Lec uhhh tuesday

Lec uhhh tuesday - Review Coordination Chemistry: Complex...

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Review Coordination Chemistry: Complex Complex Ion Ligands Coordination Number Coordination Compound Naming Compounds
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Preview Crystal Field Model (and its applications) Isomers
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Isomers Two or more species with the same formula but different properties Structural Isomers Isomers with the same atoms, but different bonds Stereoisomers Isomers with the same bonds, but different spatial arrangements
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Isomers (Same formula but different properties) Structural Isomers (different bonds) Stereoisomers (same bonds, but different spatial arrangements)
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Examples of structural isomers: Coordination Isomer The composition of a complex ion varies Example: [Cr(NH 3 ) 5 SO 4 ]Br [Cr(NH 3 ) 5 Br]SO 4
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Examples of structural isomers: Linkage Isomer The composition of the complex ion is the same, but the point of attachment of at least one of the ligands differs Examples: Thiocyanate (SCN - ) Nitrite Ion (NO 2 - ) Both can bond to the metal through two different atoms with lone pairs
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[Co(NH 3 ) 4 (NO 2 )Cl]Cl
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This note was uploaded on 03/21/2009 for the course CHEM 6C taught by Professor Hoeger during the Spring '08 term at UCSD.

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Lec uhhh tuesday - Review Coordination Chemistry: Complex...

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