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chem 105a notes

Course: CHEM 105a, Fall 2011
School: USC
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gas Ideal particles: 1. Are volumeless 2. Strike each other with elastic collisions 3. Have no attraction to one another Real gases approach pv=nrt behavior under LOW pressure and HIGH temperature Low P: the particles volume is less significant High T: high KE reduces attractions, makes collisions more elastic This is where vaaderwaals equation comes in; modification of ideal gas law that fits more real gas...

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gas Ideal particles: 1. Are volumeless 2. Strike each other with elastic collisions 3. Have no attraction to one another Real gases approach pv=nrt behavior under LOW pressure and HIGH temperature Low P: the particles volume is less significant High T: high KE reduces attractions, makes collisions more elastic This is where vaaderwaals equation comes in; modification of ideal gas law that fits more real gas behavior P + a (n/V)2 x (V nb) = nRT Accounts for interactions among gas particles Gases with weak intermolecular forces have low values of a P corrected for intermolecular forces V corrected for gas volume; subtracts the volume of gas molecules generally increases themselves; with the size of the molecule Exam covers 4 and 5 EXCEPT gas forming reactions and 5.11 Energy: capacity to do work Work: force acting over a distance Potential energy: energy stored due to position or composition Kinetic energy: energy due to motion of an object When delta E is negative; thats from systems perspective Lose energy = negative Gain energy = positive J = the energy needed to move 1 kg mass 1 m Calorie: energy needed to raise 1 g of water 1 C The total energy of the universe is constant or energy is neither created nor destroyed Energy can be transferred between objects; from one form to another
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697170736971Ag+ + ClPb2+ + 2 ClHg22+ + 2 ClHg2Cl2AgClPbCl273697173697174697174697274697274
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81t81b8285t81tBa 2+ + CO3 2BaCO3---Ag+ + Cl Ag+ + Br Ag+ + I -AgClAgBrAgIThe test involves placing each ionin a separate tube, and theunknown as well.Silver ions are then added to precipitatethe ions.Discard thesolutionsSave thepptsC
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95 t95 t95 b95 b91096 t96 t96 b97 t91097 t97 b97 b98 t1098 t98 b99109999999999100 t100 t100 t100 t100 t100 t100 t100 t100 b100 b100 b100 b100 b100 b100 b100 b9100 b101 t101 t101 b101 b101 bSuppose you solve
Moraine Valley Community College - CHM - 132
125 t125 b125 b125 b125 b125 b125 b126 t126 b126 b126 b126 b127 t127 t127 t127 bExpandedon next slide1010127 b128 t128 t128 t128 t128 t128 t128 b128 b128 b129 t109 b129 t129 t129 t121 b129 t129 t129 b109 b10129 b1
Moraine Valley Community College - CHM - 132
147 t 1-147 t 1147 t 2147 t 2147 t 2147 t 2147 t 2147 b147 b147 b147 b147 b148148147 b148148148148148148148148148-Commercial batteries must be manufactured tofit into the device in which they will be used.149 t149 t149 bInab
Moraine Valley Community College - CHM - 132
178 t178 b187 t187 t187 t187 t187 t187 b187 b187 b187 b187 b187 b187 b188 t188 t188 t188 t188 t188 b188 b188 b9188 b189 t189 t189 t9189 t189 t189 t189 t189 t189 t910189 t189 t189 t189 b190 t190 t190 b9190 b191
Moraine Valley Community College - CHM - 132
207 t207 t3207 t7207 t207 b207 b208209 t209 t209 t209 t209 t209 b209 b4209 b209 b62106210210210210210210210210211 t211 t211 t211 t211 b6212 t6212 t212 t212 t212 t212 t208212 bExperimenterhas no controlover th
Moraine Valley Community College - CHM - 132
209 t210214 t214 b218 t223421224 t224 t224 t224 t224 t224 t223224 b224 b224 b224 b223225 t225 t223225 t225 t225 t225 b225 b225 b225 b225 b225 bIf the next slide is 100%The next slide isabout .000236%2082264227 t227 t
Moraine Valley Community College - CHM - 132
347 b349 t350 t348 t348 b350 bConditions That Change EcellTemperature although temp affects Ecell ,we will not consider this effect.Concentration concentrations of thesubstances in the cell affect Ecell .The Nernst Equation describes the effect
Moraine Valley Community College - CHM - 132
375 t375 b376 t376 b 4377 t377 t377 t377 b377 b377 b377 b377 b378 t378 t378 t378 t378 t378 b378 b378 b379 t-379 b379 b379 b379 b380 t380 t380 t380 b381 t 1381 t 2381 b381 b381 b382383 t383 t383 t383 b383 b383 b383
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Further, the deflection at B must be the same for both segments; therefore, equate Eqs. (d) and (i):wL4 C1L 5wL4 C3 L+=++ C419223842(k)Evaluate constants: Solve Eqs. (g), (j), and (k) simultaneously to determine the values of constants C1,C3,
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Texas A&M - MATH - 323
Texas A&M - MATH - 323