifbymagic.Butdestroyourfarmsandthegrasswillgrowinthes

UGA - HIST 2112 - 2112

The Era of Jim CrowJim Crow 1890s-1950s/60s De Jure segregation Disenfranchisement Industrial education LynchingWhite backlash Conditions for African Americansworsened in the SouthWhy? Opposition to black progressMaggie Lena Walker (b.1867)Fi

UGA - HIST 2112 - 2112

UptonSinclair,TheJungle,1906DiversityofissuesConcentrationofcorporatepowerandwealthAlarge,andrebelliousworkingclassCrowded,unsafecitiesCorruptionofmachinepoliticsAssimilationofmillionsofimmigrantsOngoinglaborconflictJimCrowpracticesRiseofradical

UGA - HIST 2112 - 2112

Womens FightFor the Right to VoteSeneca Falls, NY 1848First U.S. womansrights conventionDeclaration ofSentiments, 1848Authored byElizabeth CadyStantonReconstructionPost-Civil Wardebates over blackmale suffrageEqual RightsAssociation 1866De

UGA - HIST 2112 - 2112

U.S. ImperialismImperialism The practice of onecountry extending itscontrol over anothercountryeconomically,politically, and/orterritorially. How and why did the U.S.become an imperial powerat the dawn of the 20thcentury?19th century foundatio

UGA - HIST 2112 - 2112

World War IParadox and WWIWar to end all warsWar for democracyBrutalityAmbiguous legacy forAfrican AmericansWar in Europe 1914 France, Russia, GreatBritain, Japan vs.Germany, AustriaHungary, (Bulgaria),(Turkey)Could/should the U.S. remainneu

UGA - HIST 2112 - 2112

1920sMass CultureCommercialized leisure andentertainment, 1920sRecap of early 1900s: dance halls,amusement parks, nickelodeonsMass consumer culture as nationalizing forceWhat does it mean to be American?Eating Kellogs cornflakes and making toast w

UGA - HIST 2112 - 2112

The Onset of the GreatDepressionThe 1920sCREDITBUBBLEGREEDSTOCK MARKETCRASH (FALL1929)STATISTICSmarket declines by 80%GNP cut by almost 9,000 banks bankrupt100,000 businesses failUnemployment 25%Personal incomes down by 1/2The Negro wasbo

UGA - HIST 2112 - 2112

The New DealRevised reading schedule 10/18: A New Deal for America? Chap. 27and document Share Our Wealth 10/20: World War II Chapter 27 anddocument A Japanese AmericanRecalls . . . Film screening (unchanged) Sunday, 10/23,7-9 pm, Miller Learning

UGA - HIST 2112 - 2112

World War IIMobilizationRosie the RiveterEconomicexpansionGov. spends 321billion, 1941-1945Bonds, taxes, jobsWhere will wartimeworkers comefrom?Women180 degree turn

UGA - HIST 2112 - 2112

The Cold WarRecap: The Life and Times ofRosie the Riveter Cold WarWWII-1991 Why the Cold War? How was it fought?Proxy wars/confictsKorean WarVietnam WarIran 1953Guatemala 1954Chile 1972Guatemala, 1954Central Intelligence Agency (CIA)Jacobo A

UGA - HIST 2112 - 2112

The 1950sAffluence and AnxietyPopular images of the 1950struth or fiction?Economic prosperityExpanding (white) middle classEconomic growth, high employmentHome buildingGNP nearly doubledU.S. producing and consuming 2/3 ofworlds goods (at 6% of wo

UGA - HIST 2112 - 2112

Civil Rights MovementJoanne Gibson RobinsonFannie Lou HamerDiane NashDr. Martin Luther King, Jr.Montgomery Bus Boycott 1955-56 Nonviolentresistance/civildisobedience Highlander FolkSchool, TN Dr. Martin LutherKing, Jr. Rosa Parkslegendvs. r

UGA - HIST 2112 - 2112

Twentieth-Century LiberalismLiberalism: Shifting definitions 19th century meaning:laissez-faireeconomics andlimited government Twentieth century Dominant political culture,1930s-1980s embracedby majority of Americans Franklin D.Roosevelt/New De

UGA - HIST 2112 - 2112

The Vietnam WarLasting legacies Americas longest war 2.5 million Americansfought 58,000 Americans died Cost in U.S. dollars150 billion National conflict,disharmony, cynicism 1.5 Vietnamese killed;10 million refugees;economy destroyed Failure

UGA - HIST 2112 - 2112

The 1960sPolitics and Culture Political movements:The StudentMovement, the CivilRights Movement, theWomens Movement,the Black PowerMovement Cultural rebellion: TheCountercultureThe Counterculture Similarities betweenthe Countercultureand pol

UGA - HIST 2112 - 2112

Watergate June 17, 1972 Break-in at Watergatebuilding National Committeeof the DemocraticParty 5 burglars arrestedNo ordinary burglars 4 of 5 had ties to theCIA James McCord = Chiefof Security for CREEP(Committee to Re-electthe President) A

UGA - RELI 1001 - 1001

Chapter 4:Christian TraditionsOrigins The Life of Jesus We know very little about the early years of Jesus otherthan his birth in Bethlehem and that his childhood homewas in Nazareth. His public years began at 30 Yrs old with his baptism byhis old

UGA - RELI 1001 - 1001

CHRISTIANITYAn IntroductionWorld SignificanceSizeHistoryComplexityDiverse ManifestationsLifestyle DifferencesWorld Influence Perception of TimeSimilarities to JudaismMonotheistic, exoteric,observant, and mysticalDistinctions fromJudaismMono

UGA - RELI 1001 - 1001

NAME:_ TIME:_3rd EDITIONChristianity 1 (O 166-171: Celebrating a Birth; Christian Origins: The Gospels and JesusTerms: Christmas; Easter; mass; Eucharist; gospels; scripture; canon;* Note: words in bold can be found in key terms section on pages 260-2

UGA - RELI 1001 - 1001

Essay Q: How have some Christians attempted to redress the patriarchal bias of theChristian tradition?The twentieth century brought dramatic changes in the cultural expectations of women insociety. The efforts to redress the patriarchal bias of two mil

UGA - RELI 1001 - 1001

Chapter 3:Jewish TraditionsOverview Judaism gave rise to two other world religions:Christianity and Islam. Each of these religions trace their spiritual lineage tothe biblical patriarch Abraham. Judaism is the smallest of the three, yet its histori

UGA - RELI 1001 - 1001

Chapter 1:About ReligionLooking Both Ways FromStonehenge:Basic Human Religion Looking Back from Stonehenge There are a few concepts, shared by virtuallyall human cultures, that are fundamental towhat we call religion:1. It seems that humans aroun

UGA - RELI 1001 - 1001

Chapter 2:Religions of the Ancient WorldOverview None of the ancient peoples had a singleword equivalent to the term religion. The word religion comes from the Latinreligio. Some claim this word is derived from religare (tobind), as in the unbreaka

UGA - RELI 1001 - 1001

JudaismReligiologyEpistemologyI) RevelationA) The meaning of the wordliterally- revelation means a disclosure orlifting of a veiltheologically- revelation is the disclosure ofthe nature of God and God's will for mankindB) revelation is historical

UGA - RELI 1001 - 1001

Judaism 1 (pg 68-77): A Ritual Initiation; Overview: Diversity in Judaism; The Biblical Period: TheHistorical Development of Judaism; Creation in Gen; The Primal Couple; Myth & Israelite Narratives;Abraham; CovenantDates: ca. 1280; Names: Adam; Eve; Ab

UGA - RELI 1001 - 1001

UGA - RELI 1001 - 1001

Religiology Matrix

UGA - RELI 1001 - 1001

ReligiologyMatrixforunderstandingEpistemologyisaninquiryintoknowledgeComesfromtheGreekEpistlemeaningletters/writingsQuestion:Whatconstitutesvalidknowledgeandhowtointerpretthatknowledge?Whatwerelyoninordertogainknowledge?Whatshouldweusetounderstanda

UGA - RELI 1001 - 1001

BethlehemThetraditionalbirthplaceofJesus,whichismarkedtodaymythe monumentpicturedabove.JerusalemSiteofJesuscruxicifion(todaymarkedbythechurchoftheHolySeplecurepicturedabove)andtheearlierJewishChristian community;capitaloflatinChristiankingdomintheH

UGA - RELI 1001 - 1001

1) Q: Explain, with examples, the five pillars of Islam.Individual faith and institutional Islam converge in the worship of God and service to others. Accordingto well-attested tradition, the prophet himself said that Islam was built on five pillars. Wi

UGA - RELI 1001 - 1001

Religiology is an analytical method for understanding and analyzing beliefs. As a system,Religiology is coherent, systematic, and relatively objective. It is coherent because all the partsare connected together into a system. It is systematic because th