problem set 4.002 solutions

problem set 4.002 solutions - Chem 316 Problem Set 4...

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Chem 316 Problem Set 4 solutions 1. For the molecular formula C 6 H 11 N: a. 2 units of unsaturation. Possible combinations: 2. Draw the two compounds with the formula CH 3 CH=NCH 3 . 3. For the following molecules, draw and label the cis and trans isomers. If geometric isomers cannot exist, write "no cis or trans". 2 rings: 2 double bonds: 1 ring, 1 double bond: N N NH 2 N N Br Br H 3 CHC CHI CHCH 3 cis trans cis trans cis trans no cis or trans Br Br cis trans Br Br cis trans I I cis trans
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4. Draw the various eclipsed and staggered conformations for the following alkane. Label each conformer as “totally eclipsed,” “eclipsed,” gauche,” and “anti.” Graph the relative energy of each conformer. 5. 1,2-dichloroethane is shown below: Cl Cl a. Draw the various eclipsed and staggered conformations of 1,2-dichloroethane using Newman projections. Label each conformation as "totally eclipsed," "eclipsed," "gauche," and "anti." b. Graph the relative energy of each conformation. (Assume that 0 ˚ is the totally
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problem set 4.002 solutions - Chem 316 Problem Set 4...

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