Acids and Acid Derivatives

Acids and Acid Derivatives - CHM 2211 Problem Set 15...

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CHM 2211 Problem Set 15 Solutions Acids and Acid Derivatives Complete the reactions by showing major product(s). Write N.R. if no reaction occurs. 1. 2. No reaction without help 3. 4. 5. 6. 7. 8. 9. 10. 11. C O OH + NaOH C CH 3 OH O + NH 3 C CH 2 CH 3 OH O + NaH C CH 2 CH 3 OH O SOCl 2 reflux Product from rxn 4 NH 3 Product from rxn 4 CH 3 NH 2 Product from rxn 4 CH 3 CH 2 COONa Product from rxn 4 H 2 O Product from rxn 4 CH 3 CH CH 3 OH Product from rxn 4 NH 2 Product from rxn 4 NH CH 3 CH 3 ONa O C CH 2 CH 3 ONa O + H 2 C CH 2 CH 3 Cl O C CH 2 CH 3 NH 2 O C CH 2 CH 3 NHCH 3 O C CH 2 CH 3 O O C CH 2 CH 3 O C CH 2 CH 3 OH O C CH 2 CH 3 O O CH CH 3 CH 3 C CH 2 CH 3 NH O C CH 2 CH 3 N O CH 3 CH 3
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12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. CH 3 CH CH CH 3 a. KMnO 4 /OH - /H 2 O/reflux b. HCl CH 2 CH 2 CH 3 OH NaCr 2 O 7 /H + /H 2 O CH O CrO 3 /H + /H 2 O or Ag(NH 3 ) + CH 3 H 3 C a. KMnO 4 /OH - /H 2 O/reflux b. HCl CN H + /H 2 O reflux Br Mg EtOEt CO 2 HCl C CH 3 OH O CH 3 CH CH 3 OH + H 2 SO 4 reflux C CH 3 O O C CH 3 O H 2 O C CH 3 O O C CH 3 O CH 3 OH C CH 3 O O C CH 3 O CH 3 NH 2 C CH 3 O O C CH 3 O NH 3 C CH 3 O O C CH 3 O NH CH 3 C CH 3 OH O 2 C CH 2 CH 3 OH O C O HO COOH HOOC C O HO C O HO C CH 3 O O CH CH 3 CH 3 C CH 3 OH O 2 C CH 3 O O CH 3 C CH 3 NH O CH 3 C CH 3 NH 2 O C CH 3 N O CH 3
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24. 25. 26. 27. 28. 29. 30. 31. the TFA - is the L.G. as it is a weaker base
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Acids and Acid Derivatives - CHM 2211 Problem Set 15...

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