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Course: ECON 332, Fall 2011
School: Rutgers
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began We class concluding the e-mail discussion on the disadvantages of emission fees. Issues raised included: o Uncertainty Compared to command and control, emission fees provide more certainty on costs, but less certainty on the final level of emissions. o Geographically-varying damage Market-based policies guarantee an overall goal, but they don't guarantee which firms will reduce and which firms won't. If...

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began We class concluding the e-mail discussion on the disadvantages of emission fees. Issues raised included: o Uncertainty Compared to command and control, emission fees provide more certainty on costs, but less certainty on the final level of emissions. o Geographically-varying damage Market-based policies guarantee an overall goal, but they don't guarantee which firms will reduce and which firms won't. If firms near an urban center choose to pay the fee rather than reduce emissions, damages may remain high. Varying the fee based on potential damages can help address this. o Distributional issues Concerns about equity might make some environmental taxes politically unpopular. For example, lower income families spend more of their income on gasoline, making a gas tax a regressive. While all policies raise the possibility of costs being passed on to consumers, there are more costs to be passed on here, as firms pay both for abatement and the fee for the remaining units of pollution. o Monitoring costs To charge a fee per unit of pollution, all pollution must be monitored and measured. o Flexibility Compared to regulations that mandate a specific abatement technique, fees are more flexible In addition, if economic conditions change, fees allow responses to adjust to new conditions. I. Implementation Issues We began class by discussing practical issues for implementing an environmental tax. o Note that most U.S. taxes that affect the environment were not implemented primarily for environmental reasons. Other concerns, such as raising revenue, tend to be more important. Questions for designing an environmental excise tax: o What is to be taxed? That is, what is the tax base. May be direct (e.g. CFCs, emissions), or indirect (e.g. gasoline) o Who is to be taxed? Here were focusing on administration, not ultimate incidence. Recall that economic incidence is independent of legal incidence. Ideally, we would like to tax users directly. However, it can be difficult to know the users. For example, to prevent non-point pollution, we may tax fertilizer, since we cant tax each farmer for his or her individual contribution. Also, there may be many users. For CFCs, it was easier to tax production than tax each user. What tax rate to impose? This is where most of the economic analysis comes in. Problems: Knowing MD is difficult. Therefore it is hard to set the tax correctly. Uncertainty could be bad if mistakes costly. As we'll see in a couple of weeks, in these cases (e.g. threshold effects), regulation may be better. Although we also might not know about MAC, taxes may help us learn about the MAC of firms. They will choose to pay the tax when tax < MAC. Are their ancillary policy goals? Taxes are not enacted in a policy vacuum. Multiple goals often conflict. Common conflict: revenue vs. abatement Taxes are a source of revenue. If an environmental tax is successful, it lowers emissions, thus lowering the tax base. Therefore, if revenues are important, we might adjust the rate. What should be done with the revenue? Economists have noted that these taxes not only help the environment, but that they can also improve economic efficiency. The theoretical argument is as follows: Most taxes cause distortions in the economy. However, environmental taxes correct a distortion. Since the revenues from environmental taxes can be used to lower other taxes, the economy benefits. However, most economists find these effects to be small. The main reason is that the tax base for environmental taxes is much smaller than the tax base for more general taxes, such as income taxes. Thus, even a large environmental tax only raises enough revenue to allow a small cut in a more general tax. o o II. Examples Although many taxes may affect the environment, frequent use of tax policies directly focused on environmental issues began in the 1970s (e.g energy conservation tax credits, gas guzzler tax) Environmental excise taxes generally fall in one of three categories: 1. User fees These are taxes designed to raise revenue for a specific purpose. Usually, the purpose is a public good. Examples: Excise taxes on sport fishing equipment and motorboat fuels fund programs such as fish hatcheries designed to ensure the survival of fish species. The federal gas tax is essentially a user fee, since revenues go into the Highway Trust Fund. Note that reducing pollution is not a goal of the federal gas tax. 2. Insurance premia in mandated risk pooling Taxes collected by an industry to pay for liability against possible damages. Examples: Oil Spill Liability Trust Fund tax of 5 cents per barrel of oil Superfund tax on chemical companies. Revenue pays for cleanup of future hazardous waste sites. 3. Pigouvian taxes Few environmental taxes explicitly aim to internalize external damages. Some that do include: Tax on ozone-depleting chemicals Passed in 1989 to help eliminate chlorofluorocarbons (CFCs) A result of US support of the Montreal Protocol. Production of CFCs is taxed per pound 1990 level was $1.37 per pound The amount has increased over time Gas guzzler tax on vehicles below a certain MPG Applies only to cars (not trucks) Applies to cars below 22.5 MPG Ranges from $1,000 to $7,700, depending on fuel efficiency Examples of environmental taxes (source: EPA Report: The United States Experience with Economic Incentives for Protecting the Environment, chapter 4) 1. Emission fees in the South Coast Air Quality Management District (SCAQMD) in Southern California Facilities exceeding their allowable emissions limits must pay fees 2. Solid waste disposal fees, such as stickers for trash Reduce weight of trash in landfills, but can also lead to more illegal dumping. Lesson: beware of unintended consequences. 3. Several states have taxes for hard to dispose of items (tires, oil, refrigerators) 4. In response to suburban sprawl, several New Jersey counties assess open space taxes 1 to 5 cents per $100 assessed value of property Money must go to trust funds to be used for purchasing open space, developing parks, etc. Examples of subsidies in U.S. (source: EPA Report: The United States Experience with Economic Incentives for Protecting the Environment, chapter 7) 1. Income tax credits in Colorado for conservation easements 2. Brownfield development grants (also include changes in liability law) For example, in New Jersey, developers get a 10 year property tax exemption for remediating a site in accordance with state standards and return it to industrial or commercial use. 3. Loans for pollution control expenses The state of California issues tax-exempt bonds to provide low interest loans to small businesses for pollution control devices & solid waste recovery projects. 4. Farming and land preservation The Conservation Reserve Program, part of the U.S. Food Security Act of 1985 (1985 Farm Bill) pays farmers for taking environmentally sensitive land out of cultivation.- The Conservation Reserve Program, part of the U.S. Food Security Act of 1985 (1985 Farm Bill) pays farmers for taking environmentally sensitive land out of cultivation. 5. Tax credits for alternative fuels Available for alternative fueled cars Available for renewable energy (1.6 cents per kWh in 1995 for biomass and wind) Estimated cost to government $970 million 6. Income tax credits for easements in Colorado Income tax credits are available for 50% of the fair-market value of the easement, up to $375,000. For those with less taxable income, such as ranchers, there are two options: If there is a budget surplus, the credit is refundable. If there is no surplus, the credits can be sold to buyers who have more taxable income. The credits sell for 80-85 cents per dollar of credit. There is little regulation of the valuation of easements Some transactions have been found to be fraudulent Colorado doesn't audit the credits. This is left to the Internal Revenue Service. Impact Total acres protected: 2000: 350,000 almost 2005: 1 million Cost to government in lost revenue: 2001: $2.3 million 2005: $85.1 million Proponents argue that, despite lost tax revenue, the preserved open space raises the value of neighboring land. 7. Note that all these subsidies have a cost: there is lost tax revenue. Developing country examples (from Randall Bluffstone, Environmental Taxes in Developing and Transitional Economies, Public Finance and Management 2003, 3(1), 143-175). 1. China Has used emissions fees for air and water since the early 1980s. Uses a two-tiered system Charge a basic fee per unit, plus a pollution levy for industrial air or water pollution that exceeds annual limits. Firms are only charged for emissions of their worst pollutant. Fees are assessed at national levels, but implemented by local environmental protection boards. Rates vary by locality. Highest in richer urban areas. Uses self reporting by firms, with spot checks by local environmental officials. 80% of air pollution revenues to go pollution reduction programs. 2. Central and Eastern Europe Many Central and Eastern European countries, as well as the former Soviet Union, implemented environmental taxes in the late 1970s and early 1980s. Goal: to give incentives for state owned enterprises to reduce emissions. Rates typically not market based (e.g. considering marginal abatement costs), but rather based on complex engineering formulas. Could lead to odd results. For example, prior to 1999, Lithuania charged several million dollars per ton of SO2. Not surprisingly, non-payment was an issue. 3. Malaysia Uses a licensing fee for water pollution from palm oil production. Uses a two-tiered system Emissions above concentration standards are charged 10 times more. Firms have used a variety of techniques to reduce wastewater emissions, suggesting that there may be differences in abatement costs across firms. 4. Columbia Began water effluent charges in 1974 Rates increased in 1993 Prior to this, rates were low, and typically only covered administrative costs. The new rates vary by region, and are linked to damages. Rates change every 6 months! Revenues go to local environmental agencies. Nationally, waste water emissions are estimated to have fallen by about 20-25% in response to the fees. III. Comparison of Policies: NOX Charges in France and Sweden The article by Millock and Sterner looks at two fee systems for NOX emissions, in France and Sweden. o Both build off existing command and control systems. o Both driven by the United Nations Economic Commission for European Convention on Long-Range Transboundary Air Pollution, which sets specific NOX limits to be met by 2010. Based on these goals, the EU set national emission ceilings in 2000. France needed 54% reduction from 1990 levels Sweden needed 56% reduction from 1990 levels o Potential technologies: Changes in combustion process Fuel switching Selective catalytic reduction for industry, catalytic converters for cars o Measurement of emissions important to properly calculate fees. Sweden o Acid rain important issue, because Swedish bedrock has little calcium, and thus does not provide buffering capacity. Goal: reduce NOX emissions by 30% by 1995, compared to 1980 levels. o Uses a refunded emissions payment (REP) for industrial boilers producing 25 GWh/yr Tax of 40 SEK/kg ($4,000/ton) NOX Rate based on engineering estimates of abatement costs, which ranged from 3 to 84 SEK/ton. Covers approximately 250 plants with 365 boilers o What happens to revenues? After administrative costs, remainder of charge is returned to plants Returned in proportion to output of useful energy Thus, if cleaner than average, can get back more than pay in Note that this can avoid one political drawback of fees, in that firms avoid needing to pay twice (for what they abate and for what they emit). The cost is that the government can not use the revenue for other purposes. However, the tax would be unlikely to pass without it. o Monitoring and compliance Units self-report annual emissions, using real-time monitoring Main costs to firms were for monitoring and abatement Average abatement costs between 12-25 SEK/kg Monitoring costs about 2-3 SEK/kg (about $250/ton) Note this is greater than the charge itself in France, suggesting that real-time monitoring would not make sense there. For about of firms, there was a net loss after refund. For another , a net gain after refund. Administrative costs at plant about 1.2 SEK/kg Low administrative costs for government: just 0.5% of revenues Effect of the tax Emissions target not met until 1998 The problem was mobile sources, where emissions only fell by 13% Stationary sources, covered by the tax, fell by more than 50% Comparison of plants across countries US EPA compared similar plants (coal-fired plants with selective catalytic reduction, or SCR) in different countries. Swedish plants have half the emission rates of plants elsewhere In fact, emission rates are below the Swedish standard Note that the emissions charge gives plants incentives to do better than the standard. Differences across industries Figure 5-2 shows that some industries gained, while other lost Pulp & paper hurt the most, while energy gained the most o o o France o o o o o o o Introduction of tax closely linked to European Community policy on acid rain. Applies to all units with 20 MW power capacity Higher threshold than the Swedish program Tax has consistently been lower than Sweden: 1990: 150 FF/ton NOX ($23/ton) 1995: 180 FF/ton NOX 1998: 250 FF/ton NOX ($38/ton) What happens to revenues? Pays for subsidies for abatement measures Compliance No fine for failure to pay Government said not needed, because there was 97% compliance Emissions data self-reported, but easily checked against fuel consumption data Administrative costs 6% of total tax revenue Effect of the tax Government reports emission reduced by 27,000 tons Subsidies for new abatement technologies less effective Many just accelerated what would have happened anyway Because of low tax rate, French policy is similar to a command and control policy Firms need to comply with national standards, but there is little incentive for continual improvement Note that average abatement costs in Sweden about 1/3 to 1/2 of charge, or $1,333 - $2,000/ton. Clearly, the French charge does not induce additional abatement at such costs. IV. Greening the Tax Code Note that taxes can not only correct externalities, but can also provide incentives that exacerbate problems. Often these come from tax expenditures (e.g. deductions). Hanson and Sandalow provide examples. o Percent depletion allowance Oil and gas producers can deduct a fixed percentage of gross income each year. This was established in 19090 to stimulate domestic production. Is it still needed? Repealing would save $900 million over five years. o Similarly, oil and gas companies can treat exploration and development as an expense, rather than depreciating over a number of years. Repealing would save $17 billion over five years. Encourages greater extraction of virgin materials, discourages recycling. o Sport utility vehicle deduction Businesses can deduct $25,000 of purchase of large vehicles (> 6,000 lbs) in the first year. No expensing allowed for light vehicles. Originally intended for large equipment (e.g. construction) Repealing would save $700 million over five years. Hanson and Sandalow also propose new green taxes. How would these work? o Water pollution tax Tax BOD in discharges from industry and wastewater treatment plants. Already monitor BOD, so administrative costs would be low. o Nitrogen fertilizer tax Tax fertilizer that leas to nutrient overload and dead zones in water. Currently, as much as 20% of fertilizer applied ends up in waterways. Tax would encourage more efficient use. o Carbon tax Tax fuels based on their carbon content. Encourages use of cleaner fuels (e.g. natural gas vs. coal).
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Rutgers - ECON - 332
. Permits: Implementation Issues Initial allocation of permitso To begin a permit trading system, firms need to have permits to trade. The initialdistribution can be done in several ways. The government can auction permits to highest bidder. At least
Rutgers - ECON - 332
I. Sulfur Dioxide (SO2) Permits and the 1990 Clean Air Act Background:o Acid rain is caused mainly by sulfur dioxide (SO2) and nitrogen oxides (NOx).o Comes from burning of fossil fuels.o Impact of acid rain: Kills aquatic life (e.g. dead lakes and p
Rutgers - ECON - 332
I.The Role of Uncertainty: Theory (continued)Using the results we covered Monday, we began class deriving rules for the desiredpolicy based on the slope of the marginal damage function (MDF):o When MDF is steeper, mistakes with quantity are more costl
Rutgers - ECON - 332
I. What is Voluntary Compliance?Policy makers and environmentalists have paid increasing attention to voluntaryenvironmental programs, in which firms improve environmental performance beyond what isrequired by regulation.Key questions include:oWhy d
Rutgers - ECON - 332
.Federalism and Environmental Protection: Theory There are three key theoretical questions:1. Choosing the extent of environmental control2. Deciding on the methods of pollution control to use3. Determining and funding the basic research agenda for a
Rutgers - ECON - 332
I. What is Environmental Economics? Economics is the study of the allocation of scarce resources.o Note that the theories of economics can be applied to any scarce resource, not justtraditional commodities.o Economics is not simply about profits or mo
Rutgers - ECON - 332
I. The Invisible Hand The goal of today's lecture is to discuss why the free market may fail, and to discuss theconsequences when that happens. To begin, we must consider how the market should function. Adam Smith, who coined the phrase &quot;The Invisible
Rutgers - ECON - 421
1. You are forecasting future commodity prices, like gold and silver prices. Describe a goodmethod to check the accuracy of your forecast.2. What is autocorrelation in terms of a linear regression model?How can you detect an AR(1) process?How do you c
Rutgers - ECON - 421
Lecture Notes 21. Review of MatricesThe ability to manipulate matrices is critical in economics.1. Matrix a rectangular array of numbers, parameters, or variablesplaced in rows and columns.Matrices are associated with linear equations.Elements aij d
Rutgers - ECON - 421
Lecture Notes 31. Types of economic variables(i) Continuous variable takes on a continuum in the sample space,such as all points on a line or all real numbersExample: GDP, Pollution concentration, etc.(ii) Discrete variables finite number of elements
Rutgers - ECON - 421
Lecture Notes 41. Confidence IntervalsPoint estimate is a single number, like To calculate a confidence interval, we start with the following equation:j j t Pr tc 1 cstd .error jwhere Pr denotes probabilitytc the critical value from the t-dist
Rutgers - ECON - 421
Lecture Notes 51. Goodness-of-FitThe goodness-of-fit measure is, R2.R2 1SSESSTIf R2 = 0, then no fitIf R2 = 1, then a perfect linear fitAlso, n = k which is algebraic systemProblem As the number of x variables increases, R2 always getslargerAdj
Rutgers - ECON - 421
Lecture Notes 61. Autocorrelation (or Serial Correlation)1. DefinitionA problem usually for time series dataThe error terms, ut, are supposed to be randomHowever, they are related by timeThe error terms are correlatedUsing the covariance term, then
Rutgers - ECON - 421
Lecture Notes 81. Trend Forecasting (or Trend Extrapolation)1. PolynomialsYt 1 2 t 32 t 2 u tYt is the series you want to forecastt is the trend variableStart t =1ut is the noise termNote then you use adjusted R2, AIC, or SIC to choose the bestmo
Rutgers - ECON - 421
Lecture Notes 91. Time Series Analysis1. Examine data collected over time.Models are simpleNo independent variables, i.e. no xsModels are mechanicalTime series is both(i)Data(ii)A processObservations are related to each other over time, i.e. co
Rutgers - ECON - 421
Lecture Notes 101. Stationary f ancy word1. Stationary time series does not depend on time.Does not vary with timeWeakly stationary the mean and variance of a time series doesnot vary with timeExamplesI means integrativeIntegration is the branch o
Rutgers - ECON - 421
Lecture Notes 11. Economic Forecasting1. Forecasting the process of estimating or predicting unknownsituationsExample usually economists predict future economic variablesForecasting applies to a variety of data(1) time series data predicting future
Rutgers - ECON - 421
1. What is an unbiased estimator?How do econometricians measure an estimator's bias?What do econometricians mean by efficiency?What does Mean Squared Error do for us?2. What are time-series, cross-sectional, and panel data?Does the type of data matte
Rutgers - ECON - 406
(Lecture 1)Game Theory is a misnomer for Multiperson Decision Theory, analyzing the decisionmakingprocess when there are more than one decision-makers where each agents payoffpossibly depends on the actions taken by the other agents. Since an agents pr
Rutgers - ECON - 406
1 The basic theory of choiceWe consider a set X of alternatives. Alternatives are mutually exclusive in the sensethat one cannot choose two distinct alternatives at the same time. We also take the setof feasible alternatives exhaustive so that a player
Rutgers - ECON - 406
We will formally define the games and some solution concepts, such as Nash Equilibrium,and discuss the assumptions behind these solution concepts.In order to analyze a game, we need to know who the players are, which actions are available to them, ho
Rutgers - ECON - 406
Howtoplay?We will now describe the most common solution concepts for normal-form games. Wewill first describe the concept of dominant strategy equilibrium, which is implied bythe rationality of the players. We then discuss rationalizability which corre
Rutgers - ECON - 406
Nash EquilibriumConsider the battle of the sexesMan\Woman opera balletopera 1,4 0,0ballet 0,0 4,1In this game, there is no dominant strategy. But suppose W is playing opera. Then,the best thing M can do is to play opera, too. Thus opera is a best-re
Rutgers - ECON - 406
What are the implications of rationality and players knowledge of payoffs? Whatcan we infer more if we also assume that players know that the other players are rational?What is the limit of predictive power we obtain as we make more and more assumptions
Rutgers - ECON - 406
Many relationships can be taken as a partnership in which two partners provide an inputtowards an outcome that they will share. For example, in a firm, the employer and theworker provide capital, know-how, and effort to produce a good that will generate
Rutgers - ECON - 406
Backwards inductionThe concept of backwards induction corresponds to the assumption that it is commonknowledge that each player will act rationally at each node where he moves even ifhis rationality would imply that such a node will not be reached.1 Me
Rutgers - ECON - 406
ExampleIn order to see the basic idea, consider the following game.S 0,0 1,3B 3,1 0,0BS1Out In(2,2)In this game, player 1 has option of staying out and getting the payoff of 2, ratherthan playing the battle of sexes game with player 2. Now the ba
Rutgers - ECON - 406
Repeated GamesIn these notes, well discuss the repeated games, the games where a particular smaller game isrepeated; the small game is called the stage game. The stage game is repeated regardless ofwhat has been played in the previous games. For our an
Rutgers - ECON - 406
Static Games with Incomplete InformationAn incomplete information game is a game where a party knows something that some otherparty does not know. For instance, a player may not know another players utility function,while the player himself knows his u
Rutgers - ECON - 406
Dynamic Games with Incomplete InformationIn these lectures, we analyze the issues arise in a dynamics context in the presence ofincomplete information, such as how agents should interpret the actions the other partiestake. We define perfect Bayesian Na
Rutgers - ECON - 406
ReputationConsider a game in which a player i has two types, say A and B. Imagine that if theother players believe that i is of type A, then is equilibrium payoff will be much higherthan his equilibrium payoff when the other players believe that he is
Rutgers - ECON - 406
strategic interactions, a party often knows something that is relevant to the problembut is not known by some other party. In that case, we say that players have asymmetricinformation. When you are interacting with parties that have private information,
Rutgers - ECON - 395
I. Externalities: The conventional analysisA. The simple argument for efficiency:ooooB. The problem:oooooooo1. The EPA or equivalent decides who can pollute how much where, whatmethods of pollution reduction have to be used, etc.2. The p
Rutgers - ECON - 395
I. Insurance: why it is interesting:o A. Because one recurring legal issue is who will bear the costs ifsomething goes wrong-i.e. who is insuring whom. For example:1. Contracts. Something changes, so either I don't want to produce what Iagreed to or
Rutgers - ECON - 395
I. Strategic behavior:o A. Bilateral monopoly.o1. Economic example: I have the only apple, worth $1 to me. You are theonly customer, and value it at $2. If we can agree on a price, there is a netgain of $1 to be divided between us, with the division
Rutgers - ECON - 395
I: What is property?o A. we take the institution for granted-for familiar thingso B. But it is a specific kind of rule and concept, as you can see byapplying it in less familiar contexts. My obligations to you are good onlyagainst me, but your owners
Rutgers - ECON - 395
Digression on simplified pictures.o A. In thinking through the logic of a problem, whether in physics,mathematics, or economics, we frequently use simplified pictures,designed to bring out the particular issue we are interested in.o B. For example, w
Rutgers - ECON - 395
If we do want to enforce the contract, how do you fill in the details?o A. By what would be efficient, eitheroB. Who should bear risks? We've been here beforeo1. Because we want efficient law, or2. Because that predicts what they would have agreed
Rutgers - ECON - 395
It is often claimed that, when I have a child, I impose net costs on others,so that leaving people free to decide how many children they have willresult in overpopulation.o A. But it is not clear what the sign of the net externalities from myhaving a
Rutgers - ECON - 395
Summary of implications:A. Assume one dimension (care) is observable by the court, another (activitylevel) is unobservable.oo1. Note that &quot;care&quot; and &quot;activity level&quot; are merely convenient examples.2. The real categories are &quot;activities with regard
Rutgers - ECON - 395
Criminal Law: A. Like tort law, someone does a wrong, we impose a cost on him, but .oooooB. Note that the Tort/Crime distinction may be less clear than we usually think.ooooooo1. Optimal level of some offenses is close to zero2. Most obvio
Rutgers - ECON - 395
Why benefits to criminals count:A. The lost hunter problem.oooB. Even if you want to deter it, how much do you want to deter it?ooooo1. If a hunter is lost and starving and comes to a locked, empty cabin containingfood and a telephone, it is
Rutgers - ECON - 395
I. Antitrust Lawo A. Monopoly produces an inefficient outcomeoB. One approach to eliminating the inefficient outcome is to preventmonopolies from existing.o1. Not workable for a real natural monopoly.2. But perhaps for preventing monopoly-by-merge
Rutgers - ECON - 395
Summary before First MidtermI. What is economics, what does it have to do with law?II. What is economic efficiency (aka &quot;wealth maximization&quot;)?o A. Important to L&amp;E for two reasons:oB. Judging rules, outcomes by the summed effect on everyone, whereo
Rutgers - ECON - 395
Review before the Second Midterm I: Determining property rules involves a set of questions:A. How rights should be bundled (Coase article, our earlier discussion)B. How should you be allowed to defend your property rights (property vsliability)C. Wh
UCSD - CHEM - 140A
Structure and Bonding in Organic MoleculesChapter 1Sections: Preface, 0-9Exercises: 1a, 2, 3, 4, 5, 6, 7, 8, 9, 13, 14, 15, 16, 17, 18Problems: 19, 20, 21, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 37, 38, 39, 41, 42, 44,47, 48, 49, 50Mode
UCSD - CHEM - 140A
Structure and ReactivityChapter 2Sections: 0, 1, 2, Table 2, 3, Table 3, 4, Table 5, Table 6, [Nomenclature: Besure that you can draw the correct structure from a molecule's name. For 140Ayou need not learn how to provide the correct name from a struc
UCSD - CHEM - 140A
Reactions of AlkanesUnderstanding the basic reactivity of simple alkanes will allow us to discusssome of the physical properties of organic molecules such as the strength ofbondsThis allows us to predict something about the products one might expectf
UCSD - CHEM - 140A
1Chapter 4 - CycloalkanesNames follow the same set of rules as linear alkanes. Alkane names aresimply preceded by the word: CYCLO.General formula is CnH2n.Stereoisomers same connectivity but different spatial arrangementRing Strain and torsional str
UCSD - CHEM - 140A
Chapter 5 - Stereochemistry1Non-superimposable mirror imagesLeft and right hands are mirror images of each other. Molecules can berelated to each other in the same manner. They are chiral molecules, calledenantiomers.2Methane as an introduction to
UCSD - CHEM - 140A
Chapter 6WhenNucleophilesA/ackC-X Bond Strength and X SizeP orbital from the halogen overlaps with the sp3 orbital on the carbon centerThe larger and more diffuse the p orbital in question, the weaker the bondbecause the poorer the overlap.C-X Bon
UCSD - CHEM - 140A
Chapter 7 Further Reactions of HaloalkanesJust when you thought it was over1SolvolysisWe learned that SN2 reaction rates diminish going from primary tosecondary to tertiary carbons at the reacting center.These kinds of carbons do undergo reactions b
UCSD - CHEM - 140A
Chapter 8 AlcoholsEthanol is the alcohol contained in alcoholic beverages like this one being enjoyedby a small child. Whilst there is no accounting for poor parenting, there is accountingfor great wine like the one made in these old school basket pres
UCSD - CHEM - 140A
Final Examination: Chem 140AImportant InformationThe Final Examination will be held next week - Either Monday or Fridaydepending on the class.The exam will cover all the material from lectures, problem sets, chapters,midterm questions (including Bonu
UCSD - CHEM - 140A
Organic Chemistry 140A Winter, 2012Professor Nathan C. Gianneschingianneschi@ucsd.edu - Contact by WebCTPacific Hall 6224AOffice Hours: Monday 4-5pm, Pacific Hall 6224A.Wednesday, 3-4pm, HSS 1128AFriday, 3-4pm, HSS 1128AMary Noe A01, A02, A03, mnoe
UCSD - CHEM - 140A
Chapter 1 Practice P roblems Answer KeyChallenge Problem #4:a. A structure with a positive charge on a carbon immediately adjacent to an alkene is termed anallylic carbocation. Shifting the electrons gives us the only other reasonable resonance structu
UCSD - CHEM - 140A
Chapter 2 Discussion Section Problems Key1.2.3. .a. So is positive; one molecule became two smaller molecules that have greater freedom in motionb. So is negative; two small molecules produced a single molecule that has less freedom of motionc. So c
UCSD - CHEM - 140A
Chapter2DiscussionSectionProblemsThermodynamicsProblems1. The following reaction has a value of Go = -2.1 kJ/mol (-0.5kCal/mol)CH3Br + H2S CH3SH + HBra. Calculate the Keq value at T=25C for the reactionb. Starting with a 1M solution of CH3Br and H2S
UCSD - CHEM - 140A
Chapter3:ReactionsofAlkanesDiscussionSectionProblems1. Rank the following radicals in decreasing order of stability2. For each of the following alkanes:a. Draw all the possible monochlorinated derivatives.b. Determine whether free radical chlorination
UCSD - CHEM - 140A
Chapter4:CycloalkanesDiscussionSectionProblems1. Draw the two chair conformations of cis-1,3-dimethylcyclohexane and label allthe positions as axial or equatorial.a. Label the higher energy and lower energy conformationb. The energy difference between
UCSD - CHEM - 140A
Chapter 5 Problem Set Answer Key1.2. 3. Your drawings may look different from this. Check by assigning R and S.4.a.b.c.d.5.a.6.a.7.sameenantiomersenantiomersenantiomersi.j.e.f.g.h.enantiomersdiastereomersenantiomerssame compound