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super_absorbent_polymers Cincinnati CHEM 652
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  • Title: super_absorbent_polymers
  • Type: Notes
  • School: Cincinnati
  • Course: CHEM 652
  • Term: Winter

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Absorbent Super Polymers Introduction: The super-absorbent material has many applications, for example, it is used in the disposable diapers that can absorb a large amount of water, which helps the baby stay dry for more time. The chemical used in the diapers is mostly sodium polyacrylate; it is also used in soil moist that is a synthetic polyacrylamide with a potassium salt base, it is a safe, non-toxic polymer and can hold over 200 times its weight in water, release it slowly over time in horticultural applications. In the industry, super-absorbent polymers can be used in oil drilling and reducing soil errosion. Purpose: To find out how much water can be absorbed by the super-absorbent materials, such as the materials in diapers and soil moist. And determine which types of water can be absorbed most effectively. Materials: Glass vial, plastic cup, pool water, plain water, salt, food color, colorful sparkle, diapers and soil moist. Procedure: Diaper Rip open a diaper and remove some filler. Put a drop of water on the polypropylene layers (inner and outer). Take 4 cups and put diaper filler in each cup. Weigh each cup. Fill cup with tap water, swimming pool water, ocean water and salt water (10%). Wait a few minutes. Pour out extra water. (Feel materials in cup. Is it dry or wet?) Weight each cup again. Compare these cups. Add salt, does the gel collapse? Soil Moist Add glitter and the proper amount of Soil Moist into a jar. Fill the jar with colored water (not too dark), and mix well. Allow the product to gel. Place the plastic items (seahorses, etc.) on the surface, one at a and time, push into desired position with a stick. Add a little water to fill the jar. Cap the jar, seal with hot glue if desired. Scientific Explanation: ( from www.psrc.usm.edu/macrog/) Sodium polyacryalte is a type of polyelectrolyte. When it is put into water, it just breaks apart into positive and negative ions as sodium chloride. [ CH2 CH2]n C O- + Na O H2 O [ CH2 CH2]n C OO + Na+ But weird things happen for the polyelectrolytes. Normal uncharged polymer molecules, when they're in solution tend to be tangled up in what big shot scientists call a random coil, All those negative charges are going to repel each other. This does weird things to the polymer chain. But when the polymer chain is covered with negative charges (which repel each other), the polymer can't be bunched in on itself. So the chain stretches out, like this: This makes the solution (remember we're talking about polyelectrolytes in solution) more viscous. Think about it. When the polyelectrolyte chain stretches out it takes up more space, and is more effective at resisting the flow of the solvent molecules around it. So the solution becomes thick and syrupy. But there's a way you can stop this from happening. If one take a solution of a polyelectrolyte in water, and throws in a lot of salt. Something fun will happen. The NaCl will separate into Na+ and Cl- ions. In the case of a negatively charged polyelectrolyte, the positively charged Na+ ions will get in between the negative charges on the polymer, and cancel them out in effect. When this happens, the polymer chain collapses back into random coil again.

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Path: Cincinnati >> MLTI >> 300 Fall, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: 020501 Quiz 6 Polymer Properties 1) Sketch the free energy versus composition for a symmetric polymer-polymer blend -for N> 2, N = 2 and N<2. -Show the critical point, critical composition, spinodal point and binodal point on these plots. -Explain ho...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: 020327 Properties Quiz 1 a) Flory discusses a Gaussian coil in his book Polymer Chemistry. -Give the Gaussian distribution function and explain how it pertains to a polymer chain. b) Give a value for <R> and <R2> for a Gaussian chain. How can these b...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: 060519 Quiz 8 Polymer Properties 1) Suppose that Flory had taken the simple route of substituting /N for \'s in the gas equation rather than substituting only the lead terms to the natural logs. a) Calculate the critical interaction parameter for a sy...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: Chapter 1 Polymer Physics The Isolated Polymer Chain Random Walk model: Brownian motion of a particle occurs in a close to random manner. If the path of a particle in a random (Brownian) walk is traced in time it will most likely cross itself several...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: Lectures on Theoretical Physics Linear Response Theory Peter Hertel University of Osnabrck, Germany u The theory of linear response to perturbations of the equilibrium state, or linear response theory, is the subject of this series of lectures. Or...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: Background for RPA: 1 Distance = Force spring constant 1) = J = is the susceptibility k = k k 2) Change in free energy, dG, is proportional to the field (force) and to the response, change in distance, dGk = k d k = ak k dk so a 2 Gk = k k ...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: Take Home Quiz 8, 030523 Polymer Properties 1) The following light scattering data was obtained for PVME/PS at 130C (critical temperature 109C) at 75% wt PVME which is the critical composition for this blend. The patterns to the right are separated b...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: 080227 Quiz 7 Polymer Properties 1) Electrostatic screening involves the reduction in the energy, dU, associated with two charges separated by a distance r associated with a change in separation distance dr. a) Show that a linear dependence of the ...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: Rubber Elasticity (Indented text follows Strobl, other follows Doi) Elasticity of A Single Chain: The spring constant associated with a single polymer chain is of importance in a wide range of situations from the development of a simple description o...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: 030411 Quiz 2 Properties Consider a polyethylene chain synthesized with 2000 ethylene units. 1) a) Calculate the root mean square (RMS) end-to-end distance if the carbon-carbon bond is 1.54 in length and the chain is considered a random walk of ethy...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: 050527 Quiz 9 Polymer Properties The random phase approximation can be used to describe the free energy of a polymer blend. For example Mueller1 gives: where in the first term is the number density of chains and T is kT. a) Use k = k k and k = dF/d...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: U.S. copyright law (title 17 of U.S. code) governs the reproduction and redistribution of copyrighted material. -I NVESTIGATIONS O N THE THEORY .OF ,THE BROWNIAN MOVEMENT BY ALBERT EINSTEIN, PH.D. e EDITED WITH NOTES BY This new Dover edition, fir...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: 030418 Quiz 3 Properties 1) The partition function, Z, gives the number of configurational states accessible to a molecule at a given temperature. For a polymer, a state relates to a given set of bond rotations. a) Write an expression for the partiti...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: ...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: Quiz 6 Properties, 5/8/01 The Gibbs free energy for mixing for a polymer-polymer blend is given by, Gmix = RTnc (a lna)/Na + (b lnb)/Nb + a b ) a) For a symmetric blend show that this expression depends on N as the governing thermodynamic feature for...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: 060421 Quiz 4 Polymer Properties 1) Scattering of electromagnetic radiation is usually considered in terms of binary interference effects (re-radiation from 2 points) because the power of scattered radiation is less than 1% of the incident radiation ...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: Properties Quiz 1 010403 In class we compared the structure of a polymer coil to the path of a Brownian particle. a) -Give a function that describes the distance traveled on average for a Brownian particle. -Compare this function with the function fo...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: Quiz 3 Polymer Properties 4/17/01 The left figure below (from Strobl) is intended to demonstrate the existence of good solvent scaling. The right figure (from Doi) shows the behavior of Rg and RH with temperature. a) -Explain the axes on this plot. ...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: 060505 Quiz 6 Polymer Properties 1) Polymer chains in a melt display ideal behavior. In dilute solution they display non-ideal behavior, for instance in terms of the second virial coefficient, A2. a) Does this observation agree with the behavior of a...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: 050429 Quiz 5 Polymer Properties The concept of excluded volume began with an extremely simple physical model based on common sense. If we consider an ideal gas composed of non-interaction spheres the ideal gas law applies, P/RT = n/V = , where the s...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: 030502 Quiz 5 Polymer Properties 1) In class we used the analogy of the edge of a forest/jungle at sunset to describe screening. a) Use this analogy to describe the screening length. b) Use this analogy to describe a mean field. c) For a mathematical...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: 030516 Quiz 7 Properties 1) The following figure is from Doi\'s text, Introduction to Polymer Physics, a) What equation would you use to describe the phase behavior seen? b) Where are the bimodal and spinodal curves in this plot? c) Explain the behav...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: 020417 Quiz 4 Properties 1) Flory defined the persistence length, using the equation a = l\'/(1-). Explain each of the terms in this equation. Define the persistence length using a sketch of a polymer coil. Explain how the persistence length could be...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: 060331 Quiz 1 Polymer Properties This week we discussed the difference between the view of a polymer chain by a chemist, physicist and engineer (rheologist). We also discussed differences between models, simulations and experiments. An example of the...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: Lecture 1: Linear Response Theory Last semester in 8.511, we discussed linear response theory in the context of charge screening and the freefermion polarization function. This theory can be extended to a much wider range of areas, however, and is ...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: 717 J. Appl. C~st. (1995). 28, 717-728 Approximations L e a d i n g to a U n i f i e d E x p o n e n t i a l / P o w e r - L a w Approach to Small-Angle Scattering BY G. BEAUCAGE Department of Materials Science and Engineering, University of Cinci...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: Molecular Weight and Branching Definitions 12 10 8 Moles \"Drop the idea of large molecules. Organic molecules with a molecular weight higher than 5000 do not exist.\" Advice given to Hermann Staudinger Mn 108, 500 Mw 118, 200 Methods for the Dete...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: 090404 Quiz 2 Polymer Properties Chain persistence is on strong footing since it can be verified analytically (calculation), theoretically and experimentally by several techniques. Chain persistence is important to calculation of chain conformational...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: THE JOURNAL OF CHEMICAL PHYSICS 125, 204901 2006 A Monte Carlo simulation study of branched polymers Arun Yethiraj Theoretical Chemistry Institute and Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53706 Received 24 October 20...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: Appendix C - Persistence length 183 APPENDIX C - PERSISTENCE LENGTH Consider an ideal chain with N segments each of length a, such that the contour length Lc is Lc = Na. (C.1) If the orientation of each element on the chain is independent of any ...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: Polymer Properties Quiz 3 080130 The characteristic ratio, Cn, is the ratio of observed end-to-end distance, and the end-to-end distance of a freely jointed chain composed of n bonds of step length lchem, r2 l2 0 Cn = = stat. seg. length 2 2 n chem l...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: Hydrodyamic Radius, RH: In addition to the analytic size of a linear (C=1) chain, the end to end distance, Reted or R0, and the structural size, the radius or gyration, Rg, dynamic measurements yield a size called the hydrodynamic radius, RH. Conside...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: 040507 Quiz 6 Polymer Properties The concept of \"screening\" of interactions was developed by Debye for electrostatics where two charges are immersed in an ionic medium. The Debye screening length scales with the ion concentration, D ~ c-1/2. We discu...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: 040423 Quiz 4 Polymer Properties For a symmetric distribution function the mean, median and most probable values are identical. This is not true for a skewed distribution (single mode but asymmetric) such as the log-normal and Lorentzian distribution...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: Quiz 8 Polymer Physics 11/18/00 The Rouse model represents a polymer coil as a series of beads and springs. a) The Rouse spring has a spring constant based on rubber elasticity theory. This is sometimes called the ideal rubber law in analogy to an id...
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Path: Cincinnati >> MTEN >> 634 Winter, 2008
Description: 060512 Quiz 7 Polymer Properties This week we covered the concentration dependencies of the osmotic pressure of a polymer solution using the concentration blob model and the Flory-Huggins (F-H) equation for polymer solutions and blends. 1) Last weeks...

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