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Course: BENG 130, Winter 2012
School: UCSD
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16.16 1. 2. 3. 4. Problem Problem 16.19 16.21 Problem Problem 16.43

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16.16 1. 2. 3. 4. Problem Problem 16.19 16.21 Problem Problem 16.43
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UCSD - BENG - 130
1. How many intensive variables (or state functions) are sufficient to specify thestate of each of these systems in addition to one extensive variable per phase.Identify for each systems which function is extensive and intensive in youranswer (a) one m
UCSD - BENG - 130
1. Calculate the standard molar enthalpy of formation of acetylene (C2H2) from itselements: (10 points)The equations for the combustion and the corresponding enthalpy changesare:(i)rH0 = -393.5 kJ/mol(ii)rH0 = -258.5 kJ/mol.rH0 = -2958.5 kJ/mol(i
UCSD - BENG - 130
1.2.3.4.5.Problem 4.2Problem 4.3Problem 4.26Problem 4.31Problem 4.53
UCSD - BENG - 130
HOMEWORK 7 PROBLEMSQuestion 1 [5.8] Write balanced reactions for the combustion of one mole of each of thefollowing to CO2 (g ) and H2 O(l ). (a ) CCl4 (l ); (b ) NH2 CH2 COOH(s ); (c ) H(g ); (d ) N2 (g ).Question 2 [5.23] True or false? (a ) The rate
UCSD - BENG - 130
1.2.3.4.5.Problem 5.8Problem 5.23Problem 5.64Problem 6.1One mole of air at 1 bar and 25 oC is compressed to 5 bar and 25 oC by twodifferent mechanically reversible processes:(a) Cooling at constant pressure followed by heating at constant volum
UCSD - BENG - 130
1.2.3.4.Problem 6.12Problem 6.15Problem 6.48Problem 7.235. Consider the following step of glycolysis:glu cos e glu cos e 6 phosphate(a) At equilibrium the reaction system contains 75.0% glucose-6-phosphate at 370C.Calculate the equilibrium cons
UCSD - BENG - 130
1. In an industrial process, nitrogen is heated to 500K in a vessel of constantvolume. If it enters the vessel at 100 atm and 300K, what pressure would it exertat the working temperature if it behaved as a perfect gas?2. The mass percentage composition
UCSD - BENG - 130
HW 2 Book Problems3) 1.16(a) What is the pressure exerted by 24.0 g of carbon doxde in a 5.00L vessel at 0C?(b) A rough rule of thumb is that one mole of gas occupies 1ft 3 at room temperature andpressure (25C and 1atm). Calculate the percent error in
UCSD - BENG - 130
1. Derive an expression for pressure P at temperature T, in terms of kineticenergy KE, exerted by an ideal gas of N molecules, each having a massm on the wall of a cubic-shaped container having edges of length d andvolume V. State and justify all the a
UCSD - BENG - 130
1. To what extent are the following systems closed, open, or isolated: (a) a seacucumber, (b) a birds egg, (c) a space capsule in orbit, (d) the earth, (f) the solarsystem, (d) the universe2. How many intensive variables (or state functions) are suffic
UCSD - BENG - 130
I PV-nwq+wr,11,SDoi ('-b1t'l alv,v&quot;&amp;a?o'T4#lln'0,7+/.^,., = &quot;, 1&quot;1,m3/y*z t, - t / tLvlV. = A.-|tt0,ofn&quot;-A.?arrcfw_dr*'P=t451,nLoV?^-(n f ; 7vv/|?tl'-&quot;W -f= (y ,(' ffi(r&quot;t@tsbtql./v,^*)'Yh , \,t/u45u?*,6byro3 dl,n,ol[*&quot; .,F r*tld4f
UCSD - BENG - 130
!&quot; #\$%&amp;'(%)* %+)* %)',)-(%.-)* %/* 0+&amp;1+* (* 233* '4* 154&amp;67)-* 1/6%(&amp;6&amp;68* 3&quot;9* 8* +)4&amp;.'* 8(\$:*+(;&amp;68*(*7)6\$&amp;%5*/&lt;*3&quot;33=*8&gt;1'=:*6)7\$*%/*?)*-)@(7A.\$%)7*&amp;6*/-7)-*&lt;/-*%+)*,-)\$.-)*%/*?)*B2=&quot;CD*EF(G**9&quot; H(41.4(%)*%+)*'/4)1.4(-*0)&amp;8+%*/&lt;*(*;/4(%&amp;4)*1/',/.
UCSD - BENG - 130
H o m e w o rk -2 :T h is h o m e w o r k is d u e o n J a n u a r y 2 1 s t T h u r s d a y a t th e b e g in n in g o f le c tu r ea n d n o la te h o m e w o r k s w ill b e a c c e p te d . Y o u r a n s w e r s s h o u ld b eth o r o u g h a n d d
UCSD - BENG - 130
Beng130 HW#3-Solutions1. To what extent are the following systems closed, open, or isolated: (a) a seacucumberopen (b) a birds eggclosed, (c) a space capsule in orbitclosed,(d) the earthopen, (e) the solar systemopen, (f) the universeisolated3 pts (1/
UCSD - BENG - 130
!&quot;#\$%&amp;'()*+&amp;(,-./( -01&quot;2034( ./( 56&quot;( 0#( 78#6839( :;&lt;-( ,-63/589( 8&lt;( &lt;-&quot;( =&quot;\$.#.#\$( 0&gt;( ?&quot;@&lt;63&quot;( 8#5( #0(?8&lt;&quot;( -01&quot;2034/( 2.?( =&quot;( 8@&quot;A&lt;&quot;5B( C063( 8#/2&quot;3/( /-06?5( =&quot;( &lt;-0306\$-( 8#5( 5&quot;&lt;8.?&quot;5B( D&gt;(906( 6/&quot;( 8/61A&lt;.0#/E( &quot;FA?8.#( &lt;-&quot;1( .#( 5&quot;&lt;8.?B( C0
UCSD - BENG - 130
BENG 130 HW #4 Solutions(1) A cylinder enclosed by a piston of negligible mass is sitting on a lab bench at 25C.The cylinder contains 0.15 moles of helium gas, which is initially in thermodynamicequilibrium with its surroundings. The piston is initial
UCSD - BENG - 130
( 1 ) A c y lin d e r e n c lo s e d b y a p is to n o f n e g lig ib le m a s s is s ittin g o n a la b b e n c h a t 2 5 C . T h ec y lin d e r c o n ta in s 0 .1 5 m o le s o f h e liu m g a s , w h ic h is in itia lly in th e r m o d y n a m ic e q u
UCSD - BENG - 130
1.Vi = 50m^3Pi = 20 PaVf = 20m^3R = 8.314 (m^3*Pa/K*mol)a) Find Ti, Tf, Pf (3 points)a. PV=nRT; Ti = 120.28 Kb. PiVi^y = PfVf^y; Pf = 72.13Pa c. PV=nRT; Tf = 177.37 Kb) (3 points)Cv = dU/dT at constant V, integrate from Ui to Uf and Ti to Tf to
UCSD - BENG - 130
1. Consider a reversible, adiabatic volumetric contraction of one mole of ideal diatomicgas. Initially, the gas is at initial volume Vi = 50 m3 and initial pressure Pi = 20 Pa.The gas is then compressed until final volume Vf = 20 m3.a.What is the init
UCSD - BENG - 130
1. Calculate the amount of water that would have to be vaporized at 40 oC to expendthe 2.5 x 106 cal of heat generated by a person in one day?2. Consider a reversible carnot cycle similar to one seen in the class involving amonoatomic ideal gas. The in
UCSD - BENG - 130
1. Calculate !S (for the system) when the state of 2.50 mol of nitrogen gas ischanged from 25 oC and 2.00 atm to 125 oC and 8.00 atm. How do yourationalizes the sign of !S? Assume that the nitrogen gas is an ideal gas.2. The enthalpy of vaporization of
UCSD - BENG - 130
1. (a) Assume the Raults law holds and calculate the boiling point of a 2Msolution of urea in water.(b) Urea actually forms complex in solution in which two or moleculeshydrogen bonds to form dimmers and polymers. How does this affect theboiling point
UCSD - BENG - 130
1. Given: V = 140cm3, P = 1.2*105Pa, T = 27oC, species = He, monatomic gasAssumptions: Ideal GasUnit Conversions: 140cm3 = .140dm3 = 1.40*10-4m3, 27oC = 300Ki. PV = nRTii. 1mol = 6.022*1023particlesiii. Mass of Helium: 4g/molUnit Conversion: 4g/mol
UCSD - BENG - 130
1. Calculate the amount of water that would have to be vaporized at 40oC to expendthe 2.5 x 106 cal of heat generated by a person in one day?32. Consider a reversible carnot cycle similar to one seen in the class involving amonatomic ideal gas. The ini
UCSD - BENG - 130
BENG 130 Winter 2010oHW #8 Solutionsor G = r G + RTlnQ = r G + RTlnr G = 5400JJ+ 8.314molKmol2PN O 2PN 2 O 4298 K ln(0.122 )2= 3.1 kJ/mol0.453Since the overall change in Gibbs free energy is negative, the reaction proceeds from left to r
UCSD - BENG - 130
1. The equilibrium constant (Kp) for the equilibrium reactionN2O4 (g) ! 2NO2 (g)is 0.133 at 298K with a corresponding standard Gibbs energy changeof 5.4 kJ/mol. In a certain experiment, the initial pressure are PNO2 =0.122 bar and PN2O4 = 0.453 bar. C
UCSD - BENG - 130
HW 9 Solutions1. Urea in water, follows Raoults Lawa.Murea = 2MH2O = 1kg/Lmurea = 2kg/LKbH2O = 0.51 C/mTH2O = Kb*mBTH2O = Kb*murea*iTH2O = (0.51 C*kg/m)*(2kg/L)*(1)TH2O = 1.02 C (or K)New TbpH2O = Tbp(pure H2O) + TH2O= 100 C + 1.02 C= 101.2 C
UC Riverside - BUS - 101
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