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South Carolina - PYSC - 101
DevelopmentAcrosstheLifespan1.2.3.4.FetalDevelopmentChildDevelopmentAdolescenceAdulthoodandAging1.FetalDevelopmentnGametesnChromosomesnSpermEggXX=femaleXY=maleMaturationFetalDevelopmentnnTrimestersZygotenEmbryonAfertilizedegg
South Carolina - PYSC - 101
DifferentMemoryStoresWe have three different memorystores, or sets of neurons thatmaintain informationEach memory store has a differentDuration: the length of time information ismaintainedCapacity: the amount of information thatis maintainedDiffe
South Carolina - PYSC - 101
LearningA relatively permanent change in behavior thatresults from experiencel Psychologistsare interested in both the contentof learning and the processl TypesClassical conditioningl Operant conditioningl Cognitive and social learninglClassica
South Carolina - PYSC - 101
ConsciousnessOurawarenessofourownexistence,sensations,andcognitionsStreamofconsciousnessWilliamJamesWhatfunctiondoesconsciousnessserve?ConsciousnessNormalconsciousnessAlteredstatesofconsciousnessSleepingDreamingHypnosisMeditationDruginducedO
South Carolina - PYSC - 101
Sensation and PerceptionSensationThe awareness of properties of an object oran event when a sensory receptor isstimulatedPerceptionThe act of organizing and interpreting sensoryinput as signaling a particular object or eventIllusionsWhen percepti
South Carolina - PYSC - 101
PsychologyInDepth:Psychology,geneticsandepigeneticsA)GenesasblueprintsB)EpigeneticsC)CareTakingD)RettSyndromeGenesasblueprintsMendelianinheritanceDeoxyribonucleicacid(DNA)GeneGenotypePhenotypeGenesasblueprintsComplexinheritanceevenforsimplet
South Carolina - PYSC - 101
The Biology of Mind and Behaviorl Theneuron and its partsl Drugs and their actionsl The Brain and its partsThe Neuronl Thebasic unit of the nervous systemReceives signals from neurons or sensory organsProcesses informationSends signals to other
South Carolina - PYSC - 101
Chapter 2: The Research ProcessA.B.C.D.The Scientific MethodDesigning ExperimentsStatisticsLying with statisticsA. The Scientific Methodl Specifya probleml Systematic observationl Form a hypothesisl Test the hypothesis with datal Formulate
South Carolina - PYSC - 101
Important InfoSyllabusTextbook, My PsychLabRequirementsBlackboardNature of the courseSupplemental Instructor: Margo ScaleTeaching Assistant for grading: AshleyRobinsonImportant InfoParticipant pool participationParticipant Pool TAEmail: psycpo
South Carolina - CHEM - 333
South Carolina - CHEM - 333
South Carolina - CHEM - 333
South Carolina - CHEM - 333
South Carolina - CHEM - 333
South Carolina - CHEM - 333
South Carolina - CHEM - 333
South Carolina - CHEM - 333
South Carolina - CHEM - 333
South Carolina - CHEM - 333
8.Sigma Bonds & Bond RotationTwo groups bonded by a single bondcan undergo rotation about that bondwith respect to each otherConformations temporary molecularshapes result from a rotation about a singlebondConformer each possible structure ofconf
South Carolina - CHEM - 333
Ch. 4 - 110. The Relative Stabilities ofCycloalkanes: Ring StrainCycloalkanes do not have the samerelative stability due to ring strain Ring strain comprises:Angle strain result of deviation fromideal bond angles caused by inherentstructural const
South Carolina - CHEM - 333
7.Naming Enantiomers: R,S-SystemUsing only the IUPAC naming that we havelearned so far, these two enantiomers willhave the same name: 2-Butanol This is undesirable because each compoundmust have its own distinct nameCh. 5 - 17A. How to Assign (R)
South Carolina - CHEM - 333
9A. Racemic Forms An equimolar mixture of twoenantiomers is called a racemic mixture(or racemate or racemic form) A racemic mixture causes no netrotation of plane-polarized lightrotationequal & oppositerotation by theenantiomerCh. 5 - 1Enantiom
South Carolina - CHEM - 333
2011 Nobel Prize in Physiology or Medicinetheir discoveries concerning the activation of innate immunityJules HoffmannBruce BeutlerRalph Steinman13. Fischer Projection Formulas13A. How To Draw and Use FischerProjectionsProjectionsFischerProjecti
South Carolina - CHEM - 333
Israeli scientist Daniel Shechtman wonthe 2011 Nobel Prize in chemistryfor his discovery of quasicrystals1. Organic HalidesCXX = Cl, Br, IHalogens are more electronegativethan carbonCh. 6 - 2Carbon-Halogen Bond Lengthsand Bond StrengthCX BondL
South Carolina - CHEM - 333
9.The Reaction of tert-Butyl Chloridewith Hydroxide Ion: An SN1 Reaction3323333Multistep Reactions & the RateDetermining StepCh. 6 - 1Free Energy Diagram of SN1 ReactionsT.S. (1)T.S. (2)T.S. (3)(CH3)3C+ BrG1(CH3)3CBr+ H2O(CH3)3C -OH2+
South Carolina - CHEM - 333
14E. The Nature of the Leaving GroupSN1 Reaction:+SN2 Reaction:Ch. 6 - 1a poorleaving groupHa goodleaving group+a strongbasic anionweakbaseCh. 6 - 215. Elimination Reactions of AlkylHalidesSubstitution reaction (SN) andelimination react
South Carolina - CHEM - 333
Chapter 7Alkenes and Alkynes I:Properties and Synthesis.Elimination Reactionsof Alkyl HalidesCh. 7 - 11. IntroductionAlkenes Hydrocarbons containing C=C Old name: olefinsCH2OHVitamin AH3CH3CHHOHCholesterolCh. 7 - 2Alkynes Hydrocarbons
South Carolina - CHEM - 333
6C. The Stereochemistry of E2ReactionsThe 5 atoms involved in the transitionstate of an E2 reaction (including thebase) must lie in the same plane The anti coplanar conformation is thepreferred transition state geometry The anti coplanar transition
South Carolina - CHEM - 333
9.The Acidity of Terminal AlkynesAcetylenic hydrogenspsp2HHCCHpKa = 25HHCHsp3CHHpKa = 44HCCHHHpKa = 50Relative basicity of the conjugate baseCh. 7 - 1HpComparison of acidity and basicity of1st row elements of the Periodic T
South Carolina - CHEM - 333
Chapter 8Alkenes and Alkynes II:Addition ReactionsCh. 8 - 11. Addition Reactions of AlkenesECC+ENuCCNuCh. 8 - 21A. How To Understand Additionsto AlkenestoThis is an addition reaction: ENuadded across the double bondECC+ENuCCNu-b
South Carolina - CHEM - 333
6.Alcohols from Alkenes throughOxymercurationDemercuration:Markovnikov AdditionStep 1: OxymercurationStep 2: Demercuration4Ch. 8 - 12H2O4MethanidemigrationComparisonacid-catalyzed hydrationCh. 8 - 2Solvomercuration-Demercuration232234
South Carolina - CHEM - 333
12. Electrophilic Addition of Bromineand Chlorine to AlkenesAddition of XX (X = Cl, Br) across aC=C bond24Ch. 8 - 1Stereochemistry Anti addition4NCh. 8 - 213. Stereospecific ReactionsA reaction is stereospecific when aparticular stereoisomer
South Carolina - CHEM - 333
15. Oxidation of Alkenes:Syn 1,2-DihydroxylationOverall: addition of 2 OH groups acrossa C=C bondReagents: dilute KMnO4 / OH / H2O /cold or OsO4, pyridine then NaHSO3, H2OCh. 8 - 1Comparison of the two reagents KMnO4: usually lower yield andpossi
South Carolina - CHEM - 333
Chapter 10Radical ReactionsCh. 10 - 11.Introduction: How Radicals Formand How They React HeterolysisionsHomolysisradicalsCh. 10 - 2Production of RadicalsHomolysis of covalent bonds Need heat or light (h)Ch. 10 - 32. Homolytic Bond Dissociat
South Carolina - CHEM - 333
Chapter 11Alcohols & EthersCh. 11 - 11. Structure & NomenclatureAlcohols have a hydroxyl (OH) groupbonded to a saturated carbon atom(sp3 hybridized)1o2oEthanol2-Propanol(isopropylalcohol)3o2-Methyl2-propanol(tert-butyl alcohol)Ch. 11 - 21
South Carolina - CHEM - 333
7. Conversion of Alcohols intoAlkyl HalidesROHRX HX (X = Cl, Br, I) PBr3 SOCl2Ch. 11 - 28A. Mechanisms of the Reactions ofAlcohols with HXSecondary, tertiary, allylic, and benzylicalcohols appear to react by amechanism that involves the form
South Carolina - CHEM - 333
11E. Silyl Ether Protecting GroupsA hydroxyl group can also be protectedby converting it to a silyl ether group264135421365Ch. 11 - 1 Direct reaction will not work(Not Formed) InsteadCh. 11 - 2 Need to protect the OH groupfirstCh. 11
South Carolina - CHEM - 333
17. Summary of Reactions ofAlkenes, Alcohols and EthersSynthesis of alcoholsXOHO1.2. H2OMgBrOH(1o alcohol)1. BH3 THF2. H2O2, NaOHCh. 11 - 1Synthesis of alcohols1. BH3 THF2. H2O2, NaOH+H , H2OOH(2o alcohol)1. Hg(OAc)2, H2O2. NaBH4or
South Carolina - CHEM - 333
Extra Office Hour:Nov 28 (Mon): 11:30-2:30pmNov 29 (Tues): 9:00-1:00pmNov 30 (Wed): 11:30-2:30pmDec 1 (Thurs): 11:00-2:30pmDec 5 (Mon): 9:00-2:30pmDec 6 (Tuesday): Final Exam (3h)Final Exam Grade: 200 pts total.If you decide to drop final exam,yo
South Carolina - CHEM - 333
Extra Office Hour:Nov 28 (Mon): 11:30-2:30pmNov 29 (Tues): 9:00-1:00pmNov 30 (Wed): 11:30-2:30pmDec 1 (Thurs): 11:00-2:30pmDec 5 (Mon): 9:00-12:00pm3:00-5:00pmDec 6 (Tuesday): Final Exam (3h)9:00am-12:00pm, PSC 006Final Exam Grade: 200 pts total.
South Carolina - CHEM - 333
11. Energy ChangesThe two fundamental types of energyare kinetic energy and potential energyKinetic energy is the energy an objecthas because of its motion; it equalsone-half the objects mass multipliedby the square of its velocity KE = m2Ch. 3 -
South Carolina - CHEM - 333
8.Relationships between Structureand AcidityHFHClHBrHIBond Length ()0.921.281.411.60pKa3.2-7-9-10Increasing acidityThe strength of HX bond HF > HCl > HBr > HIThe stronger the HX bond,the weaker the acid.Ch. 3 - 18.Structure and Aci
South Carolina - CHEM - 333
3.Lewis Acids and BasesLewis Acids are electron pair acceptorsLewis Bases are electron pair donorsIn Lewis acidbase theory, theattraction of oppositely chargedspecies is fundamental to reactivityCh. 3 - 14.Heterolysis of Bonds to Carbon:Carbocat
South Carolina - CHEM - 333
1.Reactions and Their MechanismsAlmost all organic reactions fall intoone of four categories: Substitutions Additions Eliminations RearrangementsCh. 3 - 1 SubstitutionsCharacteristic reactions ofsaturated compounds such asalkanes and alkyl hal
South Carolina - CHEM - 333
4. Alkyl Halides or HaloalkanesRX (X = F, Cl, Br, I)5. AlcoholsROH6. EthersROR7. AminesRNH2Ch. 2 - 18.Aldehydes and KetonesOORHR(ketones)(aldehydes)9.RCarboxylic Acids, Esters, and AmidesOOROH(carboxylicacid)ROR(ester)OROC
South Carolina - CHEM - 333
Chapter 2Families of CarbonCompoundsFunctional Groups& Intermolecular ForcesCh. 2 - 11. HydrocarbonsHydrocarbons are compounds thatcontain only carbon and hydrogenatomsAlkyl group Alkanes Alkenes Alkynes AromaticsAromatic groupCh. 2 - 21A
South Carolina - CHEM - 333
14. The Structure of Ethyne(Acetylene): sp HybridizationspCh. 1 - 1Ch. 1 - 2Ch. 1 - 3Ch. 1 - 415. Molecular Geometry: TheValence Shell Electron PairRepulsion ModelCh. 1 - 517. How to Interpret and WriteStructural Formulas1-PropanolBall-and-S
South Carolina - CHEM - 333
11. Molecular OrbitalsCh. 1 - 1A bonding molecular orbital (molec)results when two orbitals of the same phaseoverlapAn antibonding molecular orbital(*molec) results when two orbitals ofopposite phase overlapCh. 1 - 212. The Structure of Methane a
South Carolina - CHEM - 333
7. Formal Charges and How toCalculate ThemFormal charge number of valence electrons1/2 number of shared electrons numberof unshared electronsorF = Z - S /2 - Uwhere F is the formal charge, Z is thegroup number of the element, S equals thenumber o
South Carolina - CHEM - 333
CHEM 333 Section 501 HonorsOrganic Chemistry IProf. Chuanbing TangLecture: MWF 10:10 11:00 AM, PSC 006Recitation: F 1:25PM- 2:15PM, PSC 104 E-mail: tang4@mailbox.sc.edu (the best way to reach me!) Office: Horizon I-234; Phone: 777-3628 Office Hours
South Carolina - CHEM - 333
3C. Nomenclature of Branched AlkylGroupsFor alkanes with more than two carbonatoms, more than one derived alkylgroup is possible Three-carbon groupsPropylIsopropyl(or 1-methylethyl)Ch. 4 - 1Four-carbon groupsButylsec-butyl(1-methylpropyl)Iso
South Carolina - CHEM - 333
3B. Nomenclature of Branched-ChainAlkanes: Rules1. Use the longest continuous carbon chain as parent name2. Use the lowest number of the substituent (sub)3. Use the number obtained by Rule 2 to designate the location ofthe sub4. # of substituents 2,
South Carolina - ECON - 222
ECON 210Fall 07SankaranSTUDY GUIDEMIDTERM # 3Remember to bring a non-programmable, non-graphical calculator, some pencils,and an eraser.I have tried to include all the important material that you will be tested on in thisreview sheet. The exam can
South Carolina - ECON - 222
Quiz 3Multiple ChoiceIdentify the choice that best completes the statement or answers the question.________1. Over time, people have come to rely more on market-produced goods and less on goods that they produce forthemselves. For example, bus
South Carolina - ECON - 222
econ222 quiz 3Multiple ChoiceIdentify the choice that best completes the statement or answers the question._1. Equilibrium Analysis: Assume that chicken is a normal good. The equilibrium market price and equilibriumquantity of chicken would increase
South Carolina - ECON - 222
Quiz 1Multiple ChoiceIdentify the letter of the choice that best completes the statement or answers the question._1. After much consideration, you have made a rational decision to attend your best friend's party instead of yourEcon class this Friday.
South Carolina - ECON - 221
Name: _ Class: _ Date: _ID: Aquiz oligopolyMultiple ChoiceIdentify the letter of the choice that best completes the statement or answers the question._1. Which of the following best describes why each member of a cartel has an incentive to increase
South Carolina - ECON - 221
Name: _ Class: _ Date: _ID: AQuiz 8Multiple ChoiceIdentify the letter of the choice that best completes the statement or answers the question.____1. The profit-maximization problem for a monopolist differs from that of a competitive firm in which
South Carolina - ECON - 221
Name: _ Class: _ Date: _ID: Aquiz 7Multiple ChoiceIdentify the letter of the choice that best completes the statement or answers the question._1. Suppose that you have won a wrongful injury lawsuit and have been awarded $5 million dollars.However,
South Carolina - ECON - 221
Name: _ Class: _ Date: _Quiz 6Multiple ChoiceIdentify the letter of the choice that best completes the statement or answers the question.Use this picture to answer the questions that follow109.509Supply8.50MSB87.507Demand50____607080
South Carolina - ECON - 221
Name: _ Class: _ Date: _ID: AQuiz 5Multiple ChoiceIdentify the letter of the choice that best completes the statement or answers the question.5.255.004.754.504.254.003.753.503.253.002.752.502.25SD2.00300____320 340360 380 4001.