CHAPTER 6 NOTES

CHAPTER 6 NOTES - CHAPTER 6 IONIC REACTIONS: ALKYL...

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Unformatted text preview: CHAPTER 6 IONIC REACTIONS: ALKYL HALIDES-- ALKYL HALIDES-- REACTIONS: SUBSTITUTION, ELIMINATION-- MECHANISMS: SINGLE STEP, MULTI-STEP-- CARBOCATIONS-- STEREOCHEMISTRY-- SOLVENT EFFECTS-- OTHER FACTORS AFFECTING ( S N / E ) REACTIONS-- ORGANIC SYNTHESES WITH R-X ALKYL HALIDES:-- WHAT IF CARBON IS sp 2 ?-- DIFFERENT REACTIVITY ! C X X = F , Cl , Br , I sp 3 C X sp 2 REACTIONS: -- SUBSTITUTION -- ELIMINATION TERMS USED COMMONLY:-- LEAVING GROUP : X -- TAKES BOND PAIR OF e WITH IT-- AFTER LEAVING, THE LEAVING SPECIES-- MUST BE STABLE ( CHECK LEWIS STRUCTURE )-- MUST NOT BE A STRONG BASE-- DO PROBLEMS : 6.18 a, b p. 281-- SUBSTRATE: ALKYL HALIDE-- HAS A GOOD LEAVING GROUP -- NUCLEOPHILE : Nu: C C X H B: C C Nu H S U B S T I T U T I O N C C E L I M I N A T I...
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CHAPTER 6 NOTES - CHAPTER 6 IONIC REACTIONS: ALKYL...

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