CHAPTER 11 NOTES

CHAPTER 11 NOTES - CHAPTER 11 ALCOHOLS ETHERS STRUCTURE...

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CHAPTER 11 ALCOHOLS & ETHERS - - STRUCTURE - - PHYSICAL PROPERTIES - - SYNTHESIS OF ALCOHOLS - - REACTIONS OF ALCOHOLS - - SYNTHESIS OF ETHERS - - REACTIONS OF ETHERS
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STRUCTURE, NOMENCLATURE : R – O – H R – O – R’ ALCOH OL ALKYL ALKYL ETHER ( COMMON ) ( COMMON ) BUT, CAN GET A LITTLE CONFUSING WITH BRANCHED – R GROUPS SO : USE IUPAC RULES: ALKAN OL ALKOXY ALKANE SMALLER LARGER R GROUP R GROUP - - CYCLIC ETHERS - - SEE p. 480
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- - SEE TABLES 11.1, 11.2 p. 480 – 481 - - cf. B.P. OF ALCOHOLS, ETHERS & HYDROCARBONS HAVING SAME MW - - NOT NECESSARILY THE SAME NUMBER OF CARBON ATOMS !) e.g. CH 3 CH 2 OCH 2 CH 3 , CH 3 CH 2 CH 2 CH 2 CH 3 , CH 3 CH 2 CH 2 CH 2 OH SYNTHESIS OF ALCOHOLS: - - FROM ALKENES: - - MARKOVNIKOV REGIOCHEMISTRY 1 ] H 3 O + , H 2 O: REVIEW! p. 332 SOMETIMES, THERE ARE PROBLEMS: C + REARRANGEMENTS ! 2
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This note was uploaded on 04/14/2008 for the course CHEM 2370 taught by Professor Dandekar during the Fall '07 term at North Texas.

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CHAPTER 11 NOTES - CHAPTER 11 ALCOHOLS ETHERS STRUCTURE...

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