2008Test3ReviewKey

2008Test3ReviewKey - Name: _ Class Number Key Midterm III...

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page 1 of 7 Name: _____________________________________ Class Number Midterm III Review , Spring 2008 Chemistry 2210 Professor S. A. Miller, April 8th, 2008 Key
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page 2 of 7 Problem Number Possible Score Your Score 1 42 2 30 3 42 4 36 Total 150 Last Name: _________________ First Name: _______________ Signature: ___________________________________________
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1. (42 pts.; 7 pts. each) Draw the following. CHM 2210 Midterm III Review page 3 of 7 (a) A reaction energy diagram for the hydrogenation of isobutylene and indicate Δ H of the reaction and its value. (b) An anti-Bredt olefin. (c) A mercurinium ion. + H 2 reaction coordinate energy Δ H = 28.0 kcal/mol a small (C7 rings and less) bridged bicyclic compound with an olefin at a bridgehead position Table 7-1 is on the front. Hg OAc
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1. (continued) CHM 2210 Midterm III Review page 4 of 7 (d) An alkene for which hydroboration and H 2 SO 4 /H 2 O would give the same product. (e) A glycol. simply a vicinal diol (f) Draw a hydrocarbon with 3 units of unsaturation and a p K a of 25. OH HO This alkene must be symmetrical and not prone to rearrangement. Thus there is no distinction between Markovnikov and anti-Markovnikov addition.
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This note was uploaded on 04/29/2008 for the course CHM 2210 taught by Professor Reynolds during the Spring '01 term at University of Florida.

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2008Test3ReviewKey - Name: _ Class Number Key Midterm III...

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