lab 1 syntheis of tpentyl chloride

lab 1 syntheis of tpentyl chloride - f t h e r e a c t i o...

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Scanned by CamScanner . . P o l l , ; B a . . . . S y n t h 1 S 0 : F : 9 y l C h l 0 r i d e
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Scanned by CamScanner E { h ˘ V 1 0 \ 1 h o u u 4 0 W U L H K } b R a t n p \ o o h u p e w i D e s M / a - 7 o u W > - 9 u Q B t e [ v v l o v e t u a r s u e c c s s j u w q b e i l 1 + t t t o e L ) c c s S ) I - V 3 e - n y h c \ - ; T A O - p e v l + y t h l o V t d e \ S o y l c h b r i d e
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Scanned by CamScanner - u n c l e r * e c - i c C O r ¡ I t h e p e n t a v a l e n t T . S . c a n t b e f o r m e d . h i n d r a n c e . I f t h e m o l e c u l e i s t o o s t e r i c a l l y h i n d e r e d t h a n c a r b o n s , o r a t l e a s t a t c a r b o n s w h e r e t h e r e i s l i t t l e s t e r i c e a c h r e a c t a n t . T h e s e r e a c t i o n s a r e f a v o r e d a t p r i m a r y t h e s e r e a c t i o n s a r e s e c o n d o r d e r , f i r s t o r d e r w i t h r e s p e c t t o S N 2 R x n . = n u c l e o p h i l i c s u b s t i t u t i o n r e a c t i o n s b i m o l e c u l a r S N 2 v s . S N 1 R e a c t i o n s
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Scanned by CamScanner
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Scanned by CamScanner @ M > c L " . B r E 1 ( » H C o _ > b o c o n # o > i f ; w i ˘ k s ( a ˜ t m p 9 > > h c c o v r > o l - u h e T e l e c k o v i t ( . G L T a s B a ( - e 0 W o r A n S N 1 R e a c t i o n e f f e c t s . i n t e r m e d i a t e c a r b o c a t i o n c a n b e s t a b i l i z e d b y r e s o n a n c e o r i n d u c t i v e h i n d e r e d c a r b o n s w h e r e S n 2 r e a c t i o n s c a n t t a k e p l a c e a n d w h e r e t h e t h e r e i s o n l y o n e r a t e - d e t e r m i n i n g - s t e p . T h e s e r e a c t h e r a t e - d e t e r m i n i n g - s t e p . T h e o v e r a l l r e a c t i o n c a n b e m a n y s t e p s , b u t d e p e n d e n t o n t h e [ ] o f o n l y o n e o f t h e r e a c t a n t s , t h e o n e i n v o l v e d i n t h e s e r e a c t i o n s a r e f i r s t o r d e r w h e r e t h
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Unformatted text preview: f t h e r e a c t i o n i s S N 1 R e a c t i o n s = n u c l e o p h i l i c s u b s t i t u t i o n r e a c t i o n s u n i m o l e c u l a r...
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