CHAPTER 13 - CHAPTER 13 CONJUGATED UNSATURATED SYSTEMS - -...

Info iconThis preview shows pages 1–5. Sign up to view the full content.

View Full Document Right Arrow Icon
CHAPTER 13 CONJUGATED UNSATURATED SYSTEMS - - INTRODUCTION - - ALLYL : RADICAL , CATION - - DIENES, POLYENES - - CONJUGATION - - UV – VISIBLE SPECTROSCOPY - - CONJUGATE ADDITION : 1 , 4 ( v. 1 , 2 ) - - DIELS – ALDER REACTION
Background image of page 1

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
INTRODUCTION - - CLASSIFICATION OF DIENES: - - EXAMINE THE DIENE STRUCTURES BELOW - - HYBRIDIZATION PATTERN ? ( OF THE CARBON ATOMS ) ALLYL SYSTEM p. 586-7 p. 583-4 - - EXAMINE HYBRIDIZATION PATTERN ( cf. CONJUGATED DIENES ) C C C C C C C C C C C C C C C ISOLATED C O N J U G A T E D CUMULATED H 2 C C H CH 2 H 2 C C H CH 2 .
Background image of page 2
- - SEE RESONANCE STRUCTURES, MO DIAGRAMS - - IMPLICATIONS ? STABILITY - - WHY ? ( DELOCALIZATION ) REVIEW : SECTION 13.5 p. 587 – 591 REACTIVITY - - SUBSTITUTION v . ADDITION ( HIGH TEMP. ) ( LOW TEMP. ) - - WHY ? H 2 C C H CH 3 H 2 C H C CH 3 X X H 2 C C H CH 2 X + X 2 LOW TEMP.
Background image of page 3

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
CONSIDER EFFECTS ON G o ( SECTION 3.9 ) (RELATIONSHIP BETWEEN G o , H o , S o , T ? ) - - FOR ADDITION REACTION : S o = ( – ) - - WHY ? SO ?
Background image of page 4
Image of page 5
This is the end of the preview. Sign up to access the rest of the document.

This note was uploaded on 04/14/2008 for the course CHEM 2380 taught by Professor Dandekar during the Winter '07 term at North Texas.

Page1 / 12

CHAPTER 13 - CHAPTER 13 CONJUGATED UNSATURATED SYSTEMS - -...

This preview shows document pages 1 - 5. Sign up to view the full document.

View Full Document Right Arrow Icon
Ask a homework question - tutors are online