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scan0003 - Pm" “TVA-as KZ~ 7(10 pts Write a chemical...

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Unformatted text preview: Pm." “TVA-as KZ~ 7. (10 pts) Write a chemical equation for conversion of the less stable chair structure (on the left) for methylcyclohexane to the more stable chair Structure(on the right). Predictthe free energy, AG”, of the reaction as written from the less to the more stable conformer. j . ‘ g 1 , ‘5] g ' __ 5 _>A_.,,- J: ‘ _ o_ W/ gigm'mw rf yawn mg.“ ' 7 - AG— g .9 / WM; 8. (10 pts) (a) Complete the following acid-base reaction. (b) give the pKa of each acid from the values in the table below, (0) Show with an arrow the direction of the equilibrium, (d) predict the equilibrium constant, K. (e) Predict AG". 4““ /~_ - 4. In /0 if“ {Ziggy If; f H30+ -2 K= M x} 1" W I W‘fié’fiy “339;!“ AG): ~— /574 ”Way/W587i 23E}; ”/1; 1:138 i: __——————— {q . . + p ex NH: 9 1130+ + NH3 + H20 4“ ”Ag: fig??? iii? ...
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