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Ch16Feb14
Course: CHEM 334, Spring 2012School: South Carolina
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South Carolina - CHEM - 334
South Carolina - CHEM - 334
South Carolina - CHEM - 334
South Carolina - CHEM - 334
South Carolina - CHEM - 334
South Carolina - CHEM - 334
South Carolina - CHEM - 334
South Carolina - CHEM - 334
South Carolina - CHEM - 334
South Carolina - ACCT - 226
PresentValueExamples1. Youhave$200,000toinvest.Youcouldinvestinarentalhousewhichwillreturnyou$8,000peryearfor10yearsandbeworth$350,000attheendorinastockwhichyouthinkwillbeworth$300,000in5years.WhichwouldyoupursueifyourRRRis8%?2. Usingadiscountrateof1
South Carolina - ACCT - 226
Chapter 9 additional ExampleHow do the standards get set exactly?Macon is charged w/ setting the standards (off of which variances will be calculated later) forone of the many products he, Carter and Luci make. This product requires a raw material that
South Carolina - ACCT - 225
AAdjusting Journal Entries Example1. On April 1st, 2004 we purchase a two year insurance policy for $2400.2. On October 31st, 2005 we receive $3600 for consulting services that wewill perform over the next six months.3. On July 31st, 2005 we borrow $
South Carolina - ACCT - 225
Journal Entries ExamplesHINT: assets, dividends & expenses increase in debit, liabilities, equity &revenue in credit1. Purchased $10,000 of stuff we intend to resell and paid cash2. Issued $100,000 of common stock3. Paid the rent for the month of $2,
South Carolina - ACCT - 225
Review Problems for Chapters 1-31. Given the list of accounts below, prepare a classified balance sheet, the retained earningscolumn of the statement of stockholders equity and an income statement in properformat for the Carter Corporation for the year
South Carolina - ACCT - 225
1. The following information pertains to Macon, Inc. as of August 31, 2010:Balance per bank statementUnadjusted Cash balance per booksOutstanding checksAugust interest earned per bank statementNSF checkDeposits outstandingCheck #800 cleared the ban
South Carolina - ACCT - 225
New Material Practice1.The following is taken from Macons Equity Section of his 2006 Balance Sheet:Common Stock ($3 par, 900,000 shares authorized,500,000 issued, 350,000 outstanding)Additional Paid In Capital, common stockTreasury StockRetained Ea
South Carolina - PYSC - 101
FinalExamPsychology101Section001December112010VersionAName_Pleaseputyournameandanswersonboththispapercopyandthescantron.AlsoputthelastFIVEdigitsofyoursocialsecurityon thescantronintheappropriateplace(leftjustified).Pleaseuseanumber2penciltofillinthe
South Carolina - PYSC - 101
ThirdTestPsychology101Section001November222010VersionAName_Pleaseuseanumber2penciltofillinthescantron.Besuretofillinyourname(onboththetestandscantron)andthelast fivenumbersofyoursocialsecuritynumber(rightjustified)onthescantron.PUTthetestversiononyour
South Carolina - PYSC - 101
FirstTestPsychology101Section001October222010VersionAName_Pleaseuseanumber2penciltofillinthescantron.Besuretofillinyourname(onboththetestandscantron)andthelast fivenumbersofyoursocialsecuritynumber(rightjustified)onthescantron.PUTthetestversiononyours
South Carolina - PYSC - 101
FirstTestPsychology101Section001September222010VersionBName_Pleaseuseanumber2penciltofillinthescantron.Besuretofillinyourname(onboththetestandscantron)andthelast fivenumbersofyoursocialsecuritynumber(rightjustified)onthescantron.PUTthetestversiononyou
South Carolina - PYSC - 101
Treatment:HealingActions,HealingWordsWhichTreatmentforWhichDisorder?EmpiricallysupportedtreatmentsEvidencebasedtreatmentsTherapy,medication,orboth?DepressionAnxietydisordersOtherdisordersInsightOrientedTherapyPsychoanalysisFirstuseofatalkingc
South Carolina - PYSC - 101
Psychological DisorderThe presence of a constellation of symptomsthat create significant distress; impair work,school, family, relationships, or daily living; or leadto significant risk or harmn SymptomsnnnCognitiveEmotionalBehavioralDefining
South Carolina - PYSC - 101
Stress,HealthandCopingA)StressandSourcesofStressB)StressandtheImmuneSystemC)CopingandInterventionsA)StressandSourcesofStressStress:thegeneraltermdescribingthepsychologicalandbodilyresponsetoastimulusthataltersonesstateofequilibriumStressor Acutes
South Carolina - PYSC - 101
DevelopmentAcrosstheLifespan1.2.3.4.FetalDevelopmentChildDevelopmentAdolescenceAdulthoodandAging1.FetalDevelopmentnGametesnChromosomesnSpermEggXX=femaleXY=maleMaturationFetalDevelopmentnnTrimestersZygotenEmbryonAfertilizedegg
South Carolina - PYSC - 101
DifferentMemoryStoresWe have three different memorystores, or sets of neurons thatmaintain informationEach memory store has a differentDuration: the length of time information ismaintainedCapacity: the amount of information thatis maintainedDiffe
South Carolina - PYSC - 101
LearningA relatively permanent change in behavior thatresults from experiencel Psychologistsare interested in both the contentof learning and the processl TypesClassical conditioningl Operant conditioningl Cognitive and social learninglClassica
South Carolina - PYSC - 101
ConsciousnessOurawarenessofourownexistence,sensations,andcognitionsStreamofconsciousnessWilliamJamesWhatfunctiondoesconsciousnessserve?ConsciousnessNormalconsciousnessAlteredstatesofconsciousnessSleepingDreamingHypnosisMeditationDruginducedO
South Carolina - PYSC - 101
Sensation and PerceptionSensationThe awareness of properties of an object oran event when a sensory receptor isstimulatedPerceptionThe act of organizing and interpreting sensoryinput as signaling a particular object or eventIllusionsWhen percepti
South Carolina - PYSC - 101
PsychologyInDepth:Psychology,geneticsandepigeneticsA)GenesasblueprintsB)EpigeneticsC)CareTakingD)RettSyndromeGenesasblueprintsMendelianinheritanceDeoxyribonucleicacid(DNA)GeneGenotypePhenotypeGenesasblueprintsComplexinheritanceevenforsimplet
South Carolina - PYSC - 101
The Biology of Mind and Behaviorl Theneuron and its partsl Drugs and their actionsl The Brain and its partsThe Neuronl Thebasic unit of the nervous systemReceives signals from neurons or sensory organsProcesses informationSends signals to other
South Carolina - PYSC - 101
Chapter 2: The Research ProcessA.B.C.D.The Scientific MethodDesigning ExperimentsStatisticsLying with statisticsA. The Scientific Methodl Specifya probleml Systematic observationl Form a hypothesisl Test the hypothesis with datal Formulate
South Carolina - PYSC - 101
Important InfoSyllabusTextbook, My PsychLabRequirementsBlackboardNature of the courseSupplemental Instructor: Margo ScaleTeaching Assistant for grading: AshleyRobinsonImportant InfoParticipant pool participationParticipant Pool TAEmail: psycpo
South Carolina - CHEM - 333
South Carolina - CHEM - 333
South Carolina - CHEM - 333
South Carolina - CHEM - 333
South Carolina - CHEM - 333
South Carolina - CHEM - 333
South Carolina - CHEM - 333
South Carolina - CHEM - 333
South Carolina - CHEM - 333
South Carolina - CHEM - 333
8.Sigma Bonds & Bond RotationTwo groups bonded by a single bondcan undergo rotation about that bondwith respect to each otherConformations temporary molecularshapes result from a rotation about a singlebondConformer each possible structure ofconf
South Carolina - CHEM - 333
Ch. 4 - 110. The Relative Stabilities ofCycloalkanes: Ring StrainCycloalkanes do not have the samerelative stability due to ring strain Ring strain comprises:Angle strain result of deviation fromideal bond angles caused by inherentstructural const
South Carolina - CHEM - 333
7.Naming Enantiomers: R,S-SystemUsing only the IUPAC naming that we havelearned so far, these two enantiomers willhave the same name: 2-Butanol This is undesirable because each compoundmust have its own distinct nameCh. 5 - 17A. How to Assign (R)
South Carolina - CHEM - 333
9A. Racemic Forms An equimolar mixture of twoenantiomers is called a racemic mixture(or racemate or racemic form) A racemic mixture causes no netrotation of plane-polarized lightrotationequal & oppositerotation by theenantiomerCh. 5 - 1Enantiom
South Carolina - CHEM - 333
2011 Nobel Prize in Physiology or Medicinetheir discoveries concerning the activation of innate immunityJules HoffmannBruce BeutlerRalph Steinman13. Fischer Projection Formulas13A. How To Draw and Use FischerProjectionsProjectionsFischerProjecti
South Carolina - CHEM - 333
Israeli scientist Daniel Shechtman wonthe 2011 Nobel Prize in chemistryfor his discovery of quasicrystals1. Organic HalidesCXX = Cl, Br, IHalogens are more electronegativethan carbonCh. 6 - 2Carbon-Halogen Bond Lengthsand Bond StrengthCX BondL
South Carolina - CHEM - 333
9.The Reaction of tert-Butyl Chloridewith Hydroxide Ion: An SN1 Reaction3323333Multistep Reactions & the RateDetermining StepCh. 6 - 1Free Energy Diagram of SN1 ReactionsT.S. (1)T.S. (2)T.S. (3)(CH3)3C+ BrG1(CH3)3CBr+ H2O(CH3)3C -OH2+
South Carolina - CHEM - 333
14E. The Nature of the Leaving GroupSN1 Reaction:+SN2 Reaction:Ch. 6 - 1a poorleaving groupHa goodleaving group+a strongbasic anionweakbaseCh. 6 - 215. Elimination Reactions of AlkylHalidesSubstitution reaction (SN) andelimination react
South Carolina - CHEM - 333
Chapter 7Alkenes and Alkynes I:Properties and Synthesis.Elimination Reactionsof Alkyl HalidesCh. 7 - 11. IntroductionAlkenes Hydrocarbons containing C=C Old name: olefinsCH2OHVitamin AH3CH3CHHOHCholesterolCh. 7 - 2Alkynes Hydrocarbons
South Carolina - CHEM - 333
6C. The Stereochemistry of E2ReactionsThe 5 atoms involved in the transitionstate of an E2 reaction (including thebase) must lie in the same plane The anti coplanar conformation is thepreferred transition state geometry The anti coplanar transition
South Carolina - CHEM - 333
9.The Acidity of Terminal AlkynesAcetylenic hydrogenspsp2HHCCHpKa = 25HHCHsp3CHHpKa = 44HCCHHHpKa = 50Relative basicity of the conjugate baseCh. 7 - 1HpComparison of acidity and basicity of1st row elements of the Periodic T
South Carolina - CHEM - 333
Chapter 8Alkenes and Alkynes II:Addition ReactionsCh. 8 - 11. Addition Reactions of AlkenesECC+ENuCCNuCh. 8 - 21A. How To Understand Additionsto AlkenestoThis is an addition reaction: ENuadded across the double bondECC+ENuCCNu-b
South Carolina - CHEM - 333
6.Alcohols from Alkenes throughOxymercurationDemercuration:Markovnikov AdditionStep 1: OxymercurationStep 2: Demercuration4Ch. 8 - 12H2O4MethanidemigrationComparisonacid-catalyzed hydrationCh. 8 - 2Solvomercuration-Demercuration232234
South Carolina - CHEM - 333
12. Electrophilic Addition of Bromineand Chlorine to AlkenesAddition of XX (X = Cl, Br) across aC=C bond24Ch. 8 - 1Stereochemistry Anti addition4NCh. 8 - 213. Stereospecific ReactionsA reaction is stereospecific when aparticular stereoisomer
South Carolina - CHEM - 333
15. Oxidation of Alkenes:Syn 1,2-DihydroxylationOverall: addition of 2 OH groups acrossa C=C bondReagents: dilute KMnO4 / OH / H2O /cold or OsO4, pyridine then NaHSO3, H2OCh. 8 - 1Comparison of the two reagents KMnO4: usually lower yield andpossi
South Carolina - CHEM - 333
Chapter 10Radical ReactionsCh. 10 - 11.Introduction: How Radicals Formand How They React HeterolysisionsHomolysisradicalsCh. 10 - 2Production of RadicalsHomolysis of covalent bonds Need heat or light (h)Ch. 10 - 32. Homolytic Bond Dissociat
South Carolina - CHEM - 333
Chapter 11Alcohols & EthersCh. 11 - 11. Structure & NomenclatureAlcohols have a hydroxyl (OH) groupbonded to a saturated carbon atom(sp3 hybridized)1o2oEthanol2-Propanol(isopropylalcohol)3o2-Methyl2-propanol(tert-butyl alcohol)Ch. 11 - 21
South Carolina - CHEM - 333
7. Conversion of Alcohols intoAlkyl HalidesROHRX HX (X = Cl, Br, I) PBr3 SOCl2Ch. 11 - 28A. Mechanisms of the Reactions ofAlcohols with HXSecondary, tertiary, allylic, and benzylicalcohols appear to react by amechanism that involves the form
South Carolina - CHEM - 333
11E. Silyl Ether Protecting GroupsA hydroxyl group can also be protectedby converting it to a silyl ether group264135421365Ch. 11 - 1 Direct reaction will not work(Not Formed) InsteadCh. 11 - 2 Need to protect the OH groupfirstCh. 11
South Carolina - CHEM - 333
17. Summary of Reactions ofAlkenes, Alcohols and EthersSynthesis of alcoholsXOHO1.2. H2OMgBrOH(1o alcohol)1. BH3 THF2. H2O2, NaOHCh. 11 - 1Synthesis of alcohols1. BH3 THF2. H2O2, NaOH+H , H2OOH(2o alcohol)1. Hg(OAc)2, H2O2. NaBH4or