CHAPTER 3 NOTES

CHAPTER 3 NOTES - CHAPTER 3 ORGANIC REACTIONS: ACIDS &...

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CHAPTER 3 ORGANIC REACTIONS: ACIDS & BASES - - REACTION MECHANISMS - - ACID-BASE REACTIONS - - STRUCTURE v. ACIDITY - - CARBOXYLIC ACIDS - - ORGANIC BASES - - SOLVENT EFFECTS - - ENERGY CHANGES - - 2 H, 3 H LABELING
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- - REACTION MECHANISMS - - MAJOR REACTION TYPES - - SUBSTITUTION - - ADDITION - - ELIMINATION - - REARRANGEMENT - - SEQUENCE OF EVENTS DURING REACTION - - BOND-BREAKING ; BOND-MAKING - - SIMULTANEOUS OR - - SEQUENTIAL
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- - IF PROCESS IS SEQUENTIAL , - - INTERMEDIATES FORMED - - DURING BOND-BREAKING - - IONS [ HETEROLYSIS ] CHARGED SPECIES ( + / - CHARGE ) - - RADICALS [ HOMOLYSIS ] NEUTRAL SPECIES ( SINGLE, UNPAIRED e - ) NOTE: - - INTERMEDIATES : NOT SEEN IN THE PRODUCT !! LEARN: CONVENTION : CURVED ARROWS - - DOUBLE - BARBED ARROW - - MOVEMENT OF 2 ELECTRONS - - SINGLE - BARBED ARROW - - MOVEMENT OF 1 ELECTRON - - WHICH ONE IS USED TO DEPICT: - - HETEROLYSIS ? - - HOMOLYSIS ? - - ACID-BASE REACTIONS : REVIEW!
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- - BRONSTED-LOWRY - - ACID: H + DONOR - - BASE: ? - - e.g. ? - - LEWIS - - ACID: ELECTRON PAIR ACCEPTOR - - BASE: ? - - e.g. ? - - CONSIDER REACTION BETWEEN BF 3 AND NH 3 - - IS THIS AN ACID-BASE REACTION ? -
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CHAPTER 3 NOTES - CHAPTER 3 ORGANIC REACTIONS: ACIDS &...

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