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Unformatted text preview: products of over-alkylation. The imine formation-hydrogenation sequence avoids this problem. Some problems in synthesis were discussed that allowed us to refresh our memory of some key reactions from 310M (epoxidation, H 2 CrO 4 oxidation, ozonation, E 2-elimination). Be sure to know the mechanisms for ketal/acetal, dithiane, imine and enamine formation and hydrolysis. The Wolff-Kishner Reduction was discussed and we reviewed the mechanism. The Clemmenson reduction was discussed. The oxidation of aldehydes employing sliver oxide was discussed. The Baeyer-Villiger oxidation was discussed and we reviewed the mechanism....
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This note was uploaded on 03/31/2009 for the course CH 318M taught by Professor Bocknack during the Spring '08 term at University of Texas at Austin.
- Spring '08