Help Session Problem Set 3-7-08

Help Session Problem Set 3-7-08 - Florida State University...

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Florida State University Chem 2210 Thursday Night Session I 1. Predict the product(s) of each reaction, then circle the most abundant one (Houjeiry). 2. Zaitsev’s rule states that elimination favors the most substituted bond. Specify whether each of the following reactions adheres to this rule. For cases that do not obey the rule explain why they do not (Houjeiry). 3. Suggest a reagent/ solvent in each case, explain your choice (Houjeiry). Me Me Me Cl Me Me Br Me KOEt/ EtOH Heat H 2 O/ Ethanol 4 products 4 products Me Me Br Me KOEt EtOH Me Me + Me Me Me 29% 71 % Me Me Br Me KOC(CH 3 ) 3 HOC(CH 3 ) 3 Me Me + Me Me Me 72 % 28% Me Me Br Me KOC(CH 2 CH 3 ) 3 HOC(CH 2 CH 3 ) 3 Me Me + Me Me Me 89% 11% HO Me Me Me Me Me Cl Me Me Me Me Me Me b a Br Me Me Me d c
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Florida State University 4. Predict the major products and the mechanism by which the reactions proceed (elimination, substitution). Also, draw the rate limiting transition state for each product formed (Demont). 5. Label the following alkenes as E or Z isomers being sure to assign priority to each functional
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Help Session Problem Set 3-7-08 - Florida State University...

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