MT2-1 - 5(4 minutesI 8 mintsl a Label the following in...

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Unformatted text preview: 5. (4 minutesI 8 mintsl a. Label the following in order of decreasing reactivity towards hydrolysis. (Label the most reactive #1.) ll ii ‘3 cram—O CH3CO—O—OCH3 CH3CO—©—N02 Z .3 l b. Circle the compound that is more reactive towards reaction with nucleophiles. M ii 1- H3 CH2CH2CCH3 or CH3CH2C|3HCCH3 CH3 0 a ll 2. CH3CH2CCH3 or w c. A carboxylate ion can be activated in cells by reacting with ATP too form either an acyl phosphate or an acyl adenylate. Show the mechanism for the formation of both of these activated compounds. 0 O O 0 O 0 II II II II n [L /C\".‘/;\—|/P\ / \ /P\O/Ad C\ F __ + AID P CH3 0- O I O I _ O I _ —’ / o/ \o " 0‘ O 0 CLE ‘0. an acyl phosphate 0 (I). (I)l (Ii (Ii 0 " AA (l c) C _ P 0 P Ad F 4-— CH3’ ‘0 + ‘0’]ijo’ Ifo’ Ifo’ —> Oti/O‘o/ (\0’ 5" ; anacyl adenylate 0" o f 6. (4 minutes, 4 points) Give two names for each of the following compounds. 0 II C a. CH3CHCH2/ ‘OCHZCHZCH3 (P “01% 3’WWU M l . Br W 5'54”»005‘9644, M ",(L _ I o b- CH3CH2CH2CH2/ \DIJCH3 N, N- WW1” CH3 ’U/ U " W VW O O— ...
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