Acid-BaseAnswers

Acid-BaseAnswers - Acids and Bases Problems Acids and Bases...

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Unformatted text preview: Acids and Bases. Problems Acids and Bases. Additional Problems Answers Problem 1 + 6”" fKaafl~ 4-10 ART/ZS: a '54s weaéey basic, gravy»: are arma'él'c. aha/neg . ' figs” CS ‘EL-L/D/(a. 31 £41: coy'otjalz and . Problem 2. R-S-NHZ «4-56: 2 H30“‘ + R_%—g~3n HR'f‘=§H<—>R~S=§H '0' O O 0" sulfonamides fie anion, #Saéénamrc/e, 1's 5Mf/fzed é/V'te. rE-SOMnCd forms, Acids and Bases. Problems ' 9 R-C-NH amides "/3 .. + 2 +Hao: 2 H30 + anion yam/He 5&45/5'2340‘ an/g 7110-0 “whence 74/7445 2:1"; "£4044 .Sa-l ham/ales 66W {flair- wean: mam itsancmcc 742/1“: 0 . a0 GD 0? n .0 u ‘ .. I K R-S-N-Ar +4410: :2 4e50+ + R-fiflj" /____\/ 6-9 R-fi=..‘<§;/ “'9 c”) HM _ 0 go N-arylsulfonamides 0 E“ a) J2 2.; 12 ‘5‘ N5291\>D 1-23-41:— 4—9 R-5=N 1““? R"S“§*\; (’3 'n” “J a “ C9 '3 '° h D o 0 O Problem3 M + Ar-NH3+ 4 Hap: :2 Ar-NHL+HsO arylammonium salts " l Z2 )- 6-9 ’ /NH2 *9 " INHD' <—-:v mfiNHL v :59 3‘9\ \ A . ‘ + R-NH3+ + Map: ‘2 R~NH2 4- H30 alkylammonium salts ) Acids and Bases. Problems Problem 4 R-S'OH 4"” o: 1.1-? 2’5’0 é—> R- _:::O <-—9 R‘S:O n ‘9‘ H n; O 0 o an/m 6i refondnce’ firms 0 e R Cyo H --'>‘_ R (C; é—--? C/O _ + : ___ __ \OH \ 06 O carboxylic acids Problem 5 3) H3C\N/CH3 H3CO (3+2 0 (693 Q /N\ CHZOH H CH3 PKG“, 16-48 'b/(Qevcwo [es/Q m -7 ,o/(aw 6-7. c '3qu; "KO/H C40 16W (3 3‘ 4‘ <3 \t/ N / \O/ 0 64-50 9 (EH Acids and Bases. Problems b) : E)‘ “O O “a O :®/H O afOMd‘é/C. rz'n ) V561 GAL“?- K‘fiH fl (‘1 * \/ \ _ 5 '16:!) CH5 ‘4ng ecu-c? Figs. 15-16 PKL. 6’ IO PKM, 16792, a. ‘V ' Problem6 a/b O p el/O @ g .'- + . ' . ' ©:</:NH +H9-O 2-? “330 + 4—? @\59* 018%0 cf \\0 o// ‘8 I, o //o / . /'$\\ 0:) O- @o ’ 'O J 0 NH? (-3 non. basic N (.E'Fu'r" I'S farts 0% Acids and Bases. Problems Problem 7 : w: I = l x ,Hom—sz 1+ 10"" g wnizauac, _—.. Q4 17. H =?¢4.‘ u / I O 00 :: .1.- = 6 P I+Io 9'F‘5‘2- ’+ ’02 7‘ Z (Jam .2: O 67:: Problem8 / Mosfiauc/vc.) arm'm 6125/5224 6 ’CSofla"“— {\I OH "e O \ R @gK/z'a N‘H H 6 \ jNH K ""J‘ H + ' \ O 3. 2 Q g é—B O \ \/ 7752* an dad g/fflcflrm 694) 646 deg/(e. a]! eD\//'|‘1YO UDNIZaé/ M/ 69 (Kg/Von ' \‘Jfir-PKH ._ I Q 0 _‘ N / I+IOPK°~”PH PH: [:8 : O( :1- , = I g Q I+Io"“’ 6’ /+/o~‘”l F /+ 1075’?” H {0’0 5 Acids and Bases. Problems Problem 9 H3C N / H k ® 6 O L, HI?! 0 N - I CH3 CH3 Problem 10 69 9 EB @NFYVa/N.)/N‘H eHgf-g-Z/ “’09 ‘H ” \/® \QED LM/aortan‘é resonance form; GD EB 3 _ / \ *——> \N9H H “N\ “H \/ ® 5‘) £59 lief/'50 (fin/60f fa" ‘6 Pale/Lance 741W": - b) I‘vaaJn '6 74).” (site S’r'c/e céwr'n/ 6A8 *W'O I’M’HQZD/e, #4 wall 65 [0/845 2914/ Acids and Bases. Problems P162:940 _ ® NH} :-<\/ Ho‘ : /N""H N V@ 2 mill 3.) /—_<\/NH3 1 N\\/:N"'H + ""K?” ‘HO‘ an e?u.u/ /~<VHH;_ [Vim ...
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Acid-BaseAnswers - Acids and Bases Problems Acids and Bases...

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