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Chemistry Organic Problem-Solving Session, December 2005 PROBLEM 1: Courtesy of the CMLD Provide a possible mechanism for the following transformations. a) Me N3 N O OMe O 1. 2. h , MeOH 75%, 2 steps Ph N N CO2Me MeO2C Me b) MOMO Me O CO2Et OPMB , toluene Me OTBDPS 60% H Me OPMB MOMO H Me O CO2Et PROBLEM 2: Courtesy of the Schaus Group Please provide a mechanism for the formation of Product B and Product C. O H3CO O N H3CO OCH3 O CO2CH3 S S H3CO S O N O H3CO OCH3 CO2CH3 O TFAA (1.5 equiv.), NEt3 (2 equiv.) DCM, -78 oC (3 BF3-OEt2 equiv.) CO2CH3 H3CO H3CO N O A Product B Product C PROBLEM 3: Courtesy of the Panek Group Provide a structure for compounds A and B. Also, provide a mechanism for the conversion of A into B. O O O 1. LiAlH4 2. Swern A C21H32O3 1. NH3 2. AcOH, B C21H31NO C21H32O3 PROBLEM 4: Courtesy of the Porco Group Provide mechanisms for the following oxidative transformations: OH 1eq. PIFA O H2O/CH2CN r.t., 15 h O OH O OH O C11H23 1eq. PIFA H2O/CH2CN r.t., 15 h C11H23 HO O O C11H23 O O HO (R)-(+)-tanikolide
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BU >> SAR HP >> 839 (Fall, 2008)
Episodic arc migration, crustal thickening, subduction erosion, and magmatism in the south-central Andes Suzanne Mahlburg Kay INSTOC, Snee Hall, Cornell University, Ithaca, New York 14853, USA Estanislao Godoy SERNAGEOMIN, Casilla 10465, Santiago, C...
BU >> SAR HP >> 870 (Fall, 2008)
Episodic arc migration, crustal thickening, subduction erosion, and magmatism in the south-central Andes Suzanne Mahlburg Kay INSTOC, Snee Hall, Cornell University, Ithaca, New York 14853, USA Estanislao Godoy SERNAGEOMIN, Casilla 10465, Santiago, C...
BU >> SAR HP >> 839 (Fall, 2008)
Laurence J. Kotlikoff Boston University June 2005 Paul Samuelsons Amazing Intergenerational Transfer1 Im deeply honored to participate in this forum celebrating Paul Samuelsons ongoing contributions to economics. Pauls work has profoundly influenced...
BU >> SAR HP >> 870 (Fall, 2008)
Laurence J. Kotlikoff Boston University June 2005 Paul Samuelsons Amazing Intergenerational Transfer1 Im deeply honored to participate in this forum celebrating Paul Samuelsons ongoing contributions to economics. Pauls work has profoundly influenced...
BU >> SAR HP >> 839 (Fall, 2008)
Pergamon Geochimica et Cosmochimica Acta, Vol. 66, No. 6, pp. 10671083, 2002 Copyright 2002 Elsevier Science Ltd Printed in the USA. All rights reserved 0016-7037/02 $22.00 .00 PII S0016-7037(01)00828-6 Spatially correlated anomalous 40Ar/39Ar ag...
BU >> SAR HP >> 870 (Fall, 2008)
Pergamon Geochimica et Cosmochimica Acta, Vol. 66, No. 6, pp. 10671083, 2002 Copyright 2002 Elsevier Science Ltd Printed in the USA. All rights reserved 0016-7037/02 $22.00 .00 PII S0016-7037(01)00828-6 Spatially correlated anomalous 40Ar/39Ar ag...
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Military Sexual Slave Women during World War II Jaemin Lee, Spring 2007 Outline I. Overview, testimonies of victims, and pictures II. Sexual slave womens postwar experiences III. Theological reflection I. Overview and testimonies of victims Overvi...
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Boston Uni versity Sports Medicine 285 Babc oc k Street Boston, M A 02215 To All Student-Athletes and Their Parents / Guardians: The information that is requested in the Athletic Medical Screening Packet is a vital part of both our Athletic Medical S...
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Boston Uni versity Sports Medicine 285 Babc oc k Street Boston, M A 02215 To All Student-Athletes and Their Parents / Guardians: The information that is requested in the Athletic Medical Screening Packet is a vital part of both our Athletic Medical S...
BU >> SED DE >> 692 (Fall, 2008)
Boston Uni versity Sports Medicine 285 Babc oc k Street Boston, M A 02215 To All Student-Athletes and Their Parents / Guardians: The information that is requested in the Athletic Medical Screening Packet is a vital part of both our Athletic Medical S...
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Boston Uni versity Sports Medicine 285 Babc oc k Street Boston, M A 02215 To All Student-Athletes and Their Parents / Guardians: The information that is requested in the Athletic Medical Screening Packet is a vital part of both our Athletic Medical S...
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Boston Uni versity Sports Medicine 285 Babc oc k Street Boston, M A 02215 To All Student-Athletes and Their Parents / Guardians: The information that is requested in the Athletic Medical Screening Packet is a vital part of both our Athletic Medical S...
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Boston Uni versity Sports Medicine 285 Babc oc k Street Boston, M A 02215 To All Student-Athletes and Their Parents / Guardians: The information that is requested in the Athletic Medical Screening Packet is a vital part of both our Athletic Medical S...
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Boston Uni versity Sports Medicine 285 Babc oc k Street Boston, M A 02215 To All Student-Athletes and Their Parents / Guardians: The information that is requested in the Athletic Medical Screening Packet is a vital part of both our Athletic Medical S...
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Boston Uni versity Sports Medicine 285 Babc oc k Street Boston, M A 02215 To All Student-Athletes and Their Parents / Guardians: The information that is requested in the Athletic Medical Screening Packet is a vital part of both our Athletic Medical S...
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Boston Uni versity Sports Medicine 285 Babc oc k Street Boston, M A 02215 To All Student-Athletes and Their Parents / Guardians: The information that is requested in the Athletic Medical Screening Packet is a vital part of both our Athletic Medical S...
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American History X A Theological Analysis by Jin Kyung Park The Content I. Introduction -Background of the Film, American History X -Characters -Family Tree -Synopsis II. Sin based on Suchockis God-Christ-Church III. Reconciliation: Justice based...
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American History X A Theological Analysis by Jin Kyung Park The Content I. Introduction -Background of the Film, American History X -Characters -Family Tree -Synopsis II. Sin based on Suchockis God-Christ-Church III. Reconciliation: Justice based...
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American History X A Theological Analysis by Jin Kyung Park The Content I. Introduction -Background of the Film, American History X -Characters -Family Tree -Synopsis II. Sin based on Suchockis God-Christ-Church III. Reconciliation: Justice based...
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American History X A Theological Analysis by Jin Kyung Park The Content I. Introduction -Background of the Film, American History X -Characters -Family Tree -Synopsis II. Sin based on Suchockis God-Christ-Church III. Reconciliation: Justice based...
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American History X A Theological Analysis by Jin Kyung Park The Content I. Introduction -Background of the Film, American History X -Characters -Family Tree -Synopsis II. Sin based on Suchockis God-Christ-Church III. Reconciliation: Justice based...
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American History X A Theological Analysis by Jin Kyung Park The Content I. Introduction -Background of the Film, American History X -Characters -Family Tree -Synopsis II. Sin based on Suchockis God-Christ-Church III. Reconciliation: Justice based...
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American History X A Theological Analysis by Jin Kyung Park The Content I. Introduction -Background of the Film, American History X -Characters -Family Tree -Synopsis II. Sin based on Suchockis God-Christ-Church III. Reconciliation: Justice based...
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American History X A Theological Analysis by Jin Kyung Park The Content I. Introduction -Background of the Film, American History X -Characters -Family Tree -Synopsis II. Sin based on Suchockis God-Christ-Church III. Reconciliation: Justice based...
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American History X A Theological Analysis by Jin Kyung Park The Content I. Introduction -Background of the Film, American History X -Characters -Family Tree -Synopsis II. Sin based on Suchockis God-Christ-Church III. Reconciliation: Justice based...
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American History X A Theological Analysis by Jin Kyung Park The Content I. Introduction -Background of the Film, American History X -Characters -Family Tree -Synopsis II. Sin based on Suchockis God-Christ-Church III. Reconciliation: Justice based...
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American History X A Theological Analysis by Jin Kyung Park The Content I. Introduction -Background of the Film, American History X -Characters -Family Tree -Synopsis II. Sin based on Suchockis God-Christ-Church III. Reconciliation: Justice based...
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Modeling and Forecasting Stock Return Volatility Using a Random Level Shift Model Yang K. Lu Boston University Pierre Perron Boston University July 28, 2008; Revised September 21, 2008. Abstract We consider the estimation of a random level shift mo...
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Modeling and Forecasting Stock Return Volatility Using a Random Level Shift Model Yang K. Lu Boston University Pierre Perron Boston University July 28, 2008; Revised September 21, 2008. Abstract We consider the estimation of a random level shift mo...
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Modeling and Forecasting Stock Return Volatility Using a Random Level Shift Model Yang K. Lu Boston University Pierre Perron Boston University July 28, 2008; Revised September 21, 2008. Abstract We consider the estimation of a random level shift mo...
BU >> SED DE >> 690 (Fall, 2008)
Modeling and Forecasting Stock Return Volatility Using a Random Level Shift Model Yang K. Lu Boston University Pierre Perron Boston University July 28, 2008; Revised September 21, 2008. Abstract We consider the estimation of a random level shift mo...
BU >> SED DE >> 691 (Fall, 2008)
Modeling and Forecasting Stock Return Volatility Using a Random Level Shift Model Yang K. Lu Boston University Pierre Perron Boston University July 28, 2008; Revised September 21, 2008. Abstract We consider the estimation of a random level shift mo...
BU >> SED DE >> 692 (Fall, 2008)
Modeling and Forecasting Stock Return Volatility Using a Random Level Shift Model Yang K. Lu Boston University Pierre Perron Boston University July 28, 2008; Revised September 21, 2008. Abstract We consider the estimation of a random level shift mo...
BU >> SED IE >> 493 (Fall, 2008)
Modeling and Forecasting Stock Return Volatility Using a Random Level Shift Model Yang K. Lu Boston University Pierre Perron Boston University July 28, 2008; Revised September 21, 2008. Abstract We consider the estimation of a random level shift mo...
BU >> SED SE >> 493 (Spring, 2008)
Modeling and Forecasting Stock Return Volatility Using a Random Level Shift Model Yang K. Lu Boston University Pierre Perron Boston University July 28, 2008; Revised September 21, 2008. Abstract We consider the estimation of a random level shift mo...
BU >> SED SE >> 598 (Fall, 2008)
Modeling and Forecasting Stock Return Volatility Using a Random Level Shift Model Yang K. Lu Boston University Pierre Perron Boston University July 28, 2008; Revised September 21, 2008. Abstract We consider the estimation of a random level shift mo...
BU >> SED SE >> 807 (Fall, 2008)
Modeling and Forecasting Stock Return Volatility Using a Random Level Shift Model Yang K. Lu Boston University Pierre Perron Boston University July 28, 2008; Revised September 21, 2008. Abstract We consider the estimation of a random level shift mo...
BU >> SMG LA >> 346 (Fall, 2008)
Modeling and Forecasting Stock Return Volatility Using a Random Level Shift Model Yang K. Lu Boston University Pierre Perron Boston University July 28, 2008; Revised September 21, 2008. Abstract We consider the estimation of a random level shift mo...
BU >> SMG LA >> 349 (Fall, 2008)
Modeling and Forecasting Stock Return Volatility Using a Random Level Shift Model Yang K. Lu Boston University Pierre Perron Boston University July 28, 2008; Revised September 21, 2008. Abstract We consider the estimation of a random level shift mo...
BU >> SMG LA >> 450 (Fall, 2008)
Modeling and Forecasting Stock Return Volatility Using a Random Level Shift Model Yang K. Lu Boston University Pierre Perron Boston University July 28, 2008; Revised September 21, 2008. Abstract We consider the estimation of a random level shift mo...
BU >> CGS HU >> 111 (Fall, 2008)
Dealing with Structural Breaks Pierre Perron Boston University This version: April 20, 2005 Abstract This chapter is concerned with methodological issues related to estimation, testing and computation in the context of structural changes in the line...
BU >> SED CH >> 655 (Fall, 2008)
Dealing with Structural Breaks Pierre Perron Boston University This version: April 20, 2005 Abstract This chapter is concerned with methodological issues related to estimation, testing and computation in the context of structural changes in the line...
BU >> SED DE >> 592 (Fall, 2008)
Dealing with Structural Breaks Pierre Perron Boston University This version: April 20, 2005 Abstract This chapter is concerned with methodological issues related to estimation, testing and computation in the context of structural changes in the line...
BU >> SED DE >> 690 (Fall, 2008)
Dealing with Structural Breaks Pierre Perron Boston University This version: April 20, 2005 Abstract This chapter is concerned with methodological issues related to estimation, testing and computation in the context of structural changes in the line...
BU >> SED DE >> 691 (Fall, 2008)
Dealing with Structural Breaks Pierre Perron Boston University This version: April 20, 2005 Abstract This chapter is concerned with methodological issues related to estimation, testing and computation in the context of structural changes in the line...
BU >> SED DE >> 692 (Fall, 2008)
Dealing with Structural Breaks Pierre Perron Boston University This version: April 20, 2005 Abstract This chapter is concerned with methodological issues related to estimation, testing and computation in the context of structural changes in the line...
BU >> SED IE >> 493 (Fall, 2008)
Dealing with Structural Breaks Pierre Perron Boston University This version: April 20, 2005 Abstract This chapter is concerned with methodological issues related to estimation, testing and computation in the context of structural changes in the line...
BU >> SED SE >> 493 (Spring, 2008)
Dealing with Structural Breaks Pierre Perron Boston University This version: April 20, 2005 Abstract This chapter is concerned with methodological issues related to estimation, testing and computation in the context of structural changes in the line...
BU >> SED SE >> 598 (Fall, 2008)
Dealing with Structural Breaks Pierre Perron Boston University This version: April 20, 2005 Abstract This chapter is concerned with methodological issues related to estimation, testing and computation in the context of structural changes in the line...
BU >> SED SE >> 807 (Fall, 2008)
Dealing with Structural Breaks Pierre Perron Boston University This version: April 20, 2005 Abstract This chapter is concerned with methodological issues related to estimation, testing and computation in the context of structural changes in the line...
BU >> SMG LA >> 346 (Fall, 2008)
Dealing with Structural Breaks Pierre Perron Boston University This version: April 20, 2005 Abstract This chapter is concerned with methodological issues related to estimation, testing and computation in the context of structural changes in the line...
BU >> SMG LA >> 349 (Fall, 2008)
Dealing with Structural Breaks Pierre Perron Boston University This version: April 20, 2005 Abstract This chapter is concerned with methodological issues related to estimation, testing and computation in the context of structural changes in the line...
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