RxnKineticsIntro

RxnKineticsIntro - Chemical Reaction Kinetics Reaction...

Info iconThis preview shows pages 1–5. Sign up to view the full content.

View Full Document Right Arrow Icon
Chemical Reaction Kinetics Reaction order and mechanism Reversible reactions Finding, and working with, with kinetic and thermodynamic constants in batch reactions Chemical reactions in open systems: the CSTR and PFR reactor types
Background image of page 1

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Order & Molecularity Elementary reaction: single-step reaction mechanism involving 1 or 2 reactants A B, A B + C unimolecular: 1 reactant Cyclopropane propene (propylene) N 2 O 5 NO 2 + NO 3 C + B A, A + B C + D bimolecular: 2 reactants Iv«»ª* I 2 N 2 O 5 + H 2 O 2 HNO 3
Background image of page 2
Mechanism Reaction mechanism: a series of elementary reactions leading from reactants to products. Example: enzymatic conversion of one substrate CH 2 OH C O CH 2 OPO 3 2- O H C H C OH CH 2 OPO 3 2- Triose phosphate isomerase Glyceraldehyde 3- phosphate Dihydroxyacetone phosphate
Background image of page 3

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Example: enzymatic mechanism S + E ES, binding of substrate and enzyme ES E + P, conversion of activated complex ES to product and free enzyme ES S + E,
Background image of page 4
Image of page 5
This is the end of the preview. Sign up to access the rest of the document.

This note was uploaded on 04/29/2008 for the course BEE 2220 taught by Professor Hunter,j.b. during the Spring '08 term at Cornell.

Page1 / 16

RxnKineticsIntro - Chemical Reaction Kinetics Reaction...

This preview shows document pages 1 - 5. Sign up to view the full document.

View Full Document Right Arrow Icon
Ask a homework question - tutors are online