Key Ch9 - x,_ [IL N7 c /er//r/Il/(’/i‘(’ is u sperm...

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Unformatted text preview: x,_ [IL N7 c /er//r/Il/(’/i‘(’ is u sperm culi»:iHI'Liclng snhslum'c i'cicaisuil by “It Iknnzili: 01' u spacius n} zilguc {Oil/«rm Iiiirl/i/H/(i). 'li'hc, conslilliiinn 0i i'iilillilidcnc is /:/;"f/(_TI [:0 m 13(31 I-i \ (311:4 'J 1;, ' brown (21) llnw 1mm)! slui't'iiisnincrs zu'c i'cpl'uscmcil by [his Cimsllllllion',’ ([3) f‘milliiidcnc has 21 uis iciiilinnship I’iclwccn Ils Lilkcnyl suhsliliicnls. (iivcn Iliis iiiioi'mzi. lion, Imw many slui'cuisnmcis Lli'c pussihic'? (a) ri‘ilL' hliicnyl siilc chuin has lhc Z C(iiiligiii'nlim'i n! ils (limhlc homl. On my basis ()1 all Hu- (ILIILL how many slcrcoismnm's an: possible? ((IJ Draw simuouhcinicnfly LlCCLIl'LllC i’cpi'cscmulinns M (iii lhc sici'coisumcrs Hm! sailist lhc sliuclui'al i'cquii'cmcnls ul' mullifidcnc. (c) How we lllcsc slcrumsomul'ic mullifidcncs i'clulul (oimmimiicrs or Lliuslci'cmncrs)? 31 fl, (GA 1N -‘ :9 3 "i bodmo‘s 0n 5?) imuaciAJW\L GACQLM‘» \ - \ IS CNM- \4) (CAKDAc-kfimaK W E/Zcfajtkwxo \SJ‘AC’L km \4\"¢y-\:CY\C.\'\ZCH3 @ PagéibJrhes _._.\ y _ I (. :— (45 k CM __ H Lag O‘P):\W) act/MMJJCA Ll ?O—n-‘ 2 H K» H H K e) \> 1 f L L \_I; t H H 6% i . fl :: Q “Cunt \o H\_Lv3 I I _ ' Muscal'inc is 21 poisonous substance present in the mushroom Antoni/a musmria. Its struc— “m 15 represented by the constitution shown. H O \ 7| CHXB\‘CI-IQN(CI-Ig)3 HO" O . (a) Including tTILlStitll'iHC, how muny SlUl'COiSOInCI'S httvc this cot'istitutioh‘! (b . . . i . ) one 0i the xiithttucnts on the ring 01 H'lLlSCle‘lnC is trans to the other [wot HOW many of the stoieoisomcm satisfy thix t'uquii‘ttmcnt'.’ . . (C - , , . . . ) MUSLLIHDC has the C(mhgut'utton 25,3“,55. Wi'tte {t Hll‘llclul'iti tormulu ()t' hutld ti l]|t)it;'(‘r u) , - ' ' ' ' 8r modd (Ii muxctu‘tnc shim/mg tts correct SiCI'COChLZI'mSll'y. identity (iIC I'LfiiltliUH‘iin in much 0i {he iUiiUWng pziii's. Hm iilL‘ thawing}, I'C|'H'(:.‘x(!lll consti— tutional isomers ()l' NIUI'UUiMHHLiIS, ()I' are they ‘iUHI Llillcx'mil W2in of drawing lhc 5mm: (:(Jii'iptiLIiiLI‘! [fthcy arc KICI'cuimnicm LII'U Hwy cmiiiliumci’s or (lizixlci'txiiiici's‘? (Mmlccuiiii' HHMiUiN may prove {4L “5%: uan‘mciA. useful in ihis, problem) {uh F “mm: (‘H 3 . H H *‘ ‘ HiC. . \é, P‘ \2 (a) C~~<ii3iai mi CvCi-ipii / I / i 5“ Co as ‘\'\-\'L..:‘: w hL’J HO I 11' (iii 3 D:- H ‘ - H \2, 5 \z, ’1 QMVQ‘.“ M) (h) (‘F- Hr Lind C‘I‘H; LVN \ 'Vm" 7 / \ / CHqCH: ,, Ciimi3 H CH? 3 Hf H _‘ ‘ \‘g )7 p (c) C Hm Lind C ‘Ci'lgCHi 3 (LL‘yx-\.\. ow»? c/\ i / (b ‘ 3i same (/(y/vgfi C9 U “TC. and H O H CH3 ‘1 1‘ H {L M M E V\ vaVJK\ O nu)». ’3 C‘HgCHn‘ Ci LOH 1 \5 0 me P) km; ‘1’». 6‘ 1” (’1'1‘3 1" v\ k. ' J k J L L Pv\‘\!’i“) {-27 x >/ .z (g) [a and HO H H ()H ‘ /“E/ H(m (h) :11 M \‘f m>H // /” (I) \y/;/ :gy/ 'md '7: (5/ C e/ 2 l / I10 H H OH HO ( ) \z/\ 7 and \xr» H0 \/ ‘CHZUH \~._/ 'C‘HJOH HO- '1 "’ (k) [L , 7 and [ /§\ _ H0 \47 ‘CHJH4 \g' WJEOH CH; H OH HO\ ,H H-{C fl 2/3 (1) . 11nd \b/\T\ ‘ / \ 9‘ (113014 H OH HO H CHZOH H Cl-h \;,CH_~\ - a (m) “' Q and H HFC CH: H ' COJH H" » - Br/[\H (l7) 11nd H‘f‘ ‘ ’ H /MB)' - CH; CH} Br-‘RH and 3 H Br COJH and €3n6L~§t\py7u#3 C (Mani—3c \“Kxfl-_7\\C VH1} )2 /\,-‘\ (-K Vq‘: \ (“ml k1,) CLL CL_.;\.,,\:_A,:] /..\,,,VL)Vr/) 5) ‘-J\N JZ/vk C‘k/vck’ \ (KW 'L .5fiflNk/A%03u Write 1h: -I:‘.':.IHIL' pmducls UI' cuch oi. the I'nllmving x'cncliom. H lwn slcrcnimmcrs are fumed. Show Inuit Labs! all alcr‘L-ngcnic cunlcrs /( m .8 us uppml'n'iulc, (it) ]»BLI1-'I'.r uml hydmgcn imlide (b) (E)':'})k'nl(.'|]t and hl'mninc in carbon loll'uchlorltlc (c) (Z)':'P(3Hl\'1‘IIC 11ml hmminc in cmbon [Cll'ilcl’llhl‘idc (Ll) LBLHmu unrl C NC \2 \U‘ H 4! (C) (Z)C-I’un§n:nc and pe-F (1') |5.39MHnL‘HIyILyclnpcxllcnc mul hydrogen in {hc ln'cxunuc ul plulinum (g) '55 'lJiI1'IL‘lhylcyclA)ptlllnmc uml dilxn'nm‘ in lL:lI'21llydl‘ol'm'nn IUHHWUII hy(>>;|(|;llit:|1 WIHl fi‘;mi1m_3ul| punxidc _/ P f I I I 3 f -“7 7 7! \A‘i ‘1 K / V / “L J: -' , 0-H ...
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This note was uploaded on 04/07/2008 for the course CHEM 218A taught by Professor Sullikowski during the Spring '08 term at Vanderbilt.

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Key Ch9 - x,_ [IL N7 c /er//r/Il/(’/i‘(’ is u sperm...

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