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Course: CHEM 360, Spring 2012
School: Colby
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Exam Name__________________________________________ Sample Questions #2 (Chapters 5, 8-10, 16) Chemistry 112 Multi ple Choice 1. The hump of the camel cont ains stores of a) water b) carbohydrates c) proteins d) triglyc erides Reaction Pathway A Reaction Pathway B Energy Energy Energy Energy 2. Which of the following repres ents the fast est, thermody namic ally fav orable reaction? Reaction Pathway...

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Exam Name__________________________________________ Sample Questions #2 (Chapters 5, 8-10, 16) Chemistry 112 Multi ple Choice 1. The hump of the camel cont ains stores of a) water b) carbohydrates c) proteins d) triglyc erides Reaction Pathway A Reaction Pathway B Energy Energy Energy Energy 2. Which of the following repres ents the fast est, thermody namic ally fav orable reaction? Reaction Pathway Reaction Pathway C D 3. Which of the following would dissolv e in your coffee the fastest? (Assume equivalent masses.) a) powdered sugar b) table sugar c) sugar cubes d) a lollipop 4. A biologic al molec ule is f ound to cont ain c arbon, hydrogen, oxygen, nitrogen, and phos phorus. It is most likely to be a a) carbohydrate b) nuc leic acid c) protein d) lipid 5. The s mall organic molecule succinate is an intermediate in sugar metabolis m. The enzy me that catalyzes conversion of succinate als o binds malonat e, which is structurally similar to succinat e. If malonate does not undergo reaction, what is its role in this reaction? a) substrate b) inhibit or c) product d) catalyst 6. Medic ally speaking, why is consumption of human brains potentially haz ardous ? a) Nonpolar drugs accumulate in brains, potentially leading to overdos es. b) Brains can be infected wit h prions, leading to the human form of mad c ow disease. c) Brains are high in saturated fat and cholesterol, leading to inc reased risk of heart attack. d) Radioactive iodine accumulat es in the thy mus of the brain. 7. The function of an enzy me depends on which of t he following? a) the sequenc e of its amino acids b) its three-dimensional struct ure c) specific interactions with its substrate d) all of the above 8. Chromatography is: a) used to separate molecules in a mixture bas ed on properties such as polarity b) used to separate biological molecules with an electric field c) used to identify molec ules based on interactions with electromagnetic radiation d) a general name for sev eral types of tests that use color c hange to detect coc aine 9. A bag seized during a drug bust is believ ed to contain cocaine. Which of the following would be most conclusiv e that the material is cocaine? a) The mat erial is a white powder. b) The mat erial giv es a positiv e res ult in the Scott test. c) The bag is labeled cocaine. d) The mass spectrum of the material is identical to t hat of a cocaine standard. 10. Who founded the worlds first crime laboratory ? a) Sherlock Holmes b) Edmond Locard c) Gil Grissom d) Henry Faulds 11. Whic h of the following is the major adv ant age of PCR-STR when compared to RFLP? a) PCR-STR uses nuclear DNA, which is more unique. b) PCR-STR can be us ed on any biological sample, whereas RFLP analysis c an be done only on blood. c) PCR-STR det ects differences in genes, whereas RFLP monitors non-coding DNA. d) PCR-STR can be done on much s maller amounts of material. 12. Whic h of the following is not a macronutrient? a) water b) carbohydrates c) lipids d) proteins 13. How does the body regulate blood sugar levels? a) The rat e of digestion slows or speeds up depending on blood sugar lev els. b) Insulin signals cells to tak e up gluc ose when blood sugar is high. c) Insulin signals the liv er to release glucos e when blood s ugar is low. d) The brain uses less sugar when blood sugar is low. 14. ATP releas es energy to power cellular proces ses a) through reaction with creatine b) through hy drolys is to ADP c) through oxidation d) through neutralization 15. Which of the following is not true of aerobic exercise? a) The maximum amount of ATP is produced during aerobic exercis e. b) Examples of aerobic ex ercis e include bowling and golf. c) Aerobic metabolis m c annot be s ustained for more than a few minutes. d) Both fats and carbohydrates can fuel aerobic exercise. Short Answer 1. Circ all le examples of potential energy below. (Flash is my dog.) Flash taking a nap Flash at the top of a hill on a sled Flashs body fat Flashs dinner Flash ready to jump off a dock Flash chasing a soccer ball 2 2. a) Draw the energy diagram f or the energetically favorable reaction of diamonds conv erting to graphit e, labeling the react ant and the product. b) On the same diagram, draw the s ame reaction in the presence of a cat alyst. c) Why doesnt all y our diamond jewelry c onvert to graphit e, giv en t hat this is the energetically downhill direction for this reaction? 3. Next to each statement below, write the c orresponding law of thermodynamics. _____ You can put a pig into a machine and get sausage, but you can't put sausage into the machine and get the pig back. _____ You cant get there from here. _____ My shoe is off; my foot is cold, I have a bird I like to hold. _____ You cant mak e an omelette without break ing a few eggs. 4. Circ le all the ex othermic process es below. Put an X in the box next to any proc esses for which entropy increas es. fireworks going off phot osynthesis: 6 CO2 (g) + 6 H2O (g) 6 O2 (g) + C6H12O6 (s) cold pack reaction: NH4NO3 (s) NH4+(aq) + NO3- (aq) sublimation of H2O burning wood 5. You are going on a backpacking trip and have t o carry all your own food. a) Whic h would provide the most energy: a pound of fat, a pound of sugar, or a pound of protein? (Circle one choice.) pound of fat pound of sugar pound of prot ein 3 all are equiv alent b) In terms of good health, does it matter what source of energy you bring? (That is, would fats, sugars, and proteins all be equiv alent?) Briefly explain. 6. For each type of evidenc e below, name the best technique for its analysis at the crime lab and give a one-sentence description of the dat a produc ed and its interpretation. a) tissue sample from Anna Anderson to det ermine whet her she was Anastas ia Romanov b) debris collected from a possible arson c) bag of white powder seiz ed in a drug bust d) blonde hair recov ered from the rape of a brunet te 7. Fill in the letter(s ) of the appropriate description(s ) for each of these molecules. A molecule may hav e more than one description. Molecules: __________ Car bohydr ate __________ Lipi d __________Pr otei n __________Nucl eic Aci d Descripti ons (may be used more than once): A) building block of cell membranes B) compos ed of amino acid building blocks C) composed of monosacc haride building blocks D) generally contains only carbon, hy drogen, and oxygen E) most us eful in forens ic settings F) the molecule shown here belongs to this class of compound H2 C H3C CH3 H2 C H2 C H2C CH HO 4 H2C CH3 CH C C C H2 C CH CH C H2 C H2 CH3 CH CH3 CH2 CH2 C H CH H2 C 8. a) To what class of perf ormanc e-enhancing drugs does the molecule shown here belong? H2 C H2 C C O b) What type of athlete would most benefit from this molecule? H2 C CH3 H2 C C CH3 CH CH C CH C C H O C CH2 C H2 CH2 C H2 c) Circle any of the following that would be ex pected to improve performance (wit hout potentially s erious side effects) in an endurance at hlete on a hot day ? ERG EPO carnitine sleeping in a hyperbaric chamber Probl ems. You must clearly show your work for full credit. 1. This question is about the energy bar with the label s hown here. a) How many Calories are in this energy bar? b) Wit h the correct number of significant figures, how many joules is this ? If you didnt get an ans wer for part a, use 100 Calories and do this question any way. (Hint: 1 cal = 4. 184 J) 2. A closed vessel c ontains 104 g of C2H2 and 300 g of O2 that react to form carbon dioxide and water. 236 kJ of heat are releas ed per mole of C2H2. a) Write the balanced equation for this reaction. b) How much heat is releas ed in this reaction? 5
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