CHE331-800 10.17

CHE331-800 10.17 - fisher Wage(£70715 CM mm W 180” nfl...

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Unformatted text preview: fisher Wage/(£70715 , CM mm W 180” nfl ip Pr. , l “if/W9 may poi/Its up mafia flame M.\91W3 won 0 Meso Compounds astreo 0 Sometimes molecules with two or more stereogenic centers .1 and In: 1 WI" have less than the maXImum number of stereOIsomers. 511:4 (mom W) GU (1646?” W I CH3 (Ml ,Wa’) 35. 'm (ind fl We *ICHBr C “'53 C H3 w some. film. 9', t ,P H ‘ 0i”) 66 Du tum ('31 ' M MD 2,3-Dibron:0butane * 87f BF \ W C“; C Ll? @ @ '1'de 0Uf€ WWMCS . ~ WW "W01 1er W WWW WCMy’ [gm “)0”de 0 Mesa compounds are achiral despite the presence of stereogenic centers. IDNot optically active #Superposable on its mirror image A IDHas a plane of symmetry ( \fl tttfld l\ L &\Br L/CKHHBI‘ CH3 L H Chapter 5 12 Write a three—dimensional formulas for all stereoisomers of each of the following compounds: " 3 CHgCHZCH(Br) H(OH)CH3 O Naming Compounds with More than One Stereogenic Center 0 The molecule is manipulated to allow assignment of each Stereogenic center separately. Apply the sequence rules as before. b 4 CH2CH3 at 3 H 2 C1 ICH3 ' W 2, 3 00Cth 0mm A 15 (M2399 21,3: ouch/0m yam/u l6 1'5 (213,35? (2’ 3 Wain/m pafl‘zuu“; 10/4/13 13 "F CH 3) CH; CR (Ear) CH (0M CH5 I be Sam (1:: CH3 CM H I Claim/n: 0(065 EDT aw?) Jwre._ #2600175 03/2/31 0Y1 obviate Owéwmd nzzgswm P , ._ WW h, , H W, w C “3 CR3 ._ 5t Qfld 3: am m/‘frpr,4wét§r€,s i ,7 W i 17 cum! 1’ are ,, I ' 4/6 w‘défréfiwsm WM, I, mam} II a m_____m Mai III COME 00M- _ L ,MQ’ 71:51.16 QUaSfl/w W n W f, i L. . ‘7‘ r _..r_ # f 9o fl ((2%)15 3‘??—a+_gpéifim “D H(d\ “’3’ a —17$at pas? M A _—_ -————_————_———_—_—_— & 0 NC) c9 1 Chiratflg Cfiflfifn mam # ' QWLDWS = 2n - fl =4*Oh£f0L\ cafiaan +=1t Obsz Jam Umns Df/dl/b/ “5L 2n:94+5:&(o:?p4_ I ...
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