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Chp 6 Organic Chemistry I

Course: CHEM 2311, Spring 2012
School: Georgia Tech
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Name Last _____________________ First Name _________________Roster # _____ No/incorrect roster number No grade Chemistry 2311 Homework Problems- Chapter 6 Use MSWord and/or ChemBioDraw softwares to answer all questions except where indicated. For structures select and then copy the red rectangle for the question and paste it into the ChemBioDraw window. Draw the requested structures and then copy the rectangle and...

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Name Last _____________________ First Name _________________Roster # _____ No/incorrect roster number No grade Chemistry 2311 Homework Problems- Chapter 6 Use MSWord and/or ChemBioDraw softwares to answer all questions except where indicated. For structures select and then copy the red rectangle for the question and paste it into the ChemBioDraw window. Draw the requested structures and then copy the rectangle and its contents in ChemBioDraw and paste them back into MS Word. Answer sheet to be printed out, one side of page only front (only side of pages will be graded). You may collaborate on the development of strategies to answer to these problems. HOWEVER, all work using must be completed independently of others. You cannot exchange electronic files with other students or cut-and-paste from other students. Violators of this instruction will receive a zero for the assignment and be referred to the Dean of Students for further sanction. 1. d 2. a 3. d 4. b 5. b 6. c 7. c 8. c 9. c 11. (a) (b) (c) (d) 10. a (e) (f) (g) (h) (i) (j) SN2
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Georgia Tech - CHEM - 2311
Last Name _ First Name _Roster # _No/incorrect roster numberChemistry 2311 Homework Problems- Chapter 7No gradeUse ChemBioDraw software to draw the requested structures within the red rectangles provided.Select and then copy the red rectangle for the
Georgia Tech - CHEM - 2311
Last Name _ First Name _Roster # _No/incorrect roster numberChemistry 2311 Homework Problems- Chapter 8No gradeUse ChemBioDraw software to draw the requested structures within the red rectangles provided.Select and then copy the red rectangle for the
Georgia Tech - CHEM - 2311
Last Name _ First Name _Roster # _No/incorrect roster numberChemistry 2311 Homework Problems- Chapter 9No gradeUse ChemBioDraw software to draw the requested structures within the red rectangles provided.Select and then copy the red rectangle for the
Georgia Tech - CHEM - 2311
Structure solutionThe electron density distribution in a solid andhence it structure can be determined by Fouriersynthesis if the the values of a large number ofFhkl are known but only |Fhkl| are obtained from measured intensities the phases are unk
Georgia Tech - CHEM - 2311
Interpreting atomic coordinatesA crystal structure refinement leads toestimates of model parametersAtomic connectivity coordinates, temperature factors andoccupanciesWhat matters chemically is atomicconnectivity (bonding) and packingNeed interatom
Georgia Tech - CHEM - 2311
Form factors - the FT of atomic rPerfect and ideally imperfect crystalsMost real crystals are not perfectly ordered they are made up of blocks displaced relative toone another angular displacement is the mosaic spreadFor perfect crystals I a |F|For
Georgia Tech - CHEM - 2311
Polar materialsMany solids have a polar axis LiNbO3, ZnS etc.Chiral materialsChiral solids can arise in a number ofdifferent ways optically pure chiral molecules will crystallizeto give a chiral solid racemic chiral molecules may crystallize asch
Georgia Tech - CHEM - 2311
Chem. 1310 Spring 2008Exam 3 VERSION AProfessors Williams/WhettenName _ Section Number _ This test is closed note/book One 8.5 x 11 handwritten crib sheet (one sided) is permitted. Please turn off your cell phone. Use a #2 pencil. Calculators are permi
Georgia Tech - CHEM - 2311
INTA 2030 Fall 2010Final Exam(1) Write your name on this sheet.(2) Write your name on the Scantron sheet.(3) Hand in this sheet AND your Scantron sheet. Good Luck!Part I: Select the best answer for each of the following questions. Each question is wo
Georgia Tech - CHEM - 2311
STUDENT NOTES: Exp 2. Molecules, Moles, & Chemical ReactionsBottomley&BottomleyChemistry 1310 2010-2011 Lab Manual; Hayden-McNeilPOST-LAB ASSIGNMENT: Lab Report Due next lab. Students Notes will be on T-squareCover Sheet: Title, Name, Lab Partners name
Georgia Tech - CHEM - 2311
DiscussionThe first part of the experiment was done in order to accuratelycalculate H in part B of the experiment. A calorimeter was preparedusing a Styrofoam cup and lid with 50 ml of cold water. Thetemperature of the water was taken when constant. T
Georgia Tech - CHEM - 2311
Chapter 10Entropy and the Second Law ofThermodynamicsChapter 10 Brown and Holme 2e10.1 INSIGHT INTO Recycling of Plastics10.2 Spontaneity10.3 Entropy10.4 The Second Law of Thermodynamics10.5 The Third Law of Thermodynamics10.6 Gibbs Free Energy1
Georgia Tech - CHEM - 2311
Ab initio structure solution frompowder diffraction dataAngus P. WilkinsonSchool of Chemistry and BiochemistryGeorgia Institute of TechnologyOutlineThe problemGeneral procedureInstrument selectionAn example - Ga2(HPO3)3.4H2ORecent developmentsH
Georgia Tech - CHEM - 2311
INTA 2030 Fall 2010Quiz(1) Write your name on your Scantron answer sheet.(2) Write your name on this sheet.(3) Hand in this sheet AND your answer sheet. Good Luck!Section I: Select the best answer for each of the following questions. Each question is
Georgia Tech - CHEM - 2311
Molecular Orbital TheoryIn principle, the electronic structure ofmolecules can be worked out in the same wayas for atoms: solve the Schrdinger equationThis gives molecular orbitals rather than atomicorbitalsBut: It is difficult to solve the Schrdin
Georgia Tech - CS - 1371
Georgia Institute of TechnologyCS1371 Fall 2009 - Exam 1 Question BankOn T-Square, under Assignments, you will find feedback for "CS1371 Fall 2009 - Exam 1." Thefeedback file contains the Question ID numbers of the random questions you were given, the
Georgia Tech - CS - 1371
CS1371 Computing for Engineers Test 1 Version E1February 4, 20091Georgia Institute of TechnologyCollege of ComputingCS 1371 Computing for EngineersTest 1 Version E - Spring Semester 20090123456789ABCDEFGHIJKLMNOPQRSTUV
Georgia Tech - CS - 1371
CS1371 - Computing for Engineers - Test 2 Version MOctober 24th, 20071Georgia Institute of Technology College of Computing CS 1371 Computing for Engineers Test 2 Version M - Fall Semester 20070 1 2 3 4 5 6 7 8 9 A B C D E F G H I J K L M N O P Q R S T
Georgia Tech - CS - 1371
CS 1371 Spring 2008 Practice Test 2Part 1 Multiple Choice [30 Points]1. Which of the following should NEVER be used within a recursive function? I. Terminating Condition II. Calling a clone of the function III. Iteration IV. Infinite Loop V. Matrix Mani
Georgia Tech - MATH - 3770
Fall 04Math 3770Name:FinalBonettoPage 1 of 91) Let X1 and X2 two discrete random variables with a joint p.m.f given by:p(1, 0) = p(1, 0) = p(0, 1) = p(0, 1) = 0.25while p(x1 , x2 ) = 0 in all other cases. Compute:a) the marginal p.m.f. pX1 (x1 )
Georgia Tech - MATH - 3770
Spring 06Math 3770Name:FinalBonettoPage 1 of 81) Let X1 and X2 be two discrete random variables with a joint p.m.f given by:p(1, 0) = p(1, 0) = p(0, 1) = p(0, 1) = 0.1p(0, 0) = 0.6while p(x1 , x2 ) = 0 in all other cases. Compute:a) the marginal
Georgia Tech - MATH - 3770
TA TB AB TS TS P (TS > t) TS TS > t TA > t TB > t P (TA > t) = et P (TS > t) = P (TA > t)P (TB > t) 2t3t P (TB > t) = e P (TS > t) = e
Georgia Tech - MATH - 3770
Fall 04Math 3770Name:Test 1BonettoPage 1 of 41) The following number represent a sample of size n = 19 form a given population.0.985 0.645 0.118 0.894 0.784 0.1010.253 0.321 1.832 0.378 0.679 0.6810.753 0.006 0.624 1.104 0.273 0.126 0.618a) Comp
Georgia Tech - MATH - 3770
Spring 07Math 3770Name:Test 1BonettoPage 1 of 51) The following numbers xi , i = 1, . . . , 18, represent a sample of size n = 18 from agiven population.2.1389 2.8132 2.4451 2.4660 2.6038 2.41863.8592 2.1988 2.3529 2.2028 2.7468 1.51042.1987 2.5
Georgia Tech - MATH - 3770
MATH 3770Test 1February 16, 2009No books or notes allowed. No laptop or wireless devices allowed. Write clearly.Name:Question:1234TotalPoints:32362210100Score:MATH 3770Test 1February 16, 2009Question 1 . . . . . . . . . . . . . . . .
Georgia Tech - MATH - 3770
MATH 3770Test 1September 23, 2010No books or notes allowed. No laptop or wireless devices allowed. Write clearly.Name:Question:1234TotalPoints:30302030110Score:MATH 3770Test 1September 23, 2010Question 1 . . . . . . . . . . . . . . .
Georgia Tech - MATH - 3770
Fall 04Math 3770Name:Test 2BonettoPage 1 of 41) In a bowl there are 3 balls numbered form 1 to 3. You extract two of them withoutreinsertion. Let X1 the result of the rst extraction and X2 the result of the secondone. Compute:a) the joint probabi
Georgia Tech - MATH - 3770
MATH 3770Test 2November 12, 2010No books or notes allowed. No laptop or wireless devices allowed. Write clearly.Name:Question:123TotalPoints:404030110Score:MATH 3770Test 2November 12, 2010Question 1 . . . . . . . . . . . . . . . . . . .
Georgia Tech - MATH - 3770
MATH 3770Test 2March 16, 2010No books or notes allowed. No laptop or wireless devices allowed. Write clearly.Name:Question:123456TotalPoints:202030101010100Score:MATH 3770Test 2March 16, 2010Question 1 . . . . . . . . . . . . . .
Georgia Tech - PHYS - 2022
PROBLEM SET 1Physics 20221. The age of the universe is about 14 billion years. What is this age in seconds? Use powersof-ten notation. 2. At what distance would a person have to hold a European 2-euro coin (which has a diameter of about 2.6 cm) in order
Georgia Tech - PHYS - 2022
PROBLEM SET 2Physics 20221. When the Voyager 2 spacecraft sent back pictures of Neptune during its flyby of the planet in1989, the spacecrafts radio signals traveled for 4 hours at the speed of light to reach Earth. Howfar away was the spacecraft? Giv
Georgia Tech - PHYS - 2022
PROBLEM SET 3Physics 20221. What is the magnification of a telescope that has an objective with twice the focal length of its eyepiece? 2. The observing cage in which an astronomer sits at the prime focus of the 5-m telescope on Palomar Mountain is abou
Georgia Tech - PHYS - 2022
PROBLEM SET 4Physics 20221. The average distance from the Earth to the Sun is 1.496 x 108 km. Express this distance in light-years. Use powers-of-ten notation. Are light-years useful units for describing distances of this size? Explain. 2. Find the aver
Georgia Tech - PHYS - 2022
PROBLEM SET 5Physics 20221. What temperature and spectral classification would you give to a star with equal line strengths of hydrogen (H) and neutral helium (He I)? Explain. 2. The bright star Rigel in the constellation Orion has a surface temperature
Georgia Tech - PHYS - 2022
PROBLEM SET 6Physics 20221. At one stage during its birth, the protosun had a luminosity of 1000 L and a surface temperature of about 1000 K. What was its radius then compared to today's? 2. Use the Sun's luminosity (3.84 x 1026 W) to calculate the mass
Georgia Tech - PHYS - 2022
PROBLEM SET 7Physics 20221. The central star in a newly formed planetary nebula has a luminosity of 1000 L and a surfacetemperature of 100,000 K. What is the stars radius? Give your answer as a multiple of theSuns radius.2. The Ring Nebula in the con
Georgia Tech - PHYS - 2022
PROBLEM SET 8Physics 20221. The distance to the Crab Nebula is about 2000 parsecs. It was observed as a supernova inAD 1054. In what year did the star actually explode? Explain your answer.2. Emission lines in the spectrum of the Crab Nebula exhibit a
Georgia Tech - PHYS - 2022
PROBLEM SET 9Physics 20221. An RR Lyrae star whose peak luminosity is 88 L is in a globular cluster. At its peakluminosity, this stars apparent magnitude is +14.3. Determine the distance to this globularcluster in parsecs.2. Calculate the energy (in
Georgia Tech - PHYS - 2022
PROBLEM SET 10Physics 20221. Suppose you discover a Type Ia supernova in a distant galaxy. At maximum brilliance, thesupernova reaches an apparent magnitude of +10. How far away is the galaxy (in Mpc)?2. The average radial velocity of galaxies in the
Georgia Tech - PHYS - 2022
SOLUTION SET 1Physics 20221. t = 14 x 109 years x 365.25 days/year x 24 hr/day x 60 min/hr x 60 sec/min = 4.42 x 1017 seconds 2. a) b) c) 3. a) b) 4. D = d tan D = d tan D = d tan d = 0.026/2 m / tan (0.5 deg) = 1.5 m d = 0.026/2 m / tan (0.5 deg / 60)
Georgia Tech - PHYS - 2022
SOLUTION SET 2Physics 20221.d = c t = (3 x 105 km/s) (4 hr) (3600 s/hr) = 4.3 x 109 km2.c = ff = c / = (3 x 108 m/s) / (0.4 m) = 7.5 x 108 Hz3.c = f = c / f = (3 x 108 m/s) / (3 x 1016 /s) = 1 x 10-8 m = 10 nm4.RadioFs 1 / ds2X-rayFe 1 / de2
Georgia Tech - PHYS - 2022
SOLUTION SET 3Physics 20221. F =2f M = F/f = 2f / f = 22.Fraction = Area (cage) / Area (mirror) = R2 (cage) / R2 (mirror) = (1 / 5)2 = 1 / 25 = 0.04 LGA Area LGA(1) (300 m)2 LGA(2) (50 m)23.LGA(1) / LGA(2) = (300 / 50)2 = (6)2 = 36 times LGA(1) / LG
Georgia Tech - PHYS - 2022
SOLUTION SET 4Physics 20221. d = 1.496 x 108 km / 9.46 x 1012 km/ly = 1.58 x 10-5 ly No - too small 2. dpluto = 39.5 AU / 206,265 AU/pc = 1.92 x 10-4 pc dprox_c / dpluto = 1.30 / (1.92 x 10-4) = 6790 3a. 3b. 4. 5a. 5b. 5c. 6a. 6b. d = (2 x 106 AU) / (20
Georgia Tech - PHYS - 2022
SOLUTION SET 5Physics 20221. 2. The two curves cross at about 20,000 K, which is about at the B3-B4 spectral type. Lrigel = 1.6 Tsun Lrigel = 64,000 LsunLrigel / Lsun = (Rrigel / Rsun)2 (Trigel / Tsun)4 (64,000) = (Rrigel / Rsun)2 (1.6)4 Rrigel = 98.8
Georgia Tech - PHYS - 2022
SOLUTION SET 6Physics 20221.L* = 1000 LsunT* = 1000 KTsun = 5800 KL* / Lsun = (R* / Rsun)2 (T* / Tsun)41000 = (R* / Rsun)2 (1000 / 5800)4R* = 1064 Rsun2.Lsun = 3.85 x 1026 J/s= 7.4 x 108 km= 4.9 AU1 reaction of H to He releases 26.7 MeVNumbe
Georgia Tech - PHYS - 2022
SOLUTION SET 7Physics 20221.L* = 1000 LsunT* = 100,000 KTsun = 5800 KL* / Lsun = (R* / Rsun)2 (T* / Tsun)41000 = (R* / Rsun)2 (100,000 / 5800)4(R* / Rsun)2 = 1.13 x 10-2R* = 0.11 Rsun2.v = 20 km/sd = 2,700 LY = 1.2 arcmin = 72 arcsecd = 2,70
Georgia Tech - PHYS - 2022
SOLUTION SET 8Physics 2022 Spring 20081. Convert parsecs to light years d = 2000 pc x 3.26 ly/pc = 6520 ly The supernova was observed in AD 1054. The light began its journey 6520 years before, so the explosion happened in AD 1054 6520 = 5466 BC time = 2
Georgia Tech - PHYS - 2022
SOLUTION SET 9Physics 20221.m = +14.3L* / Lsun = 88Msun = +5.0Msun M* = 2.5 log ( L* / Lsun ) = 2.5 log ( 88 ) = 4.86M* = 5.0 4.86 = 0.14 magm M = 5 log ( d / 10 ) = 14.3 0.14 = 14.16D = [ dex ( 14.16 / 5 ) ] ( 10 ) 6800 pc2.E = h c / = (6.63 x
Georgia Tech - PHYS - 2022
Georgia Tech - PHYS - 2022
Georgia Tech - PHYS - 2022
Black HolesTheories of RelativityEinsteins Special Theory of Relativity was a comprehensivedescription of the behavior of light and, by extension, ofelectricity and magnetism. It is called Special because it dealswith the special case of constant vel
Georgia Tech - PHYS - 2022
Georgia Tech - PHYS - 2022
Georgia Tech - PHYS - 2022
GalaxiesFirst ObservationsTo the naked eye and even through a small telescope, galaxies appear asdiffuse objects. They were originally thought to be another type of nebulae.Earl of RosseThe first person to have had a largeenough telescope to study t
Georgia Tech - PHYS - 2022
Clustering of GalaxiesThe Local GroupThe Milky Way is a member of a small group of galaxies called the LocalGroup. It is spread over about a million parsecs and contains at least 26members. There are 3 large spiral galaxies (our own, the AndromedaGal
Georgia Tech - PHYS - 2022
Life of a High-Mass StarsEvolutionary TracksPaths of high-mass stars on the HRDiagram are different from those oflow-mass stars.Once these stars leave the mainsequence, they quickly grow insize to the supergiant regime(~100 R).These extended star
Georgia Tech - PHYS - 2022
Georgia Tech - PHYS - 2022
Georgia Tech - PHYS - 2022
Georgia Tech - PHYS - 2022
Georgia Tech - PHYS - 2022
The Milky WayThe Milky WayThe Milky Way is a continuous band of diffuse light. The band is thickerand brighter in one part of the sky and 180o away it is thinner and fainter.The band is tilted about 60o with respect to the Celestial Equator.Telescopi