Midterm1_Review

Midterm1_Review - Chemistry 17 Review Session #1 Monday,...

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Chemistry 17 Review Session #1 Monday, October 16, 2006 Part 1: Andres Martinez Question 1 . (a) Provide the hybridization and bond angles for all C, N, and O atoms in the starting material and in the product of the following reaction. H 3 C O H NaCN H 2 O H 3 C OH CN (b) How many resonances would you expect in the 13 C NMR spectra of the starting material and product? (c) What would be the main difference in the IR spectra of the starting material and product? Question 2. How many resonances would you expect in the 13 C NMR spectra of the following compounds? t -Bu H 3 C O NH 2 Et H 3 C CH 3
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Part 2: Miriam Quintal Question 1. For each of the following pairs of reactants: i) identify the nucleophile and electrophile ii) draw the curved arrow mechanism for the addition of the nucleophile to the electrophile iii) predict the product iv) draw and label the frontier molecular orbitals involved in the reaction (HOMO and LUMO) 1.
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Midterm1_Review - Chemistry 17 Review Session #1 Monday,...

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