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PS6Key - CHM 2210 Problem Set 6 Due March 5th 2008 Multiple...

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page 1 of 2 Name: _______________________ CHM 2210 Problem Set 6 Due: March 5th, 2008 S. A. Miller score/20 student# KEY Multiple Choice (1 point each) (1) What is the IUPAC name of the following compound? (A) 1,1-dibromo-3-tert-butylcyclohexane (B) 3-tert-butyl-1,1-dibromocyclohexane (C) 3,3-dibromo-1-tert-butylcyclohexane (D) 1,1-dibromo-3-isopropylcyclohexane letter A (7) Which of the following alkyl halides reacts most slowly with NaN 3 in dimethylsulfoxide? (A) (B) (C) (D) A (6) The reaction of 1-bromopropane with sodium iodide gives 1-iodopropane. What is the effect of doubling the concentration of NaI on the rate of the reaction? (A) The rate is halved (B) The rate increases by a factor of 2 (C) The rate increases by a factor of 4 (D)The rate remains the same B (2) Which of the following alkenes undergoes allylic bromination to form a single monobrominated product? (A) (B) (C) (D) (E) E (5) What is the major product of reacting ( S )-2-bromopentane with sodium cyanide? (A) (B) (C) (D) B Br Br (3) How many different monobromination products can be formed in the allylic bromination of the following molecule? (Count stereoisomers separately.)
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