| Terms |
Definitions |
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c=
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vλ
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Photon
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quanta of light
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1 nm (1 nanometer)
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10^-9 m
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spectrum
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when the different frequencies separate into a spectrum of colors
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Sublevel
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sublevels of principle energy level, represented by s,p,d, and f.
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Electromagnetic Radiation
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Includes radio waves, microwaves, infrared wave, visible light, ultraviolet waves, x-rays, and gamma rays.
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amplitude
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the height of the wave's crest
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electron-dot structure
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consists of an electrons symbol, representing the atomic nucleus and inner-level electron, that is surrounded by dots representing the atom's valence electrons
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ground state
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lowest energy level for an electron
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wavelength
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The distance between crests of waves, such as those of the electromagnetic spectrum.
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Aufbau principle
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an electron occupies the lowest-energy orbital that can receive it
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Quantum
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The amount of energy required to move an electron from its present energy level to the next higher one
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Hund's rule
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states that single electrons with the same spin must occupy each equal-energy orbital before additional electrons with opposite spins can occupy the same orbitals
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Quanta
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Max Planck discovered in 1900. It is the energy that can only exist in discrete quantities.
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electron cloud
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visual model of the probable locations of electrons in an atom
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Electron Configurations
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The ways in which electrons are arranged in various orbitals around the nuclei of atoms.
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energy levels
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the fixed energies an electron can have.
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lowest energy
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closest to the nucleus, higher the energy further away and each level gets closer
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Valence Electron
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The electrons in an atom's outermost orbitals; determine the chemical properties of an element.
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frequency
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number of waves that pass at a given time
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atoms lose energy
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when electrons go to lower energy levels
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pauli exclusion principle
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an atomic orbital may describe may describe at most two electrons.
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Heisenberg Uncertainty Principle
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it is impossible to know exactly both the velocity and the position of a particle at the same time
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Atomic orbital
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- Often thought as a region of space in which there is a high probability of finding an electron
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energy sublevels
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labeled s, p, d, or f according to the shapes of the atom's orbitals
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Democritus proposed the world is
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made up of empty space and atoms are the smallest particals
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sublevels
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s,p,d,f
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Photons
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Particles of light.
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angular momentum quantum
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shape of orbital
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electromagnetic spectrum
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includes all forms of electromagnetic radiation with the only differences in the types of radiation being their frequencies and wavelengths
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gamma rays
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have the highest frequency and shortest wavelength
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Quantum Mechanical
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The modern description of the behavior of electrons in atoms
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electron configuration
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the arrangement of electrons in an atom, which is prescribed by 3 rules
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James Clerk Maxwell
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1873, proposed light consists of electromagnetic waves(waves with electric field component & a magnetic field running perpendicularly)
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atomic emission spectrum
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a set of frequencies of electromagnetic waves given off by atoms of an element; consists of a series of fine lines of individual colors
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quantum mechanical model
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determines the allowed energies an electron can have and how likely it is to find the electron in various locations around the nucleus
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energy of quanta
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E(energy of single quanta in whole numbers) = H (planck's constant/ 6.63 x 10^-34) x F (frequency of photon)............................discovered by planck 1900 after observing color changed of solids after heated.
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more intense light =
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more packets of energy or photons. more electrons...velocity never changed. increased frequency is just changed color.
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Why don't electrons fall into the nucleus?
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Bohr proposed a planetary model where electrons orbit the nucleus in an elliptical path much as planets orbit the sun-- earth orbits the sun so fast that it does not crash into the sun. Can only orbit at certain distances.
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principle energy level
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...
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sphere
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shape of an s orbital
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Low Frequency Waves
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Waves with long wavelengths.
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Hertz
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SI unit of cycles per second
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Electromagnetic Radiaton
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the radiation associated with electric and magnetic field; it caries periodically and travels at the speed if light
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c=lambda*nu
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the speed of light, wavelength times frequency
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s orbitals
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- spherical
- the probability of finding an electron at a given distance from the nucleus does not depend on direction
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3
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The number of valence electrons of B, Al, Ga, In, and Tl.
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photoelectric effect
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high energy light particles shine on piece of metal releases an electron off the metal and completes the circuit
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3.00 x 10^8 m/s
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speed electromagnetic waves travel at in a vacuum
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absorbs energy
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when an electron moves to a higher energy level
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quatum
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amount of energy it takes to move an electron to another energy level
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Excited State
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the state in which an atom had more energy than it does at its ground state
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Dual nature of electron
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why is electron restricted to orbiting nucleus or why energy of hydrogen electron are quantisized (small discrete energy)
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Niels Bohr Atomic Model - 1913
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- Bohr proposed that an electron is found only in specific circular paths, or orbits, around the nucleus
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2nd energy level can hold
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8
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nucleus
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positively charged center of an atom
contains protons and neutrons
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Classical theory
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molecule/atoms and macroscopic items are NOT governed by the same physical laws. CANNOT explain photoelectric effect. belief that any amount of energy could be released in a radiation process not in small units.
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how are the orbitals diff
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different axes
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Niels Bohr
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proposed that electrons must have enough energy to keep them in constant motion around the nucleus
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Rutherford model
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small dense center, nucleus is positively charged, atom is mostly empty space
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Schrodinger's equation
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determines shape of atomic orbitals. all about the probability of where electron would be.
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Excitation
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When electron absorbs energy, the atom raises from its ground state to an excited state, where n = 2, 3, 4, 5, 6 and so forth
- A quantum of energy in the form of light is emitted when the electron drops back to a lower energy level
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Noble-Gas Configuration
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an outer main energy level fully occupied, in most cases, by eight electrons
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de Broglie equation
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predicts that all moving particles have wave characteristics λ=h/mv
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principal quantum numbers
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which the quantum mechanical model assigns to indicate the relative sizes and energies of atomic orbitals
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6
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The number of valence electrons of O, S, Se, Te, and Po.
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energy level
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the specific energies an electron in an atom or other system can have
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loses energy
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when an electron falls to a lower energy level
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J.J. Thomson - 1897
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- Discovers the electron
- "Plum pudding model" - electrons embedded in a sphere of positive electrical charge
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Orbital
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a region in an atom where there is a high probability of finding electrons
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spin quantum number
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an orbital can hold 2 electrons that spin in opposite directions, electron spins 1/2 or -1/2
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Speed of Light - a constant - (c) =
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(lampda) * (nu)
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Albert Einstein - 1905 - Photons
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Einstein - Light could be described as quanta of energy, that behave as if they were particles
Light quanta - Photons
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