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Page 1 of 10HOUR EXAM 3 NAME (Print clearly)__________________ ____________ Chemistry 030.102 Last name First name Section 1 – Prof. Dagdigian April 26, 2013 jhed ID__________________ BE SURE TO PUT YOUR NAME ON THE LAST PAGE Calculators allowed, but do not use programmable features. One sheet of 8 ½×11 in. paper with notes may be brought into the exam. Miscellaneous information: Speed of light c= 3.00×108m s–1Avogadro's number N0= 6.02×1023mol–1 Planck's constant h= 6.63×10–34J s Electron charge e= 1.60×10–19CParticle in a box energies En= n2h2/(8mL2) Electron mass me= 9.11×10–31kg Bohr radius a0= 5.29×10–11m Proton mass mp= 1.67×10–27kg Planck's formula E= hνde Broglie's relation: λ= h/p1 Joule = 1 kg m2s–21 eV = 1.602×10–19J Heisenberg uncertainty relation: (Δx)(Δp) ≥h/4πPermittivity of vacuum ε0= 8.85×10–12C2J–1m–1Energies in one-electron atoms En= –(2.18×10–18J)Z2/n2Relationship of light frequency and wavelength: νλ= cBeer-Lambert law (base 10): –log10[IS/IR] = A= εCl First five rows of the periodic table H He Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe Atomic numbers of the inert gases: He 2 Ne 10 Ar 18 Kr 36 Xe 54 Rn 86 You may use the space below or on page 9 for calculations, etc.
Page 2 of 10 1. Orbital Correlation Diagram for Second-Row Diatomic Molecules One of the oxides of nitrogen is the diatomic molecule nitric oxide (NO). This molecule is a by-product of combustion in air and is an important signaling molecule in mammals. (a) Draw the molecular orbital correlation diagram for NO. Please note that the ordering of the orbitals is similar to that of the O2molecule. (b) Write down the electron configuration for the ground electronic state of NO.