HW%203%20Solutions

HW%203%20Solutions - HW 3 Solutions CH 353 Physical...

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HW 3 Solutions CH 353: Physical Chemistry I (54655) Spring 2008 Bersuker (5 points) I. Show p T V C T H = κ αμ 1 , where H p T = μ , p T V V = 1 α , and T T p V V = 1 . Using Euler’s chain relation (a.k.a. the triple product rule) we say since the total derivative gives: p T V p p H T T T p V p H T T p V p V T V p T C T H C T H p T p H p V V T T p H T T p p H p V V T T p C T p p H T H dT T H dp p H dH = = = = = = = + =
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HW%203%20Solutions - HW 3 Solutions CH 353 Physical...

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